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Rotating-Magnetic-Field-Assisted Electrodeposition of Copper for Ambulance Medical Equipment Syamsuir, Syamsuir; Susetyo, Ferry Budhi; Soegijono, Bambang; Yudanto, Sigit Dwi; Basori, Basori; Ajiriyanto, Maman Kartaman; Edbert, Daniel; Situmorang, Evi Ulina Margaretha; Nanto, Dwi; Rosyidan, Cahaya
Automotive Experiences Vol 6 No 2 (2023)
Publisher : Automotive Laboratory of Universitas Muhammadiyah Magelang in collaboration with Association of Indonesian Vocational Educators (AIVE)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31603/ae.9067

Abstract

This study examines the influence of the application of a rotating magnetic field in the electrodeposition of copper (Cu). During the electrodeposition, five constant magnets were rotated (500 and 800 rpm) towards the bottom of the sample. To investigate deposition rate, surface morphology, phase, structure, corrosion resistance, and hardness in deposited Cu using a weighing scale, a scanning electron microscope equipped with energy dispersive spectroscopy (SEM-EDS), X-ray diffraction (XRD), potentiodynamic polarization, and hardness tester respectively. Bacterial activity was also evaluated through this research. Morphological surface observations showed that the increase in the rotational speed of the magnets during the electrodeposition process led to a smooth surface. A perfect Cu phase covers Al alloy with no oxide. The potentiodynamic polarization demonstrated by the increase in the rotating led to a shift to the more positive value of the corrosion potential. Moreover, the corrosion current also decreases with the increase in the rotating speed of the magnets. Less crystallite size promoted forming a higher hardness and inhibition zone of the Cu films.
SINTESIS DAN ANALISIS INTERAKSI SENYAWA MATERIAL KOMPOSIT BATIO3/HAP DAN KOMPOSIT PVDF/ BATIO3/HAP DENGAN METODE SOLUTION MIXING Adnan, Septian Rahmat; Kurniawan, Budhy; Soegijono, Bambang; Erni, Nofi; Rachman, Taufiqur
AME (Aplikasi Mekanika dan Energi): Jurnal Ilmiah Teknik Mesin Vol. 10 No. 2 (2024)
Publisher : Universitas Ibn Khaldun Bogor

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Fenomena ferroelektrik yang telah secara luas diterapkan pada berbagai bidang, terutama bidang otomasi industri, komunikasi, diagnosis medis, pertahanan, energi hingga energi baru dan terbarukan. Material ferroelektrik dalam bentuk komposit polimer/keramik yang telah banyak dikembangkan adalah komposit Barium Titanat (BaTiO3)/Polyvinylinede Fluoride (PVDF) dan komposit BaTiO3/Hydroxyapatite (HAp) karena memiliki sifat polarisasi, dielektrik dan breakdownstrength yang baik dan juga relatif murah di pasaran. Beberapa peneliti telah melakukan sintesis material komposit PVDF/BaTiO3 dan BaTiO3/HAp dengan berbagai metode salah satunya adalah metode solution mixing dilanjutkan Hot pressed dan metode Hydrothermal tetapi belum ada peneliti yang mensintesis material komposit PVDF/BaTiO3/HAp. Tujuan dari penelitian ini adalah untuk mencari solusi sintesis dari material komposit BaTiO3/HAp, dan komposit PVDF/BaTiO3/HAp dengan menggunakan metode solution mixing dan melakukan karakterisasi Fourier-transform infrared spectroscopy (FT-IR) untuk mengetahui interaksi senyawa yang terjadi pada material komposit BaTiO3/HAp, dan komposit PVDF/BaTiO3/HAp yang dihasilkan. Hasil penelitian menunjukkan sintesis material komposit BaTiO3/HAp dan komposit PVDF/BaTiO3/HAp telah berhasil dilakukan menggunakan metode solution mixing dilanjutkan dengan pemanasan menggunakan hotplate. Hasil pengujian pengujian FT-IR komposit BaTiO3/HAp didapatkan 8 puncak spektrum, dengan 3 puncak mengidentifikasi ikatan atom pada material hydroxyapatite (HAp) dan 5 puncak merupakan hasil interaksi larutan material dengan udara dengan jenis ikatan stretching. Pada komposit PVDF/BaTiO3/HAp didapatkan 15 puncak yang keseluruhannya merupakan ikatan atom dari material pembentuk dengan mayoritas ikatan pada material Polyvinylidene Fluoride (PVDF).
Nickel Salt Dependency as Catalyst in the Plating Bath on the Film Properties of Cu/Cu-Ni Rosyidan, Cahaya; Kurniawan, Budhy; Soegijono, Bambang; Maulani, Mustamina; Samura, Lisa; Nababan, Frederik Gresia; Putra, Valentinus Galih Vidia; Susetyo, Ferry Budhi
Science and Technology Indonesia Vol. 9 No. 3 (2024): July
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/sti.2024.9.3.529-538

Abstract

Metal plating frequently employs nickel (Ni) and copper (Cu) as anodes. Cu/ Cu-Ni film formed has many advantages, such as better corrosion resistance and high hardness characteristics. This study aims to assess the properties of Cu/Cu-Ni film, such as phase, surface morphology, crystallographic orientation, hardness, corrosion analysis, and contact angle, which were fabricated using electrodeposition with various Ni salt additions (0.3, 0.5 and 0.7 M). In addition, the cathode current efficiency (CCE) and deposition rate of the Cu/Cu-Ni electrodeposition were also investigated. An increase in Ni salt in the plating bath could enhance the pH, promoting higher CCE and depleting hydrogen evolution at the cathode, leading to the presenting Ni phase in the alloy. The higher concentration of Ni salt in the solution could also enhance the deposition rate due to a shift to a pH value, which affects the roughening of the surface morphology, promoting a higher contact angle. All crystal structures generated by Cu/Cu-Ni electrodeposition were FCC, with the preferred orientation of the (111) plane. Crystallite size and lattice strain depend on the deposition rate. Less crystallite size and lattice strain affect the film’s hardness and corrosion resistance. Moreover, the third bath had the resulting Cu-Ni layer with the best hardness and corrosion rate of around 136 HV and 0.081 mmpy.
Diamagnetic to Ferromagnetic Like Transition of Non-Stoichiometry Barium Titanate (BaTiO3-x) Prepared by Sol-gel Method Soegijono, Bambang; Susetyo, Ferry Budhi; Notonegoro, Hamdan Akbar; Raksa, Teguh Yoga
Science and Technology Indonesia Vol. 9 No. 4 (2024): October
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/sti.2024.9.4.876-883

Abstract

The oxygen vacancy properties are significant, creating ferromagnetic properties of material in metal oxide systems like dilute magnetic semiconductors. An aqueous sol-gel method has been used in the present study to synthesize non-stoichiometry BaTiO3-x polycrystalline. In an attempt of examining the oxygen deficiency consequences on the magnetic properties, the gel samples were sintered (1000◦C) at various times (6, 12, 18, and 24 hours) under a vacuum environment. This study employs an X-ray diffraction apparatus in terms of characterizing segments and structures of the samples. It also investigates morphology and element distribution on the surface of the samples exploiting an Electron microscope where Energy dispersive spectroscopy is supplied. For the purpose of characterizing the magnetic properties of the samples, it applies vibrating sample magnetometers. The chemical state of the element and its corresponding bond to other elements was identified using X-ray photoelectron spectroscopy. Single-phase compounds were observed. The crystal system is tetragonal, but the crystal parameters are different. Increase sintering time leads to increase crystallite size and decrease in micro strain. Moreover, sintering in a vacuum environment results in oxygen deficiency and leads to the atomic ratio of Ba/Ti change as the sintering time increases. The Ba/Ti ratio change affects the transformation from diamagnetic to ferromagnetic-like. The elements (Ba, Ti and O) chemical state is shown and its bonding to the corresponding element along with the X-ray photoelectron spectroscopy pattern of the BTX2 sample. The element of oxygen binds to Ti and Ba while Ba element exists in two chemical states.
Carbon Micron-size Content Dependency in Epoxy/Carbon Composite Coated onto SPCC Plate for Automotive Bodies Protection Anggrainy, Rani; Susetyo, Ferry Budhi; Lubi, Ahmad; Yudanto, Sigit Dwi; Rosyidan, Cahaya; Soegijono, Bambang; Ajiriyanto, Maman Kartaman; Kurniawan, Ova; Nanto, Dwi
Science and Technology Indonesia Vol. 9 No. 4 (2024): October
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/sti.2024.9.4.989-998

Abstract

Conventional epoxy coating for surface metal corrosion protection reported many unsolved technical problems. Adding filler in the epoxy could enhance the promising properties of the composite coating. Our work describes in detail the synthesizing and characterizing epoxy/carbon composite coating. Epoxy was mixed with thinner high gloss (HG) and hardener and stirred using a stirrer apparatus. After blending, various carbons were added (1 wt. %, 3 wt. %, and 5 wt. %) and then appropriately stirred. The different mixture composite was coated onto the steel plate cold rolled coiled (SPCC) plate using high-volume low-pressure (HVLP) in two passes. Various characterizations were performed, including crystallographic orientation, Infra-Red (IR)-spectra, surface morphology, thickness, hydrophobicity, hardness, and corrosion using X-ray diffraction (XRD), Fourier transform infrared (FTIR), Scanning electron microscopy (SEM), portable dry film coating thickness (DFT), digital camera, Vickers microhardness tester, and Potentiostat, respectively. More carbon micron-sized content led to elevate the peak intensity, surface bumpiness, and hydrophobicity. The uppermost external bumpiness and hydrophobicity values are 23.51 µm and 101◦. Hardness depends on carbon content and more carbon leads to an increase in the hardness of the composited coating. The highest average Vickers hardness value is 28.24 HV. The coating thickness influenced the corrosion rate, more coating thickness promoted lesser corrosion rate. The highest coating thickness (60.8 µm) promoted a corrosion rate of around 5.65×10−4 mmpy.
Creation and Evaluation of a Polyurethane/Carbon/Zinc Oxide Film Composite for Use as a Coating Material Kurniawan, Ova; Soegijono, Bambang
Jurnal Konversi Energi dan Manufaktur Vol. 10 No. 2 (2025)
Publisher : Universitas Negeri Jakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21009/JKEM.10.2.9

Abstract

The material used as a coating must have unique characteristics. A frequently used coating material is polyurethane. Even though Polyurethane has been widely used as a coating material, it has limitations in thermal resistance. Incorporating fillers such as carbon and ZnO can improve its thermal, dielectric, and corrosion-resistant properties. Composite films of polyurethane with carbon, ZnO, and a mixture of both were prepared. Characterizations included FTIR, TGA, DSC, XRD, dielectric testing, salt spray, water vapor permeability, hydrophobicity, and adhesion tests. FTIR confirmed the presence of functional groups from the fillers. TGA and DSC showed improved thermal stability, particularly in carbon-filled composites. Salt spray and permeability tests indicated enhanced corrosion resistance in ZnO-filled samples, while dielectric properties improved with carbon addition. Hydrophobicity and adhesion tests met coating material criteria. Among all variants, the polyurethane/carbon composite demonstrated the most favorable combination of thermal, dielectric, and surface properties, making it the most suitable for protective coating applications.
Layer Influence on Organosilica Composites Strength to Withstand the Impact of 9mm Caliber Bullets Notonegoro, Hamdan Akbar; Sofyan, Muhammad Azis; Rizkynawan, Benridho; Soegijono, Bambang; Setiawan, Jan; Aritonang, Sovian; Suherman, Andri; Ali, Nora'aini
Jurnal Sains Materi Indonesia Vol. 27 No. 1 (2025): Jurnal Sains dan Materi Indonesia
Publisher : BRIN Publishing (Penerbit BRIN)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55981/jsmi.2025.10243

Abstract

The use of steel panels in conventional bulletproof vests is no longer relevant to current needs. In addition to being heavy, troop flexibility is disrupted. It is necessary to develop lighter and more reliable composite panels. The purpose of this study was to determine the ability of organosilica resin composite panels that were given variations of 5, 7 and 9 layers of woven fiberglass to withstand 9 mm caliber bullets using the NIJ-0101.06 Standard. The results of the firing test showed that the bullets were held back in the 7th and 9th layers. This result shows that this composite is a worthy candidate to replace conventional steel panels in bulletproof vests.
INVESTIGASI SIFAT DIELEKTRIK LAPISAN KOMPOSIT PVDF/ BATIO3/HAP DISINTESIS DENGAN METODE SPIN COATING Adnan, Septian Rahmat; Kurniawan, Budhy; Soegijono, Bambang; Erni, Nofi; Rachman, Taufiqur; Amperajaya, M. Derajat
AME (Aplikasi Mekanika dan Energi): Jurnal Ilmiah Teknik Mesin Vol. 11 No. 2 (2025)
Publisher : Universitas Ibn Khaldun Bogor

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32832/ame.v11i2.1635

Abstract

Pada penelitian ini larutan komposit PVDF/BaTiO3/HAp disintesis menggunakan material Polyvinylidene Fluoride (PVDF), Barium Titanat (BaTiO3) komersial dan Hydroxyapatite (HAp) yang disintesis dari tulang sapi. Selanjutnya larutan komposit disintesis menggunakan metode solution mixing dan dideposisi menggunakan metode spin coating pada subtrat tembaga (Cu), Silikon (Si) dan Platinum (Pt) pada kecepatan 2000 rpm, 3000 rpm dan 4000 rpm sebanyak 2 lapis untuk tiap sampel. Didapatkan bahwa kecepatan spin coating optimum pada 4000 rpm. Ketebalan dan kekasaran lapisan komposit PVDF/BTO/HAp yang dideposisi pada subtrat silicon (Si) dan Pt 2 lapis yaitu pada rentang 1,04 – 2,52 μm dan kekasaran < 0,1 μm. Dengan bertambahnya komposisi hydroxyapatite pada lapisan komposit PVDF/BTO/HAp dengan kecepatan spin coating 4000 rpm menyebabkan nilai impedasi, konstanta dielektrik dan dielectric loss (tg δ) dengan nilai konstanta dielektrik 15(100 Hz) pada komposisi komposit 35,83 Wt%:35,83 Wt%:28,34 Wt% dan 9 (100 Hz) pada komposisi 40 Wt%:40 Wt%: 20 Wt%, serta nilai dielectric loss (tg δ) 0,15 (100 Hz) dan 0,5 (100 Hz)  pada komposisi 35,83 Wt%:35,83 Wt%:28,34 Wt%. Nilai konstanta dielektrik dari lapisan komposit PVDF/BTO/HAp mengalami kenaikan dengan bertambahnya komposisi hydroxyapatite dari 20Wt% ke 28,34Wt% pada frekuensi rendah di rentang 10 – 1k Hz tetapi menurun pada frekuensi rendah direntang 10 – 100 Hz.
Co-Authors A.A. Ketut Agung Cahyawan W Aditia Pradipta Adnan, Septian Rahmat Akmal Johan Ali, Nora'aini Andika W. Pramono Andri Suherman Anggrainy, Rani Arief Ramadhan Arief Ramadhan Arief Sudarmaji Arief Syarifuddin Fitrianto Arief Syarifuddin Fitrianto Aritonang, Sovian Arsali Arsali Asep Yudi Hercuadi Asep Yudi Hercuadi, Asep Yudi Azwar Manaf Basori Basori Bintoro Siswayanti Budhy Kurniawan Cahaya Rosyidan Caing Caing Chandra, Johannes Daniel Edbert, Daniel Decky J. Indrani Dhimas Satria Dona Sulistia Kusuma Dwi Nanto, Dwi Dwita Suastiyanti Edie Sasito, Edie Elman Panjaitan Emil Budianto Emil Budianto Erfan Handoko Evi Ulina Margaretha Situmorang Fendy Rokhmanto Ferry Budhi Susetyo Ferry Budhi Susetyo Ferry Budhi Susetyo Ferry Budhi Susetyo Ganis Sanhaji, Ganis Gina Libria Nadjamoeddin Greida Frista Hamdan Akbar Notonegoro Hamdan Akbar Notonegoro Hamdan Akbar Notonegoro Hasanudin Gufron Fachrudin Ika Kartika Ika Kartika Isom Mudzakir, MSi. Iwan Sugiharto Iwan Sugihartono Jan Setiawan Kiky C. Sembiring Koji Yoneda Koji Yoneda, Koji Kurniawan, Ova La Ode Husein ZT La Ode Husein ZT, La Ode Lubi, Ahmad M Yudi Masduky M. Derajat Amperajaya M. Hikam M. Hikam Maman Kartaman Ajiriyanto Manawan, Maykel Maryati Maryati Maulani, Mustamina Maykel Manawan Moch Iqbal Zaelana Muttahar Mohammad Khotib Muhamad Farid Muhammad Hikam Muhammad Hikam, Muhammad Muhammad Irfan Faturrohman Muhammad Irfan Faturrohman, Muhammad Irfan Musfirah Cahaya Fajrah Nababan, Frederik Gresia Naila Mubarok Nazarudin Koto Nino Rinaldi Nofi Erni Notonegoro, Hamdan Akbar Ordas Dewanto Ordas Dewanto, Ordas Ova Kurniawan Pius Sebleku Putra, Valentinus Galih Vidia Rakhman Sarwono Raksa, Teguh Yoga Ramlan Ramlan Renanto Putra Wijaya Rizkynawan, Benridho Rizqon Priyotomo Rizqon Priyotomo, Rizqon Rokhmanto, Fendy Samura, Lisa Septian Rahmat Adnan Septian Rahmat Adnan Septian Rahmat Adnan Septian Rahmat Adnan, Septian Setia Budi Sofyan, Muhammad Azis Sovian Aritonang Sudaryanto Sudaryanto Suhariyanto Suhariyanto Suharso Suharso Suharso Suharso Sukarno Sukarno Surya Darma Sutrisno S Syamsuir, Syamsuir Tarmizi Tarmizi Taufiqur Rachman Widjaya, Robert Ronal Wisnu Purno Aji Wisnu Purno Aji, Wisnu Yosef Sarwanto Yudanto, Sigit Dwi Zainal Alim Mas&#039;ud Zainal Alim Mas’ud Zulkarnain Jalil Zulkarnain Jalil