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Pengaruh Variasi Polivinilpirolidon (PVP) Terhadap Pembentukan Serat Nano TiO2 Menggunakan Metode Electrospinning Vega Rahmawati Ar; Posman Manurung; Junaidi Junaidi; Pulung Karo Karo
Journal of Energy, Material, and Instrumentation Technology Vol 2 No 1 (2021): Journal of Energy, Material, and Instrumentation Technology
Publisher : Departement of Physics, Faculty of Mathematics and Natural Sciences, University of Lampung

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (544.33 KB) | DOI: 10.23960/jemit.v2i1.49

Abstract

Research on the formation of TiO2 nanofiber has been carried out with PVP variations of 1.1; 1,2; 1.3; 1.4 and 1.5 grams using electrospinning. This study aims to determine the effect of PVP variation on the viscosity and morphology of TiO2 nanofibers and to determine the crystal structure of the fibers. Synthesis of TiO2 was carried out using the sol-gel method. TTIP is used as a precursor, ethanol as a solvent, acetic acid as a catalyst and PVP as a fiber-forming polymer. The results of the viscosity measurement show that the amount of PVP used in the sample is directly proportional to the level of solution viscosity. Based on the results of SEM characterization, it showed relatively uniform nanofiber morphology with fiber diameter ranging from 94 nm - 735 µm. The results of TEM characterization showed that the size of TiO2 nanofiber particles ranged from 7-15 nm. The results of XRD analysis showed that the crystal structures formed at a calcination temperature of 450 oC were the anatase and rutile phases.
Perhitungan Burn Up Model Assembly Heksagonal pada Reaktor SCWR Menggunakan Bahan Bakarr Thorium Mey Puji Astuti; Yanti Yulianti; Posman Manurung; Simon Sembiring
Journal of Energy, Material, and Instrumentation Technology Vol 3 No 1 (2022): Journal of Energy, Material, and Instrumentation Technology
Publisher : Departement of Physics, Faculty of Mathematics and Natural Sciences, University of Lampung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23960/jemit.v3i1.85

Abstract

The research about the calculation of burn-up model of the hexagonal assembly in SCWR reactor using thorium as fuel materials has been done. This research uses thorium-232 and uranium-233 as fuel materials. Calculations were performed using the ASMBURN code in the SRAC program, by determining fuel enrichment, cell radius, analyzing atomic density after burn up, increasing burn up level, and change of linear heat. The calculation results obtained show the value of efficient fuel enrichment at 4% enrichment, with 0.3902 cm of fuel cell radius, 0.4508 cm of cladding, and 0.5586 cm of moderator. The atomic density of Th232 decreased for each burn-up period meanwhile, the atomic density of U233, U235, and Pu239 increased. The keff value will decrease along with the addition of burn-up and greater change of linear heat.
Pengaruh Laju Penambahan Doping Fosfor terhadap Aktivitas Fotokatalis Nanotitania Menggunakan Metode Sol Gel Yunita Yunita; Posman Manurung; Agus Riyanto
Journal of Energy, Material, and Instrumentation Technology Vol 2 No 2 (2021): Journal of Energy, Material, and Instrumentation Technology
Publisher : Departement of Physics, Faculty of Mathematics and Natural Sciences, University of Lampung

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Abstract

Pengaruh Waktu Penambahan Doping Sulfur terhadap Luas Permukaan dan Struktur Kristal Nanotitania Menggunakan Metode Sol Gel Anggi Puspita Dewi; Posman Manurung; Syafriadi Syafriadi
Journal of Energy, Material, and Instrumentation Technology Vol 2 No 2 (2021): Journal of Energy, Material, and Instrumentation Technology
Publisher : Departement of Physics, Faculty of Mathematics and Natural Sciences, University of Lampung

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Abstract

Sintesis titania doping sulfur (S-TiO2) dilakukan melalui metode sol-gel. Titanium isopropoksida (TTIP), tween-80, isopropanol dan asam sulfat (H2SO4) sebagai sumber doping sulfur digunakan sebagai bahan utama. Penelitian ini bertujuan untuk mengetahui pengaruh variasi waktu penambahan doping sulfur selama 0, 30, 60, 90 dan 120 menit menggunakan pompa injeksi terhadap pembentukan struktur kristal dan luas permukaan. Serbuk titania dikalsinasi pada suhu 450 oC selama 5 jam. S-doping TiO2 dikarakterisasi menggunakan x-ray diffraction (XRD) dan surface area analyzer (SAA). Hasil pengujian XRD menunjukkan bahwa fasa yang diperoleh yaitu fasa anatase untuk semua sampel sedangkan hasil dari SAA menunjukkan bahwa pada sampel S-02 memperoleh nilai luas permukaan 95, 310 m2/g dan hasil perhitungan ukuran partikel sampel S-02 memperoleh nilai sebesar 10,17 nm hal ini sesuai dengan teori dimana, semakin kecil ukuran partikel yang diperoleh maka luas permukaanya akan semakin besar.
Pengaruh Laju Penambahan Doping Fosfor terhadap Struktur Kristal dan Luas Permukaan Spesifik Nanotitania dengan Metode Sol Gel Vidi Nurhidayah; Posman Manurung; Ediman Ginting
Journal of Energy, Material, and Instrumentation Technology Vol 2 No 2 (2021): Journal of Energy, Material, and Instrumentation Technology
Publisher : Departement of Physics, Faculty of Mathematics and Natural Sciences, University of Lampung

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Abstract

Research on the effect of the addition phosphorus doping using a syringe pump with the sol-gel method. The purpose of this study was to determine the effect of the addition rate of phosphorus doping to the crystal structure and specific surface area of TiO2. Doping increment rate used are 0,4; 0,2; 0,13 and 0,1 ml/hours of TiO2 samples were calcined at 450ºC for 5 hours. The powder was characterized by x-ray diffraction (XRD) and surface area analyzer (SAA) by the BET method. XRD diffractogram generally shows that the nanotitania crystal structure phase is anatase which is the result of TTIP synthesis as the main source of TiO2. Particle size analysis using XRD data on TiO2 with different rates in a row that is 10.13; 9.98; 9.25 and 10.33 nm. BET test results for each sample were 86.954; 87,367; 99,694; 96,295 and 96,187 m2/g. The results of XRD characterization can affect the surface area, getting smaller the particle size, the greater surface area will be obtained.
Pengaruh Unsur Pemadu Mo dan Proses Fabrikasi Terhadap Kekerasan Plat Zirlo-Mo Yuant Tiandho; Posman Manurung; Futichah Futichah
Jurnal Teori dan Aplikasi Fisika Vol 1, No 1 (2013): Jurnal Teori dan Aplikasi Fisika
Publisher : Universitas Lampung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23960/jtaf.v1i1.482

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Paduan zirlo-Mo merupakan kandidat material kelongsong bahan bakar nuklir generasi baru. Penelitian ini dilakukan untuk mengetahui pengaruh penambahan Mo dan proses fabrikasi yang dilakukan terhadap kekerasan plat zirlo-Mo. Zirlo-Mo yang dibuat memiliki komposisi Zr-1%Sn-1%Nb-0,1%Fe dengan variasi Mo sebesar 0,3%; 0,4%; dan 0,5%. Fabrikasi yang dilakukan meliputi peleburan, β-quenching, pengerolan panas, anil 760°C, pengerolan dingin 1,5 mm, anil 650°C, pengerolan dingin 1 mm, serta anil 500°C. Melalui uji kekerasan dengan microhardness Vickers tester diketahui bahwa penambahan unsur pemadu Mo dapat meningkatkan kekerasan paduan zirlo-Mo. Proses fabrikasi memiliki pengaruh yang besar terhadap kekerasan zirlo-Mo. Peningkatan kekerasan dapat dicapai dengan melakukan proses β-quenching dan pengerolan. Sedangkan proses anil bersifat menurunkan kekerasan paduan. Kekerasan tertinggi dicapai pada proses rol panas untuk sampel ZM-0,5 dengan nilai kekerasan 3,6 GPa sedangkan kekerasan terendah dicapai pada ZM-0 pasca peleburan dengan nilai kekerasan 1,6 GPa. Kata Kunci: zircaloy, zirlo-Mo, β-quenching, pengerolan, anil, dan kekerasan.
Characteristics of Nanosize Spinel NixFe3-xO4 Prepared by Sol-Gel Method Using Egg White as Emulsifying Agent Rudy Situmeang; Sukma Wibowo; Wasinton Simanjuntak; R. Supryanto; Rizki Amalia; Mitra Septanto; Posman Manurung; Simon Sembiring
Indonesian Journal of Chemistry Vol 15, No 2 (2015)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (438.236 KB) | DOI: 10.22146/ijc.21204

Abstract

In this study, sol-gel method using egg white as emulsifying agent was applied to prepare nano size spinel NixFe3-xO4 (with x = 0.2–1). Sample preparation was carried out by mixing the solution of Fe(NO3)3.9 H2O and Ni(NO3)3.6 H2O with egg white, and then the sample was stirred thoroughly using magnetic stirrer. After freeze–drying process, the sample was subjected to calcination treatment and subsequently characterized. The phase composition was evaluated using the X-ray diffraction (XRD) technique, followed by quantitative analysis using Rietveld and Debye-Scherrer Methods. The functionality of the sample was identified using Fourier Transform Infrared (FTIR) spectroscopy, and surface morphology and elemental composition were analyzed using scanning electron microscopycoupled with electron dispersive spectroscopy (SEM/EDS). The results of XRD characterization indicated that materials consist of various crystalline phases, with NiFe2O4 as a major phase. FTIR Analysis revealed the existence of both Lewis and Brønsted–Lowry acid sites, with Lewis acid as the prominent site. The sample was found to display relatively homogeneous surface morphology, having the crystallite size in the range of 33 to 61 nm according to the Debye-Scherrer equation. The EDS data indicated that the ratio of Fe/Ni is in agreement with the composition of the raw materials used.
Synthesis and Characterization of Titania-Rice Husk Silica Composites as Photocatalyst Posman Manurung; Rudy Situmeang; Ediman Ginting; Indra Pardede
Indonesian Journal of Chemistry Vol 15, No 1 (2015)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (482.219 KB) | DOI: 10.22146/ijc.21221

Abstract

This article describes the synthesis of titania-silica composites by a sol-gel method using a mixture of silica of rice husk and titanium butoxide sols. Microstructures were examined at calcination temperature in the range of 500 to 700 °C, with temperatures interval of 50 °C. The sintered catalysts were subsequently tested for photodegradation of methylene blue (MB) under ultraviolet and sunlight rays. Physical characteristics were analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM)/energy dispersive X-ray spectroscopy (EDS), and Brunauer-Emmett-Teller (BET). The XRD results did not show the presence of silica crystal phase in each sample. The results showed that the highest BET surface area of samples was obtained at the temperature of 650 °C. In sample calcined 500 °C, the activity of the catalyst on MB was relatively similar in both sunlight and ultraviolet rays.
Efek NaOH pada Pembentukan Nano ZnO Metode Hidrotermal Rahma Fauza; Posman Manurung; Yanti Yulianti
Journal of Energy, Material, and Instrumentation Technology Vol 2 No 3 (2021): Journal of Energy, Material, and Instrumentation Technology
Publisher : Departement of Physics, Faculty of Mathematics and Natural Sciences, University of Lampung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23960/jemit.v2i3.146

Abstract

Hydrothermal methods have been developed for the manufacture of ZnO. This study aims to find out the effects of variation on the chemical composition and structure of nanoZnO, the nanoZnO phase formed and the nanoZnO particle size formed. The NaOH variation used is 1; 2; 3; and 4 grams. The characteristics used are X-Ray Diffactions (XRD) and Scanning Electron Microscopy (SEM). The XRD characterization results show that the diffraction peaks correspond to standard databases and show wurtzite phases with hexagon structures. The results of SEM characterization showed that the mean measurement of ZnO particles and the error value in the 1 gram variation was 67 ± 3 nm, while the 3 gram variation was 76 ± 6 nm.
Sintesis Nanotitania dengan Cara Hidrotermal sebagai Fungsi Suhu Sumiyati Sumiyati; Posman Manurung; Suprihatin Suprihatin
Journal of Energy, Material, and Instrumentation Technology Vol 2 No 4 (2021): Journal of Energy, Material, and Instrumentation Technology
Publisher : Departement of Physics, Faculty of Mathematics and Natural Sciences, University of Lampung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23960/jemit.v2i4.152

Abstract

Research has been carried out on the synthesis of nanotitania by hydrothermal as a function of temperature. The purpose of this study was to determine the effect of temperature on the phase formation, structure and particle size of TiO2 using the hydrothermal method with TiOSO4 as the main ingredient. In this study, using temperature variations of 150, 200, 250 and 300°C and samples were characterized using X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM). The phases formed are the anatase and rutile phases which have a tetragonal structure and the hilly phase with an orthorhombic structure. The rutile phase appeared predominantly in each sample and the sulfuric phase only appeared at 250ºC. The anatase phase obtains a particle size of 10-18 nm, where the higher the temperature, the bigger the particle size. Furthermore, the rutile phase obtained a particle size of 14-25 nm, where the higher the temperature, the smaller the particle size.
Co-Authors Abdurrahman, Ahmad Faruq Agnesia, Donna Agus Riyanto Agus Riyanto Agus Riyanto Agus Riyanto Agus Suyatna Ahmad Rosadi Alfin Edo Kaisar Lubis Amir Supriyanto Anggi Puspita Dewi Anggi Stevani Anggraini, Adeliya Ayu Anggraini, Anisyah Aprilia, Ayu Arya R. Syah Ayu Aprilia Benyamin, Chairunissa A Chandra Ertikanto Craig Buckley Delfi Oktavia Amrani Della M. Andini Dita Rahmayanti Dwi Asmi Ediman Ginting Ediman Ginting Ediman Ginting Suka Erika Sempana Ginting Fajar Nurjaman Faradilla Syani Fath, Yusril Al Fatia Ulfah Fegi Liani Firdaus, Iqbal Futichah Futichah Gregorius N. Susanto Gultom, Rysa Sonya Reni Paulin Hasni Handayani Imaniar Romaeni Indra Pardede Iqbal Firdaus It Meng Low Jayanti Pusvitasari Johar Sitohang Junaidi - Junaidi Junaidi Junaidi Junaidi Junaidi Junaidi Juniati Br Simbolon Karo Karo, Pulung Karo, Pulung Karo Ketut Putra Wijaya Lady Permatasari Lusi Vusfita Sari Maharani, Renita Marjunus, Ronius Marjunus, Roniyus Mega Pertiwi, Mega Mey Puji Astuti Miranti Syafitri Mitra Septanto Nabilah Rafidiyah Nadia Febriyanti Nita Susanti Nola Fricilia Nurcahayaniati, Hikmah Nurqori Setiawati Pauzi, Gurum Ahmad Pertiwi, Salwa Dian Prihanto, Surya Pulung Karo-Karo Putri, Faradilla Nabila R. Supryanto Rahayu, Sri Rahma Fauza Rahmayanti, Dita Renita Maharani Fauzi Rika Rahayu Riska Trisna Nuraini Riyanto, Agus Rizki Amalia Rudy Situmeang Rudy Situmeang Rudy T M Situmeang S Suprihatin Sahtoni Sahtoni Sari, Tria Permata Sembiring, Simon Sempana, Erika Shabrina, Shabrina Yakosati Simon Sembiring Simon Sembiring Simon Sembiring Simon Sembiring Siti Fadilah Sitohang, Rosanti sri wahyu suciayti Sri Wahyu Suciyati Sri Wahyu Suciyati Sukma Wibowo Sumardi . Sumardi, Sumardi Sumiyati Sumiyati Supardi Supardi Suprihatin Suprihatin Suprihatin Suprihatin Suprihatin Suprihatin Supriyanto, Amir Syafriadi Syafriadi Syafriadi Syafriadi Trianasari, Trianasari Vega Rahmawati Ar Vidi Nurhidayah Wasinton Simanjuntak Windhini Anggraeni Yanti Yulianti Yanti Yulianti Yanti Yulianti Yanti Yulianti Yanti Yulianti Yanti Yulianti Yuant Tiandho Yudhistira Novita Handayani Yunita Yunita Zaharani, Rethanita Zahra Maria Ulfa