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Journal : Waste Technology

Liquid and Gaseous Fuel from Waste Plastics by Sequential Pyrolysis and Catalytic Reforming Processes over Indonesian Natural Zeolite Catalysts Mochamad Syamsiro; Shuo Cheng; Wu Hu; Harwin Saptoadi; Nosal Nugroho Pratama; Wega Trisunaryanti; Kunio Yoshikawa
Waste Technology Vol 2, No 2 (2014)
Publisher : Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (462.88 KB) | DOI: 10.14710/2.2.44-51

Abstract

In this study, the performance of several differently treated natural zeolites in a sequential pyrolysis and catalytic reforming of plastic materials i.e. polypropylene (PP) and polystyrene (PS) were investigated. The experiments were carried out on two stage reactor using semi-batch system. The samples were degraded at 500°C in the pyrolysis reactor and then reformed at 450°C in the catalytic reformer. The results show that the mordenite-type natural zeolites could be used as efficient catalysts for the conversion of PP and PS into liquid and gaseous fuel. The treatment of natural zeolites in HCl solution showed an increase of the surface area and the Si/Al ratio while nickel impregnation increased the activity of catalyst. As a result, liquid product was reduced while gaseous product was increased. For PP, the fraction of gasoline (C5-C12) increased in the presence of catalysts. Natural zeolite catalysts could also be used to decrease the heavy oil fraction (>C20). The gaseous products were found that propene was dominated in all conditions. For PS, propane and propene were the main components of gases in the presence of nickel impregnated natural zeolite catalyst. Propene was dominated in pyrolysis over natural zeolite catalyst. The high quality of gaseous product can be used as a fuel either for driving gas engines or for dual-fuel diesel engine.
Co-Authors Abdulloh Badruzzaman Ade Setiawan Agus Mulyono Agus Prasetya Agus Prasetya Agus Prasetya Ahmad Jamaludhin Al Muafi Sandono Andika Andika Anugrah K Pamosoaji Anwar, Nurcaya Putra Arip Nur Hadiyanto Bakhtiyor Nakhshiniev Bayu Megaprastio Bayu Megaprastio Bayu Megaprastio Bisrul Hapis Tambunan Bisrul Hapis Tambunan, Bisrul Hapis Cahya Tresna Pradana Chinnathan Areeprasert Didik Nurhadiyanto Djoko Budiyanto Setyohadi Eko Subandono Erni Umi Hasanah Fadmi Rina Fredy Surahmanto Fumitake Takahashi Haris Riswanto Hariyanti, Kristiana Harwin Saptoadi Harwin Saptoadi Hasanah, Erni Ummi Herlambang, Bagas Hermawan Prasetyanto Heru Setiawan, Heru Setiawan Huda, M Okta Rachman Hudi Baitul Fajri Ika, Siti Rochmah Irvan Irvan Irwan Novianto Joko Winarno Joko Winarno Juriah Mulyanti Kunio Yoshikawa Laksana, Feri Febria Malik Khidir Maria Ratih Puspita Liestiono Megaprastio, Bayu Muchammad Ajhi Romadhon Muhammad Arief Saputro Muhammad Aziz Muhammad Azizi Muhammad Kunta Biddinika Muhammad Luk Marsakti Muhammad Noviansyah Aridito Muhammad Sigit Cahyono Mujiyono Mujiyono Nosal Nugroho Pratama Nugraha, Rizqi Arya Nur Azmi Ainul Bashir Nur Azmi Ainur Bashir Nurwiyanta Nurwiyanta Pamungkas, Lucki Putra Aji Prabandari, Anis Prabang Setyono Pratama, Dandy Hendra Rena Juwita Sari Retno Lantarsih Ricki Rafli Rico Setiono Bayu Saputra Rustam Asnawi Saptoadi, H. Saputro, Muhammad Arief Satria Pinandita Sawtipan, M Imam Septian Rico Hernawan Shuo Cheng Slamet . Srikandi Novianti Sudarja Sudarja, Sudarja Sukamta Sukamta Sukoco Sukoco Sutanto, Gatot Syahril Machmud Syamsul Ma’arif Tambunan, B H. Teguh Widodo Wahyudi, Danang Wega Trisunaryanti Wirantara, Rizky Wu Hu Zahrul Mufrodi Zulkhairi