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Sintesis dan Aplikasi SiO2 dari Daun Bambu Wulung (Gigantochloa atroviolacea) sebagai Pengemban Fotokatalis untuk Degradasi Pewarna Congo Red Sri Budiasih, Kun; Kolonial Prodjosantosa, Anti; Utomo, M. Pranjoto; Christyan, T.
Jurnal Sains Dasar Vol 8, No 1 (2019): April 2019
Publisher : Faculty of Mathematics and Natural Science, Universitas Negeri Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21831/jsd.v8i1.38665

Abstract

Penelitian ini bertujuan untukmensintesis nanosilika dari daun bambu dan mengaplikasikannya sebagai pengemban fotokatalis CuO (0,25% CuOx@SiO2) pada reaksi degradasi congo red. Senyawa SiO2 dihasilkan dari abu daun bambu wulung (Gigantochloa atroviolacea) melalui proses kalsinasi pada suhu 800°C selama 6 jam. Senyawa 0,25% CuOx@SiO2 yang dihasilkan selanjutnya dikarakterisasi dengan UV-Vis diffuse reflectance spectra dan uji aktivitas adsorbsinya pada keadaan gelap, dilanjutkan uji aktivitas fotodegradasi larutan pewarna congo red pada sinar UV dan sinar tampak. Analisis Diffraksi sinar X menunjukkan senyawa SiO2 yang bersifat kristalin yang ditandai dengan puncak tajam pada 2Ø=21,87 (sesuai dengan JCPDS PDF No. 39-1425). Analisis UV-Vis diffuse reflectance menunjukkan bahwa energi celah pita senyawa 0,25% CuOx@SiO2 adalah 4,269 eV. Aktivitas adsorbsi sampel mengikuti pola isoterm adsorbsi Freundlich dengan nilai kapasitas adsorbsi 2011,731425 mol/gram. Aktivitas fotokatalitiknya terhadap degradasi congo red pada sinar UV dan sinar tampak mengikuti laju reaksi orde dua dengan nilai laju reaksi 0, 010464.C2 pada sinar UV dan 0.010481.C2 pada sinar tampak.
PENGEMBANGAN MEDIA PEMBELAJARAN BERBASIS PROGRAM DIRECTOR MX PADA PEMBELAJARAN TOPIK KIMIA INTI DAN RADIOKIMIA Marfuatun, Siti Marwati, dan Kun Sri Budiasih
Jurnal Cakrawala Pendidikan No 2 (2012): CAKRAWALA PENDIDIKAN EDISI Juni 2012, Th. XXXI, No. 2
Publisher : LPMPP Universitas Negeri Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (139.118 KB) | DOI: 10.21831/cp.v5i2.1561

Abstract

Abstrak: Pengembangan Media Pembelajaran Berbasis Program Director MX pada Pembelajaran Topik Kimia Inti dan Radiokimia. Penelitian ini bertujuan untuk mendeskripsikan cara pembuatan media pembelajaran menggunakan director MX dan efektifitas penggunaan media tersebut untuk mengajarkan topik Produk akhir penelitian pengembangan ini adalah media pembelajaran dalam bentuk CD. Proses pengembangan media pembelajaran berbasis program Director MX terdiri atas kegiatan pengumpulan referensi, penginstalan program, penciptaan media, evaluasi reviewer, revisi, aplikasi, dan evaluasi. Hasil penelitian menunjukkan bahwa kualitas media termasuk bagus. Di samping itu, penerapan media efektif untuk meningkatkan motivasi dan hasil belajar mereka. Kata Kunci : media, director MX, efektivitas, pembelajaran berbasis program, kualitas pembelajaran Abstract: Developing a Director MX Program-Based Learning Media to Improve the Learning Quality of Nuclear Chemistry and Radiochemistry Topics. This research was aimed to describe how to develop a learning media using director MX and examine the effectiveness of this media for Nuclear Chemistry and Radiochemistry topics. The final product of this research development was a compact disc (CD) learning media. The process to develop a director MX program-based learning media consisted of collecting references, installing the program, creating media, reviewer’s evaluation, revision, application and evaluation. This study concluded that the quality of media was good. Furthermore, the application of media is effective to improve students’ motivation and their learning achievement. Keywords: media, Director MX, effectivity, program-based teaching
An Application of Digital Chemistry Telling (DCT) in the Basic Inorganic Chemistry Course to Improve Students’ Listening and Speaking Skills Dyah Purwaningsih; Hari Sutrisno; Kun Sri Budiasih
JOURNAL OF EDUCATION Vol 4, No 01: November 2011
Publisher : LPPM UNY

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (6871.789 KB)

Abstract

This study aims to design implementation strategies of DCT in the Basic Inorganic Chemistry course, develop an appropriate course to increase students’ active participation, and develop an evaluation system capable of providing an integrated assessment (both the learning process and outcomes) in the course. This study was conducted in two cycles for one semester during the academic year of 2008/2009. The implementation applied the principles of classroom action research consisting of four stages, i.e. planning, action implementation, observation, and reflection. The data were analyzed by grouping them into categories. The findings were as follows. Qualitatively, the classroom obser­vations showed an increasing active participation of students, both in making the DCT and in conducting discussions in English. Quantitatively, the results of the observations on the learning activities showed an average value of 4 (scale 1-5) for several aspects of DCT.
NITROGEN ADSORPTION OF URINE WITH ZEOLITE M.Pranjoto Utomo; Endang Widjajanti; Kun Sri Budiasih
Jurnal Penelitian Saintek Vol 15, No 1: April 2010
Publisher : Institute of Research and Community Services, Universitas Negeri Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (6368.514 KB) | DOI: 10.21831/jps.v15i1.19168

Abstract

Tlte aints of the research v,ere to determine the nitrogen contained in humatt ttrine before and after ipplying zealyte ancl  to determine the influence o.f MgO to nitrog'n contained in human urine. The tJetermination ofZeolyte aclsorptio  capacity' to nitrogen contained in htrmqn trrine inclLtcled 3 s'teps. Activation ol' nature zeolf ie'nitrogen adsorptiort' Iotal nin"ogen determination Ly Kjeclahl test. Zeolyte activation wqs done by soaking zeollte itio0' 1 14 HCl, HNO: and H2soafor I hour and calcin(ltedJbr t hours at 100"c. The  adsorption proses  adding  y,as  clone byaicting inactivated ancl activated zeolyte tuithand without MgOThe iptimunt mass of zeolyte was 3 grants. The adsorption capacities oJ' inactivated zeolytes u,ithoutAnd with LttgO adcting were 0.00780994 and 0.0102% pq grdm zeolyte, respectivety. The adsorptionCapacities of activated zeoll'te by HCl, HNO: dan H:SO| wiihout Mgo addingw)re 0.00i01%,0.006610.4, and  0a0917?i,  per gram:eolil'te. Lhe adsorption capacities of activated zeolyle by HCl, HNO j dan H2SO| v'i* )IgO udding were 0.00839%,0.0i01%  dan 0.011% per gram zeoll'te. The activation and lulgO adr)ing increasecl the aclsorption capacitl' oJ' zeolyte to nitrogen contained in httman urine.
EFFECT OF RATIO VARIATION Mg / AL IN SYNTHESIS OF HYDROTALSIT WITH HYDROTHERMAL COPRECIPITATION METHOD Sri Handayani; Cahyorini Kusumawardani; Kun Sri Budiasih
Jurnal Penelitian Saintek Vol 19, No 1: April 2014
Publisher : Institute of Research and Community Services, Universitas Negeri Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1654.376 KB) | DOI: 10.21831/jps.v19i1.2333

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Catalyst are divided into two kinds, homogeneous and heterogeneous catalysts. The catalys tthat constantly developed isa heterogeneous catalyst because could  be separated easily and reuseable. The purpose of this research were synthesis and characterization of hydrotalcite Mg/Al as a heterogeneous catalyst which can be use din the aldol condensation reaction. Synthesis hydrotalcite was conducted by hydrothermal coprecipitation method. Synthesis performed with variations mol Mg/Alat a temperature hydrothermal 1000C for 15 hours. Hydrotalcite as a heterogeneouscatalyst preparation was done by calcinationat 4000C. Characterization of synthesized hydrotalcyte was performed by FTIR to identified functional group and XRD analysis to characteriz edits structure. The results showed that the optimum conditions for the synthesized hydrotalcite was obtained atmole ratio Mg/Al3:1.   
THE DEVELOPMENT OF STANDARDIZATION NATURAL COLOUR FROM BATIK OF STEAM BARK (Caesalpinia sappan L) BY SPECTROSCOPHY METHOD Arum Restu Widyasti; Astuti Lestari; Khoirul Amri; Fakhrizal Naufal; Kun Sri Budiasih
Jurnal Penelitian Saintek Vol 22, No 1: April 2017
Publisher : Institute of Research and Community Services, Universitas Negeri Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (452.976 KB) | DOI: 10.21831/jps.v22i1.14850

Abstract

The purpose of this research is to obtain a method of color standardization which is a consistent assessment of the color formed by secang natural dye, so it can be used as a reference color of natural dyes of batik.Standardization steps of natural dyes included taxonomic examination, preparation of secang dye by extraction, standardization process by spectroscopic measurement, with “rapid” dye as standard, application on batik process including batik pattern making and wax application on batik  and batik coloring process with secang dye. Data was analized by absorbance vs wavelength obtained from red color formed by secang dye. The results showed that the maximum absorption wavelength of the standard red color was obtained at 450.20 nm. This value is used as the standard red color measurement 
INFLUENCE OF CALCULATION TEMPERATURE TO HIDROTALSIT Mg / Al WHICH IS DISINTESTED THROUGH UNSECUAL METHOD OF PRESIPITATION Hasan Adidarma; Sri Handayani; Cahyorini Kusumawardani; Kun Sri Budiasih
Jurnal Penelitian Saintek Vol 19, No 2: Oktober 2014
Publisher : Institute of Research and Community Services, Universitas Negeri Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (482.687 KB) | DOI: 10.21831/jps.v19i2.3502

Abstract

This research aims to determine the effect of calcination temperature variation from 200°C to 500°C on the Mg/Al hydrotalcite structure. Mg/Al hydrotalcite has been synthesized via a low supersarturated precipitation method with hydrothermal treatment, using Mg(NO3 )2 .6H2 O and Al(NO3 )3 .9H2 O as the raw materials, and base solution of NaOH and Na2 CO3 as the precipitators. Mg/Al hydrotalcite compound synthesized before and after calcination were characterized using fourier transform infrared (FTIR) and X-ray diffractometer (XRD). The results of FTIR and XRD data analysis showed that the calcination of hydrotalcite of Mg/Al at 200o C did not changed the structure of hydrotalcite compounds, calcination at temperatures 300-400o C showed that structure of hydrotalcite compound starts to change form a mixture of magnesium oxide and aluminum, and calcination at 500°C showed that the crystal structure of Mg/Al hydrotalcite has broken to form a mixture of metal oxides, namely MgO (phericlase) with a little mixture of aluminum oxide in the form of θ-Al2O3 and γ-Al2O3.
Penentuan Efisiensi Immobilisasi Kromium (VI) Pada Geopolimer Abu Sekam Padi Dengan Uji TCLP (Toxicity Characteristic Leaching Procedure) Kun Sri Budiasih
EKSAKTA: Journal of Sciences and Data Analysis VOLUME 12, ISSUE 1, February 2011
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

This research aimed  to determine  the efficiency of immobilization of Cr(VI) on  the rice husk  ash  based  geopolymer with  a TCLP  (Toxicity Characteristic  Leaching Procedure)  study. The TCLP was    refer  to  the  standard method  from  Japan  Environmental  Agency. There were three  variables  used  i.e.,    concentration  of Cr(VI)  impregnated,  particles  size,  and  the  kind  of leaching  water. Determination  of  immobilization  efficiency  was  done  by  calculate  the concentration  of  Cr(VI)  in  the  leachate  water  after    the  leaching  processes.    Quantitative measurement of the chromium was done by Uv-Vis spectrometer with biphenyl carbazid  reagent. Immobilization of Cr(VI) on the rice husk ash based  geopolymer was establish until 25 ppm Cr impregnated. The efficiency of the immobilization can reach 90% - almost 100% depend on the variable of leaching processes.   Keywords: eficiency, immobilization, geopolimer, rice husk ash, TCLP study
Synthesis of Mg/Al Hydrotalcite by Using Low Supersaturated Precipitation Method with Variation of Mole Ratio Christanty Wahyu Septyaningrum; Sri Handayani; Cahyorini Kusumawardani; Kun Sri Budiasih
EKSAKTA: Journal of Sciences and Data Analysis VOLUME 14, ISSUE 2, August 2014
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20885/eksakta.vol14.iss2.art1

Abstract

This research aims to synthesize Mg/Al hydrotalcite with mole ratio variations of Mg/Al precursor through low supersaturated precipitation method. Mg/Al hydrotalcite was synthesized with Mg/Al mole ratio variation of 1:1, 2:1, 3:1, and 4:1. Mg/Al hydrotalcite was synthesized using NaOH and Na2CO3 base solutions. The mixture of precursor was stirred for 2 hours then treated by hydrothermal at 100 °C for 4 hours. Results of the synthesis Mg/Al hydrotalcite with mole ratio variations is a white powder. The formation of the structure of Mg/Al hydrotalcite showed by certain peaks in the FTIR spectra and XRD diffractogram.The results of data analysisshowed that variation of mole ratio Mg/Alcauses a shift of peak in the XRD diffractogram shifted towards the left along with a comparative increase in mole ratio Mg/Al, but the main functional groups on the compound Mg/Al hydrotalcite increasingly formed with better.
Penyuluhan Dan Pelatihan Teknologi Pemanfaatan Tanaman Obat Berbasis Kearifan Dan Sumber Daya Alam Lokal Untuk Perbaikan Tingkat Kesehatan Masyarakat Desa Karangsari Wedomartani Sleman Sri Handayani; Sri Atun; Nurfina Aznam; Kun Sri Budiasih
Jurnal Pengabdian Masyarakat MIPA dan Pendidikan MIPA Vol 1, No 1 (2017)
Publisher : Yogyakarta State University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (62.573 KB) | DOI: 10.21831/jpmmp.v1i1.12964

Abstract

Program Pengabdian kepada Masyarakat ini bertujuan untuk memberikan penyuluhan dan pelatihan teknologi pemanfaatan tanaman obat berbasis kearifan dan sumber daya alam lokal untuk perbaikan tingkat kesehatan masyarakat desa karangsari wedomartani Sleman. Pada akhirnya kegiatan ini akan memberikan wawasan, pengetahuan, kemampuan, dan keterampilan kepada warga terutama para remaja dan  ibu –ibu dalam memanfaatkan bahan alam di lingkungan sekitar sebagai minuman kesehatan. Kegiatan ini dilaksanakan pada tanggal 7 Agustus 2016 dengan peserta kegiatan adalah remaja dan ibu-ibu PKK desa Wedomartani Sleman. Kegiatan ini diawali dengan analisis permasalahan di lapangan, diikuti oleh persiapan rancangan  pelaksanaan program, pelatihan dan sosialisasi program yang dilengkapi alat dan bahan serta sarana dan prasarana penunjang kegiatan. Kegiatan diakhiri dengan sosialisasi serta pengarahan pembuatan minuman kesehatan berbasis sumber daya alam local.Hasil kegiatan ini menunjukkan bahwa 100% para peserta pelatihan merasakan bahwa kegiatan ini bermanfaat dan memiliki kemauan yang kuat untuk belajar hal baru. Dengan pelatihan yang berkelanjutan,diharapkan peserta memiliki pengetahuan dan keterampilan yang dapat digunakan untuk meningkatkan kualitas hidup bahkan menunjang kebutuhan ekonomi. Kata kunci: Tanaman obat, sumber daya alam local