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Graphene oxide synthesis from coconut fiber powder using triple superphosphate catalyst and its potency for secondary battery electrode Marcelinus Christwardana; Adhista Fania; Deni Shidqi Khaerudini
Journal of Bioresources and Environmental Sciences Vol 3, No 2 (2024): August 2024
Publisher : BIORE Scientia Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.61435/jbes.2024.19926

Abstract

Coconut fiber, considered an organic waste, emerges as a promising alternative carbon source for graphene oxide production—a material characterized by its conductive nature due to oxidation and the introduction of functional groups. The synthesis process involves carbonization with varied holding times (10, 20, and 30 minutes) and the utilization of Triple Superphosphate (TSP) and Ferrocene catalysts at concentrations of 10 wt.% and 20 wt.%. Subsequently, the sonication method is employed to enhance the electrical conductivity of graphene oxide post-carbonization. Notably, the electrical conductivity tests, conducted using a sourcemeter, revealed the optimum performance at 20 minutes of carbonization duration and a 20 wt.% TSP catalyst concentration, yielding an impressive electrical conductivity of 11,489.86 S/m. These findings underscore the significance of tailored parameters in optimizing graphene oxide synthesis for applications such as high-conductivity battery anodes.  
SIMULATION HEAT AFFECTED ZONE WELDING ON AISI 1045 STEEL USING MATLAB gunawan, hardi; Firdaus, Andi; Tarigan, Kontan; Azizi, M; Khaerudini, Deni Shidqi
Jurnal Teknik Mesin (Journal Of Mechanical Engineering) Vol 15, No 01 (2026)
Publisher : Universitas Mercu Buana

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22441/jtm.v15i01.27335

Abstract

Abstract--In this research, AISI 1045 steel plate test objects were welded using SMAW welding. Heat input simulation of the welding process (thermal simulation) by entering the highest temperature of the heat distribution is carried out on a 140 x 140 mm plate with a thickness of 4 mm made of AISI 1045 steel. Initially, the plate has temperature limits of 700 °C, 500 °C, above 1300 °C, and below 0 °C. The bottom side of the plate is protected with constant temperature. The test object is then described using numerical methods using the MATLAB program. In this research, we can use MATLAB to develop a mathematical and numerical model that reflects the effect of the heat affected zone (HAZ) on the mechanical quality of AISI 1045. This model helps in the understanding of how the heat input provided from the welding process influences the mechanical material properties and allows us to optimize the influence of the process to obtain the desired results. Calculations carried out using the MATLAB application obtained results in the 9th iteration for errors <1%, namely 0.4681%. Large heat input results in low tensile strength, this shows that the welded joint with the electrodes used and the given welding parameters produced good joint strength.
Pengaruh Perlakuan Asam Hidrofluorat terhadap Kandungan SiO₂ dan Al₂O₃ dalam Red Mud untuk Meningkatkan Kadar Fe₂O₃ Nafisah, Sayyidatun; Hidayat, Arif; Khaerudini, Deni Shidqi
INDONESIAN JOURNAL OF CHEMICAL RESEARCH Vol. 10 No. 2 (2025): Volume 10, ISSUE 2, 2025
Publisher : Chemistry Department, Universitas Islam Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20885/ijcr.vol10.iss2.art1

Abstract

Red mud is a solid waste generated from the Bayer process that contains valuable metals such as Fe₂O₃, Al₂O₃, SiO₂, and TiO₂. However, to optimize red mud as an iron source, the high content of silica and alumina must be reduced, as these impurities can lower the efficiency of iron processing. This study aims to evaluate the leaching of red mud using 100 mL of 6.5 M hydrofluoric acid (HF), with variations in red mud mass (10, 20, 25 g) and stirring time (1 to 6 hours), to produce iron-rich residue. XRF analysis showed an increase in Fe₂O₃ content up to 44.65% in the 25 g sample after 6 hours. Al₂O₃ content consistently decreased, while SiO₂ decreased to 20.23% after 4 hours. XRD results revealed that the dominant phases in the residue were hematite, magnetite, and goethite, while silica and alumina phases were diminished. The optimal condition was achieved with 25 g of red mud and 4 hours of reaction time, resulting in high Fe₂O₃ content and low impurities. ICP-MS analysis of the leachate showed increasing Si and Al concentrations with longer reaction times, indicating HF selectively dissolved both elements. The novelty of this research lies in the use of HF to selectively dissolve Si and Al without affecting iron, yielding a residue with potential use as a precursor for magnetite or other iron-based materials. This method effectively reduces impurities and enhances residue quality, supporting sustainable red mud processing and circular economy initiatives.
PENINGKATAN KANDUNGAN BESI PADA LIMBAH PERTAMBANGAN BAUKSIT (RED MUD) DENGAN METODE ACID LEACHING MENGGUNAKAN LARUTAN ASAM FLUORIDA Nafisah, Sayyidatun; Khaerudini, Deni Shidqi; Hidayat, Arif
Jurnal Inovasi Teknik Kimia Vol. 10 No. 4 (2025): October| INTEKA - Jurnal Inovasi Teknik Kimia
Publisher : Fakultas Teknik Universitas Wahid Hasyim

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31942/inteka.v10i4.14296

Abstract

Red mud merupakan limbah padat hasil samping industri pengolahan bauksit melalui proses Bayer yang mengandung besi dalam jumlah tinggi, namun bercampur dengan berbagai oksida logam. Penelitian ini bertujuan untuk meningkatkan kandungan besi dalam red mud melalui metode acid leaching menggunakan larutan asam fluorida (HF). Proses leaching dilakukan dalam sistem refluks dengan variasi waktu (1–4 jam) dan konsentrasi asam (12–48%), kemudian residu dianalisis menggunakan X-Ray Fluorescence (XRF) untuk mengetahui perubahan komposisi. Hasil penelitian menunjukkan bahwa peningkatan waktu dan konsentrasi larutan asam mampu memperkaya kandungan Fe₂O₃ dalam residu, dengan nilai maksimum sebesar 45,91% pada kondisi 48% HF dan waktu leaching 4 jam.
Co-Authors Abdul Hamid Budiman Abu Bakar, Afarulrazi Ade Utami Hapsari Adhista Fania Adnan, Farrah Anis Fazliatun Afarulrazi Abu Bakar Aghni Ulma Saudi Agustanhakri, Agustanhakri Ahmad, Faozan Aiman Sajidah Abd Aziz Akhiruddin Maddu Andhika Prima Prasetyo Andi Firdaus Sudarma Andrameda, Yurian Ariandi Anggito Pringgo Tetuko Annisa Azzahra Arif Hidayat Arif Tjahjono Arif Tjahjono Arif Tjahjono Asadullah, Masud Azizi, M Azizi, Muhammad Bambang Mulyanto Bambang Mulyanto Chollacoop, Nuwong Dafit Feriyanto Damisih Damisih Damisih, Damisih Damsyik, Akhmad Dani Tri Wahyudi Dani Tri Wahyudi Desi Fajarwati Destyorini, Fredina Dianta Ginting Djajadiwinata, Eldwin Dwi Pudjisusilo, Raden Edy Herianto Majlan F. Adany Fajar Arif Kurniawan Fira Rizky Firdaus, Andi Fitri Suryani Arsyad Fredina Destyorini Friliandita, Vivi Gea, Markus Gerald Ensang Timuda Gumelar, Muhammad Dikdik Hanif Yuliani Hapsari, Ade Utami Hardhienata, Hendradi Hardi Gunawan Hardiansyah, Andri Henry Widodo Husin, Saddam Ilham Nur Dimas Yahya Indayaningsih, Nanik Indri Susanti Indriyati Indriyati Iqbal, Rendy Muhamad Irmawati, Yuyun Isnaeni Isnaeni Jarot Raharjo Jarot Raharjo Kurniawan Kurniawan Lukman Faris Nurdiyansah Marcelinus Christwardana Mardiyati, Mardiyati Masno Ginting Muhamad Fitri Muljadi Muljadi Muljadi Muljadi Nada Hashida Lathifah Nafisah, Sayyidatun Nanik Indayaningsih Nisya Ulmiah Nofrijon Sofyan, Nofrijon Nono Darsono Nono Darsono, Nono Octaviani, Ana Nur Oka Pradipta Arjasa Oka Pradipta Arjasa Oktaviani, Ana Nur Pandriana, Aap Perdamean Sebayang Permono Adi Putro Pratama, Wisnu Pravitasari, Retna Deca Pudjiwati, Sri Putra, Yunata Mandala Retna Deca Pravitasari Retno Agnestisia Riandy Putra Rifai, Abdulloh Rike Yudianti Robi Suherman Sabilly Handi Pradana Safaat, Mukhtar Sagir Alva Sanusi, Yasa Saptari, Sitti Ahmiatri Saputra, Dita Adi Saudi, Aghni Ulma Simanjutak, Elfrida Roulina Simarmata, Sari Namarito Sinaga, Tiara Cristy Sinaga, Tiara Cristy Agatha Slamet Priyono SRI RAHAYU Susilo, R Dwi Pudji Taqwatomo, Galih Tarigan, Kontan Tasomara, Riesma Teguh Imam Prasetya Tommy Martin Syauta Triyanto Pangaribowo Vivi Friliandita Wahyu Mulyo Utomo Wahyu Mulyo Utomo Wahyu Tri Utami Wahyudi, Dani Tri Widodo, Aditya Putra Widodo, Henry Wulandari, Ika Octavia Yuliani, Hanif Yuyun Irmawati Yuyun Irmawati