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SINTESIS METIL ESTER DARI LIMBAH KELAPA SAWIT DENGAN SONOCHEMISTRY DAN CRACKING MENJADI BIOFUEL DENGAN KATALIS CrMo/HZ Jertadi Putri Dhani; Agus Sundaryono; Dewi Handayani
ALOTROP Vol 3, No 2 (2019)
Publisher : University of Bengkulu

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33369/atp.v3i2.10498

Abstract

This study aims to calculate the percentage methyl ester converted to biofuel through catalytic cracking reaction,analyzes component and determine characteristics using catalyst CrMo/HZ. This research begins with impregnation sample preparation which includes heating oil,degumming,bleaching and determination free fatty acid (FFA). Methyl ester obtained from liquid waste conversion crude palm oil through an esterification and transesterification reaction with H2SO4 and NaOH catalyst with sonochemistry methode is a method that utilizes ultrasonic waves origanating from a device is ultrasonic cleaner for one hour at temperature 60oC. The methyl ester obtained was cracked with a CrMo/HZ catalyst which was carried out for 2 hours at temperatur 380oC. To find out the components of compounds formed in methyl ester, an analysis was performed using GCMS then characteristics of biofuel are determined from the result of catalytic cracking obtained through acid number testing,density,viscosity,pour point and fog point. The result obtained from the conversion of methyl ester to biofuel with Crmo/HZ Catalyst Is 60,17% And For Testing The Physical Characteristics Of Biofuel Namely The Acid Number 1,87 Mg KOH/G, density 0,804 g/cm3, viscosity 1,162 Cst, pour point 0oC and fog point 1,4oC. The result of cracking produce a consituent component of biofuel namely gasoline 33,67%, kerosene 16,26%, gas oil 10,24% beside that, there are still methyl ester as much as21,89%.
AKTIVITAS FRAKSI ETANOL DARI EKSTRAK DAUN Peronema canescens TERHADAP TINGKAT PERTUMBUHAN Plasmodium berghei Dhea Prasiwi; Agus Sundaryono; Dewi Handayani
ALOTROP Vol 2, No 1 (2018)
Publisher : University of Bengkulu

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33369/atp.v2i1.4601

Abstract

 [THE ACTIVITY OF THE Peronema canescens LEAVES ETHANOL EXTRACTS FRACTION AGAINST Plasmodium berghei GROWTH RATE ] The purpose of this research was to identify the secondary metabolites of compounds contained in the fraction of ethanol from leaves of Peronema canescens (Sungkai) as well as to measure the level of activity of ethanol fraction antiplasmodium leaf P.canescens against the male mice (Mus musculus) infected with Plasmodium berghei which is parasitic hemaprotozoa that can cause malaria in rodents such as rats and mice as well as molecular similarity with the parasite Plasmodium. falciparum that causes malaria in humans. The methods used in this study i.e. in maceration extraction methods to attract secondary metabolite compounds from the leaves of P.canescens followed by oil bath method to get a fraction of ethanol with the purpose of separating polar compounds from a mixture of secondary metabolite compounds contained in the sample leaf P.canescens. Assay activity against antiplasmodium males mice infected with P. berghei is done by dividing into the 5 mice group treatment i.e. Group K (-) that are quads, group K (+) given kloroquin anti malarial drug, and P1, P2, P3, which each group was given a dose of ethanol fraction from leaves of P. canescens with each dose of 0.028 (P1); 0.056 (P2), and 0.0084 g/kgBB (P3).The results of research conducted showed that administering ethanol fraction from leaves of P. canescens antimalarial activity can increase with very real on the best dose of kg BB 0084 g i.e. with the percentage inhibition of 54.06%.
PROFIL FITOKIMIA DAN PENGARUH EKSTRAK TANGKAI DAUN TALAS KEMUMU (Colocasia gigantea Hook.f ) TERHADAP JUMLAH LEUKOSIT Mus musculus Rofiqa Asri; Dewi Handayani; Agus Sundaryono
ALOTROP Vol 3, No 1 (2019)
Publisher : University of Bengkulu

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33369/atp.v3i1.9038

Abstract

This research aims to identify secondary metabolite compounds in Talas kemumu leaf stalk (Colocasia gigantea Hook.f) and to determine the effect of extract on the number of male Mus musculus leukocytes that have been induced aspirin. Aspirin is used to increase the number of M.musculus leucocytes.The method used in this research is the method of extraction by maceration to attract secondary metabolites of active compounds  C.gigantea leaf stalk and the measurement of blood leukocyte counts are calculated using a hemocytometer (improved neubauer). Test of the effect of the leaf stalk of C.giganteaextract on the number leukocytes of M.musculus  was performed by dividing into 5 groups with 5 replications according to the Federer formula, namely K (-) were given distilled water, K (+) were given aspirin, P1, P2 and P3 are each given a dose of extract of  C.gigantea leaf stalk of 0,028 g/KgBB, 0,056 g/KgBB and 0,084 g/KgBB. The results showed that the identification of phytochemical profile in C.gigantea leaf stalk contains secondary metabolite compounds such as alkaloids, flavonoids, terpenoids, tannins and saponins. The results shows that giving of C.gigantea leaf stalk extract can reduce the number of leukocytes M.musculus which have induced aspirin. The giving of C.gigantea leaf stalk extract can decrease the number of aspirin-induced M.musculus leukocytes. This is evident from the results of One Way Anova analysis and the Smallest Real Difference Test (BNT) because in each treatment group has a significant influence. The effective dose that has the greatest activity in decreasing the number of M.musculus leukocytes found in the P1 treatment of 0,028 g /KgBB can decrease the blood leukocyte count by 6,830 / mm3.
UJI BIOFUEL HASIL PERENGKAHAN METIL ESTER DARI LIMBAH CAIR PABRIK MINYAK KELAPA SAWIT DENGAN KATALIS MoNi/HZ Dian Kartika Sari; Agus Sundaryono; Dewi Handayani
ALOTROP Vol 1, No 2 (2017)
Publisher : University of Bengkulu

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33369/atp.v1i2.3534

Abstract

[CONVERSION OF LIQUID WASTE OIL PALM OIL FACTORY BECOME BIOFUEL WITH MONi / HZ CATALYST] This study aims to produce biofuel from liquid waste oil PMKS with worditik cracking using catalystMoNi / HZ. This study involves the preparation of a catalyst performed by means of a separate impregnation, this impregnation lasting for 12 hours. The next stage of sample preparation includes heating, filtering, degumming, bleaching and ALB determination, followed by the production of methyl esters through esterification and transesterification processes. Then the obtained methyl ester was cracked using a catalyst for 2 hours at 380 °C and followed by distillation of the product for 2 hours at 380 °C, followed by distillation step at 380 °C to obtain methyl ester. The physical characteristics of biofuel resulting from the catalytic cracking reaction of the methyl ester using the MoNi / HZ catalyst of the PMKS wastewater include the acid number 1.92 mg KOH / g, density 0.803 g/cm3, kinematic viscosity 1,113 cSt, a pour poin of 0oC and fog poin at 1,43 oC. Biofuel resulting from catalytic cracking using this MoNi / HZ catalyst of very high biofuel acid numbers can be used in areas that have a cold climate. the biofuel viscosity of the experimental results has not matched the viscosity of gasoline or kerosene, so it can not be used as fuel equivalent to gasoline and kerosene with the composition of 100% biofuel density from biofuel is still slightly above gasoline and kerosene
Pembuatan Biofuel dari Limbah Cair PMKS dengan Katalis MoCo-HZ Tyas Sri Muryati; Agus Sundaryono; Dewi Handayani
ALOTROP Vol 2, No 2 (2018)
Publisher : University of Bengkulu

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33369/atp.v2i2.7486

Abstract

This research aims to convert vegetable oils contained in Palm Oil Mill waste (PMKS) into biofuels through the cracking process with MoCo-HZ catalyst . PMKS Liquid waste will be prepared with a process of a filtering, degumming, bleaching, warming, and free Fatty Acids determination.  The results obtained are then converted into biofuel with catalytic cracking with use of MoCo-HZ catalyst . Then the cracking products will to test for specified physical characteristics of biofuel eq : acid number , density, viscosity, pour point and cloud point. . The research results showed that the MoCo-HZ catalyst is able to convert vegetable oils contained in the PMKS liquid waste will be cracked into biofuel. Conversion yield obtained is amounting to 48.19%. The physical characteristics of the test results against biofuels produced from the cracking process has not met the standard of comparison from gasoline and kerosene. This is shown by the still high number of biofuel produced acids amounting to 1.72 mg KOH/gr. higher than the numbers of  sour gasoline (0.748 mg KOH/gr) and Kerosene (0.935 mg KOH/gr). The result of the test of density, viscosity, pour point and cloud point against biofuels produced from the cracking process have meet standard compared to gasoline and kerosene respectively 0.807 gr/cm for density, 1.056 cSt viscosity for viscosity , and 0 º C and 1.33 each º C to the freezing point and the cloud point..
UJI FRAKSI ETIL ASETAT DAUN Peronema canescens TERHADAP Plasmodium berghei PADA Mus musculus Fuji Ramadenti; Agus Sundaryono; Dewi Handayani
ALOTROP Vol 1, No 2 (2017)
Publisher : University of Bengkulu

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33369/atp.v1i2.3508

Abstract

[DETERMINATION OF ETHYL ACETATE FRACTION FROM Peronema canescens LEAF EXTRACT  AGAINST Plasmodium berghei  INFECTED  Mus musculus] This study was conducted to identify secondary metabolite compounds contained in ethanol extract and ethyl acetate fraction from Peronema canescens leaf (sungkai) and to measure the effect of ethyl acetate fraction on anti plasmodium  activity on Mus musculus infected by  Plasmodium berghei. The ethyl acetate extract was obtained by maceration of leaves with 96% ethanol solution in3 days followed by fractionation by ethyl acetate for further test. 25 of male white  M. musculus  with the weight 20-40 g and 6-8 weeks old , divided into 5 groups with 5 head / group. Groups 3, 4 and 5 are treated and groups 1 and 2 are controls. The negative control will be given food and drink only, and for positive control group will be given chloroquine with dose  0,028,  0,056, and  0,084 g / KgBW.  Development of levels of parasitemia were calculated by by observing a thin blood smear with giemsa staining under a microscope , observed until the parasitemia in the blood had reached 20-30% to be given a 3-day follow-up treatment, and then for the next 7 days after it was given treatment.. Anti-plasmodium activity test is determined by the number of parasitemia, percent growth and resistance of parasitemia in the blood. Data were analyzed by using one way anova method (? = 0,05 and 0,01). The results showed that the secondary metabolite compounds found in the ethyl acetate fraction of  P.canescens leaf, namely alkaloids, flavonoids, tannins and phenolics and at a dose of 0.056 g / KgBW  ethyl acetate fraction  can inhibit the growth of parasitemia in the blood of  M. musculus by 50 , 89% , with greater percentage of parasitemic inhibition compared with positive and negative control group.
Preparasi dan Karakterisasi Katalis Mo-Ni/HZ dengan Metode Impregnasi untuk Cracking Katalitik Minyak Limbah Cair Pengolahan Kelapa Sawit menjadi Bahan Bakar Nabati Shinta Lestari; Agus Sundaryono; Rina Elvia
ALOTROP Vol 3, No 1 (2019)
Publisher : University of Bengkulu

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33369/atp.v3i1.9047

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This study aims to determine the characteristics of Mo-Ni/HZ catalysts and test the ability of Mo-Ni/HZ catalysts in converting vegetable oils into biofuels through catalytic cracking reactions.Catalyst preparation is carried out by the impregnation method which begins with activation of natural zeolite.Impregnation is carried out by dissolution, reflux, filtration, drying and calcination.Catalyst characterization included the determination of the distribution of metals in zeolites using IR spectroscopic analysis and total acidity of the catalyst by ammonia adsorption gravimetric method.Preparation of samples prior to cracking is heating, degumming and bleaching.Catalytic cracking was carried out at 280oC using Mo-Ni/HZ catalyst for 100 minutes.The constituent components of the cracking results were analyzed by GC-MS and IR spectroscopy.The results obtained from the catalytic cracking process were then determined by physical characteristics which included density, viscosity, fog point and pour point test.Based on the shift of wave number in IR spectroscopy, it can be concluded that the Ni and Mo metals are embedded in the HZ.This Mo-Ni/HZ catalyst has total acidity of 8.39 mmol/gammonia.The results of the study prove that the Mo-Ni/HZ experiment proved to be able to crack oil frompalm oil processing wastewater by 91.46% to composition C=O ester CH aliphatic.The physical characteristics of cracking productshave parameters density of 0.93 g/cm3, a viscosity of 26.60 cSt, a fog point of 15oC and pour point of 11.67oC.
PENGEMBANGAN E-MODUL KIMIA BERBASIS METAKOGNISI MENGGUNAKAN APLIKASI EDMODO Shiba Meike Indira; Agus Sundaryono; Rina Elvia
ALOTROP Vol 4, No 1 (2020)
Publisher : University of Bengkulu

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33369/atp.v4i1.13707

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Metacognition is one of the factors that influence academic achievement, so it is very important in each student's learning activities. The objective of this research was to find out the level of feasibility and students response to E-chemistry-based metacognition using the edmodo application as teaching material to train students' knowledge and metacognition experience of students of the XI MIPA class of SMA Negeri 2 Kota Bengkulu T/P 2018/2019 on acid-base material. This research was an Research & Development (R&D) using the 4D development model limited to the development stage. The development of this emodule uses the edmodo application and in its using the flipped classroom learning model. Information worthy of being used as teaching of expert assessments and student responses to limited testing and field testing. The assessment of e-module was carried out by media experts, it was obtained that e-module is very feadible to use without revision with an evaluation percentage of 93%, an assessment by material experts and practitioners ( chemistry teacher) was very feasible to use without revision with an evaluation percentage of 92%, then the metacognition –based was assessed by material experts was obtained e- module was very feasible to use without revision with a percentage of 88% so that based on the results of expert evaluations, e-module could testedon a limited trial class and field trial. Sample selection in limited trials and field trials obtained from the results of normality tests conducted on january 3,2019 from the popuation of class XI Mipa A- XI Mipa F as many 190 students obtained 15 students XI Mipa C as samples ini limited trials and 31 students XI Mipa E in the field trial. Response of students in limited trials carried out on january 14,2019 and field tests on january 30,2019 amounting to 86% and 84% this shows that the use of emodules is very teasible to use as teaching materials and obtained information that e-module can train the ability of metacognition students of the XI MIPA SMA Negeri 2 Kota Bengkulu T/P 2018/2019 in particular the knowledge and metacognition experience of student from less trained to being trained.
KARAKTERISASI NANOPARTIKEL KITOSAN EKSTRAK DAUN UBIJALAR (Ipomoea batatas L.) MENGGUNAKAN METODE GELASI IONIK Ade Indriani Putri; Agus Sundaryono; I Nyoman Chandra
ALOTROP Vol 2, No 2 (2018)
Publisher : University of Bengkulu

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33369/atp.v2i2.7561

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The purpose of this study is to determine and measure the results of the characterization of Chitosan nanoparticle synthetized from leaves of sweet potato (Ipomoea batatas l.) extracts . The methods used to make nanoparticles is made with Ionic Gelation method based on electrostatic interaction between the Hydroxyl Amine on Chitosan with cluster of negative charge from the polianion NaTPP with conditioned surfactant Tween 80 used as surfactant. Characterization test of nanoparticle morphology in this study obtained using the Fourier Transformation  Infra Red (FTIR), and Particle Size Analyzer (PSA). Results with FTIR characterization test from the obtained Chitosan-white purple sweet potato leaf extract nanoparticles has a cluster of N-H and P = O that show the occurrence of ammonium ion interaction between Chitosan with polianion from NaTPP and sweet potato leaves. The interaction seen from wave number and intensities  O-H shifting from pure Chitosan at 3425.56 cm-1 to 3427, 51 cm-1, as well as on pure Chitosan N-H absorption  undergoes a shift from 1597, 06 cm-1 to becomes 1629.85-1 cm-1, which shows that there has been a cross connective between ammonium ion on Chitosan and Posphat from NaTPP and white purple sweet potato leaf extract. The results of the analysis from the PSA, is known to the average Nanokitosan particle sizes extracts from white purple sweet potato leaf extracts with the addition of NaTPP i.e. of 302.6 nm and that the aim of the research on Chitosan nanoparticle synthesis has been successfully done.
Implementation of Integrated Science Model With Audiovisual Teaching Materials To Improve Students’ Learning Outcomes and Science Process Skills Emilia Candrawati; Sumpono; Agus Sundaryono; Mellyta Uliyadari
IJORER : International Journal of Recent Educational Research Vol. 1 No. 2 (2020): July
Publisher : Faculty of Teacher Training and Education Muhammadiyah University of Makassar

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.46245/ijorer.v1i2.34

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This study aims to determine the effectiveness of the integrated science learning type connected to achieving basic competencies and improving science process skills. This study uses a 4-D development model that is defined, design, develop, and disseminate with one-group posttest design implemented in 5th-semester students of Chemistry Education, University of Bengkulu. The research instrument is a posttest question to measure learning outcomes and observation sheets to measure science process skills. The teaching materials used are sourced from part of the process and the results of the activity test of palm oil endophytic bacteria ethyl acetate extract against Fusarium oxysporum f.sp. by TLC-bioautography is packaged in the form of learning videos. The results showed that the Integrated Science type of Connected model was used effectively to improve student learning outcomes and science process skills.
Co-Authors ACENG RUYANI Ade Indriani Putri Alfia Novera Indah Esa Kasih Arina Fatharani Arsela Eko Listiono Bedah Rupaedah Bedah Rupaedah, Bedah Bhakti Karyadi Bhakti Karyadi BHAKTI KARYADI Bonodikun Bonodikun Candrawati, Emilia Candrawati, Emilia Chyntia Margareta Cici Romayanti Dapot Parulian Manurung Devi Silsia Dewi Handayani Dhea Prasiwi Dian Kartika Sari Eko Swistoro Elvinawati Elvinawati Emi Hartati Emilia Candrawati Emilia Candrawati Endang Widi Winarni Endang Widi Winarni Ernis, Gustria Euis Nursa’adah Fahrurrozi, Fahrurrozi Fenny Andriani Fitri Yuwita Fuji Ramadenti Hadi Apriyoanda Hadi Apriyonda Henny Johan Herison, Catur Hermansyah Amir I Nyoman Candra I Nyoman Chandra Ilham Agus Saputra Jertadi Putri Dhani Kirent Arikhsa Putri Krisandini, Triana Lina Widawati M Lutfi Firdaus M. Farid M. Lutfi Firdaus M. Lutfi Firdaus Maya Wahyunarti Mayshah Purnamasari Megasari Megasari Meizul Zuki Mellyta Uliyadari Mina Sihite Hutasoit Muchammad Farid Mukhsin Mukhsin Muzanip Alperi Nur Wakidatul Khasanah Nurhamidah Nurhamidah Nurhamidah Nurhamidah Nurhamidah Nurhamidah Nurleli Nurleli Nurlia Latifah Nursaa'adah, Euis Nursaadah, Euis Pandu Imam Sudibyo Adib Pandu Imam Sudibyo Adib Pramesthi Regita Putri Putri Suci Asriani Rantika Khumairah Rasie Janika Reni Jumika Ridwan Yahya Rika Partika Sari Rina Elvia Rina Elvia Rina Elvia, Rina Rina Endriani Ririn Trinanda Rofiqa Asri Sari Puspita Ningsih Shiba Meike Indira Shinta Lestari Sipriyadi Sri Astuti Sumpono Sumpono Sumpono Sumpono Sumpono, Sumpono Suryadi Suryadi Theo Kuntara Tuti Maryana Tyas Sri Muryati Ulfah Anis Umaya Umi kalsum Wuri Marsigit Yenni Okfrianti Yohannes Adimar Marbun Yulia Suparti Zulman Efendi