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EFFECT OF ZEOLITE 4A ON WATER CONCENTRATION IN THE SYSTEM OF THE ESTERIFICATION REACTION OF ACETIC ACID WITH 1-BUTANOL Ratna Dewi Kusumaningtyas
Indonesian Journal of Chemistry Vol 6, No 2 (2006)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (307.547 KB) | DOI: 10.22146/ijc.21748

Abstract

The usual problem encountered on a reversible reaction is that the reaction cannot achieve a complete conversion of reactants since it is limited by the thermodynamic equilibrium. Due to this low conversion, it will face challenges with product purification and recycling of the reactants, which then cause an increase in the operation cost. To obtain higher conversion, it is necessary to shift the equilibrium towards the products by continuously removing the water formed. One popular example of reversible reaction is esterification process. In this research, water removal was conducted through an adsorption process using zeolite 4A. Effect of zeolite 4A on water concentration in the liquid phase esterification of acetic acid and 1-butanol catalyzed by sulfuric acid was investigated. It was performed in an isothermal batch reactor. The molar ratio of 1-butanol - acetic acid was 1.4 times theoretically, the catalyst concentration was 1 % wt and the mixing intensity was 1000 rpm. The influence of the temperature was studied at 40 to 80 °C and the zeolite 4A loading was varied at 1.6 to 5.52 % w/ v. The reaction was compared to the conventional esterification reaction carried out under identical conditions but without addition of zeolite 4A. Concentration of each component in the system was analyzed using on-line Gas Chromatography. Effect of removing the water produced during the reaction by using zeolite 4A was demonstrated. It was revealed that the amount of water removed was proportional to the amount of the zeolite 4A to be employed. On the other hand, the increase of the temperature led to the lower amount of water to be adsorbed. Among all the experiments, the best result was achieved on the addition of 5.52 % b/v zeolite 4A at 40 °C, where water concentration was 3.1356 g mole/L and the conversion was 76.11 % at the equilibrium condition. As comparison, water concentration on the conventional reaction performed at 40 °C was 6.9161 g mole/L and the conversion was 62.5 % at the equilibrium condition. The equation illustrating the effect of zeolite 4A loading on the conversion obtained at the equilibrium condition was: XAe = 0.6248 + 0.0868 C4A0.2848, where XAe was equilibrium conversion of Acetic Acid and C4A was Zeolite 4A loading (g/100 mL liquid).
REKAYASA PROSES DISTILASI EKSTRAKTIF PADA PEMBUATAN PELARUT BERBASIS HIDROKARBON DENGAN MENGGUNAKAN ENTRAINER SULFOLANA Haniif Prasetiawan; Ratna Dewi Kusumaningtyas; Bayu Triwibowo; Dhoni Hartanto; Muhammad Fikri Al Ghifari; Syifa Karimah
Jurnal Inovasi Teknik Kimia Vol 7, No 1 (2022)
Publisher : Fakultas Teknik Universitas Wahid Hasyim

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31942/inteka.v7i1.6032

Abstract

Pelarut atau solvent merupakan salah satu komponen penting dalam proses kimia pada industri kimia. Salah satu jenis pelarut yang sering digunakan pada industri cat dan pelapis yaitu pelarut berbasis hidrokarbon yang terdiri dari campuran cairan kompleks yang beragam dan mengandung unsur alifatik, alisiklik dan aromatik (C5-C8). Aromatik hidrokarbon merupakan polutan lingkungan yang terkenal bersifat toksik, karsinogenik dan mutagenik sehingga dibutuhkan pelarut berbasis hidrokarbon dengan kandungan aromatik dibawah 1%. Metode pemisahan yang tepat untuk memisahkan komponen aromatik dan nonaromatik yang memiliki titik didih berdekatan adalah distilasi ekstraktif dengan entrainer sulfolana. Pada penelitian ini, sistem distilasi dengan entrainer sulfolana dijalankan menggunakan process simulation software Aspen Plus V.10 dengan tujuan untuk mengetahui pengaruh jumlah sulfolana, feed stage dan jumlah stage terhadap sifat fisis pelarut berbasis hidrokarbon serta analisis energi dan ekonominya. Simulasi ini difokuskan pada variasi rasio sulfolana:crude feed ( 7:1, 7,5:1, 8:1, 8,5:1), variasi feed stage (stage ke-10 sampai ke-35) dan variasi jumlah stage (70,75,80). Hasil penelitian didapatkan kondisi optimum yaitu menggunakan rasio sulfolana:crude feed  8,5:1, feed stage ke-25 dan jumlah stage 80. 
Analysis of Inventory Problems Using the Fault Tree Analysis Method (Case Study: PT Kimpai Dyna Tube) Siti Salwa Azzahra Nurazizah Nuruljannah; Ratna Dewi Kusumaningtyas; Tyas Samesti
OPSI Vol 15, No 2 (2022): ISSN 1693-2102
Publisher : Jurusan Teknik Industri Fakultas Teknologi Industri UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/opsi.v15i2.7978

Abstract

PT Kimpai Dyna Tube focuses on PBL (Plastic Barier Laminate) Tube products, which currently focuses on providing cosmetic products with plastic-based materials. Based on the results of the field survey on the inventory process, several problems were found, namely overstock material, deadstock material and outstanding material. The analysis process used is the Fault Tree Analysis (FTA) method because of its efficiency. Based on the results of the FTA, it was found that the basic event in the case of overstock material and deadstock material, namely changes in skincare trends in the community that caused very significant changes in the results of purchase orders and forecasts. The solution for the problem of overstock material and material deadstock is the application of a stock level system on inventory. Meanwhile, in the Outstanding material case, 3 basic events were obtained including, long lead time for delivery by overseas suppliers, trouble machines and many rejected quality items. Based on the results of the FTA, solutions were found for these problems, including performing careful calculations for the process of purchasing goods from foreign suppliers, providing machine spare parts and coordinating with suppliers and customers regarding the quality standards of production.
Peningkatan Keterampilan Masyarakat UMKM Tahu Kelurahan Sumurejo, Semarang melalui Pelatihan Pembuatan Pelet Pakan Ternak dari Limbah Ampas Tahu Nadya Alfa Cahaya Imani; Ratna Dewi Kusumaningtyas; Dwi Widjanarko; Irene Nindita Pradnya; Handri Rama Pradani; Ashroful In'am
Dedikasi:Jurnal Pengabdian kepada Masyarakat Vol 3, No 1 (2022): Jurnal Dedikasi
Publisher : Universitas Jayabaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31479/dedikasi.v3i1.203

Abstract

Jumlah limbah yang terus meningkat merupakan dampak negatif dari perkembangan industri pengolahan kedelai yang sebenarnya meningkatkan perekonomian masyarakat. Dalam upaya untuk menyelesaikan masalah tersebut, pemanfaatan limbah ampas tahu menjadi pakan alternatif bagi ternak merupakan salah satu solusi yang potensial untuk dilakukan. Namun, karena keterbatasan informasi dan keterampilan, produk limbah ampas tahu yang diproses menjadi produk pakan alternatif masih kurang sempurna. Bentuk akhir berupa butiran tepung dirasa masih kurang optimal dan memiliki bermacam kekurangan seperti mudah hancur, mudah tercecer, dan bahkan terkadang lengket hingga menempel satu dengan lainnya. Solusi dari masalah tersebut adalah teknologi pembuatan bentuk pelet pada produk pakan ternak dari limbah ampas tahu. Berkaitan dengan permasalahan tersebut maka dilakukan upaya inovasi kegiatan pengabdian kepada masyarakat di wilayah Kelurahan Semurrejo, Kecamatan Gunungpati, Kota Semarang yang diprioritaskan pada pemberian edukasi kepada masyarakat mengenai pentingnya pengelolaan limbah yang baik dan potensi dari limbah ampas tahu dan pelatihan keterampilan pada masyarakat mengenai teknologi pembuatan pelet pakan ternak dari limbah ampas tahu. Hasil dari kegiatan yang telah dilakukan membuktikan bahwa adanya peningkatan edukasi pada masyarakat dan juga peningkatan kualitas pakan ternak.
Review Pemanfaatan Design Expert untuk Optimasi Komposisi Campuran Minyak Nabati sebagai Bahan Baku Sintesis Biodiesel Reshita Amalia Ramadhani; Dody Herdian Saputra Riyadi; Bayu Triwibowo; Ratna Dewi Kusumaningtyas
Jurnal Teknik Kimia dan Lingkungan Vol. 1 No. 1 (2017): October 2017
Publisher : Politeknik Negeri Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (768.923 KB) | DOI: 10.33795/jtkl.v1i1.5

Abstract

Mixing different types of vegetable oils for synthesis of biodiesel is one of the efforts for renewable alternative energy. Mixed oil of vegetable oils more potential because it is not difficult to finding raw materials and not useful yet. Vegetable oils mixture as raw materials used include: Jatropha curcas oil, nyamplung oil and waste cooking oil. The mixed and optimized compositions use the simplex lattice design method with a total mixture. The data to be obtained is the influence data of each mixed oil to decrease of FFA during esterification reaction. Simplex lattice design method is one of the methods available in the software Design Expert 10.0. The designs used to optimize the formula on different amounts of different material compositions. The biodiesel synthesis is run based on the experimental design produced by the Expert Design 10.0 program. The use of lattice simplex method design: determination formula, optimizing formulation variable and total number of runs, keeping total concentration constant. ANOVA (Analysis of variance) to determine the significance of response analysis among variables and can know the suggested model. Desirability is a method that shows the program's ability to meet the criteria specified in the final product. The desired value that is critical to the desired product improvement program is so perfect.
Sintesis Nanoenkapsulasi Ekstrak Kulit Durian dengan Metode Spray Drying dan Aplikasinya sebagai Biopestisida: Review Nina Hartini; Syarifatur Richana; Bayu Triwibowo; Nur Qudus; Ratna Dewi Kusumaningtyas
Jurnal Teknik Kimia dan Lingkungan Vol. 2 No. 2 (2018): October 2018
Publisher : Politeknik Negeri Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (397.298 KB) | DOI: 10.33795/jtkl.v2i2.61

Abstract

Indonesia sebagai negara agraris, sebagian penduduk Indonesia bermata pencaharian di bidang pertanian. Pada umumnya, masyarakat menggunakan pestisida untuk membasmi hama. Karena tingginya penggunaan pestisida maka WHO (2016) menyatakan kasus keracunan pestisida mencapai 193.000 jiwa selama tahun 2012. Untuk mengatasi permasalahan tersebut, biopestisida menjadi bahan alternatif pengganti pestisida karena lebih aman dan ramah lingkungan. Salah satu bahan alam yang berpotensi sebagai biopestisida adalah kulit durian. Rata- rata produksi durian setiap tahunnya 780.032,8 ton/tahun. Limbah kulit durian memiliki berat 60-75% dengan kandungan senyawa metabolit sekunder relatif tinggi belum termanfaatkan secara maksimal. Senyawa tersebut dimanfaatkan sebagai antioksidan dan antimikroba dalam proses pembasmi hama. Biopestisida yang dikembangkan dengan metode sokletasi menghasilkan ekstrak berbentuk cair. Namun, hasil tersebut kurang efektif dan mudah teroksidasi sehingga menurunkan keefektifitasan kadar bahan aktif. Mengatasi masalah tersebut maka perlu dikembangkan inovasi dengan proses enkapsulasi. Artikel ini me-review pengembangan metode enkapsulasi. Metode yang dapat digunakan untuk enkapsulasi biopestisida yaitu ekstrusi, spray chilling dan spray drying. Metode spray drying lebih berpotensi mengenkapsulasi biopestisida dari kulit durian karena memiliki efisiensi enkapsulan lebih tinggi dan hampir mendekati 100%. Distribusi ukuran partikel yang dihasilkan tergolong nanoenkapsulan. Indonesia as an agrarian country, most of Indonesia's people work in agriculture. In general, people use pesticides to eradicate pests. Due to the high use of pesticides, WHO (2016) stated the case of pesticide poisoning reach 193,000 in 2012. To solve the problem, Biopesticide as an alternative of synthetic pesticides because it’s more safe and environmentally friendly. One of the natural ingredients that potentially as biopesticide is durian peel. The average durian production per year is 780,032.8 tons/year. Durian peels waste weighs 60-75% with a relatively high contains of secondary metabolite not yet fully utilized. It’s used as antioxidants and antimicrobials in pesticides. Biopesticide is developed by socletation method. However, the results are less effective because it’s easily oxidized, so reduce the flavonoid efectiveness. To solve this problem, to be developed innovation with encapsulation process. This article reviews the development of encapsulation methods. Methods that can be used for biopesticide encapsulation are extrusion, spray chilling and spray drying. Spray drying method is more likely to encapsulate biopesticides because it has higher encapsulation efficiency and is close to 100%. The resulting particle size distribution is classified as nanocapsul.
Enzymatic Interesterification of Crude Palm Oil with Methyl acetate: Effect of Pre-treatment, Enzyme’s Dosage and Stability Muhammad Zarin Amin Zainal; Harumi Veny; Fazlena Hamzah; Miradatul Najwa Muhd Rodhi; Andri Cahyo Kumoro; Ratna Dewi Kusumaningtyas; Haniif Prasetiawan; Dhoni Hartanto
Bulletin of Chemical Reaction Engineering & Catalysis 2023: Just Accepted Manuscript and Article In Press 2023
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.17763

Abstract

In the present study, biodiesel was produced via the enzymatic interesterification of Crude Palm Oil (CPO) and methyl acetate within ultrasonic condition. In contrast to alcohol, methyl acetate as an acyl acceptor does not inhibit lipase activity and can create triacetin as a useful byproduct.  In this work, Immobilized lipase from Candida Antartica A (CaLA) was utilized as biocatalyst and the effect of using non-pretreated CPO and pre-treated CPO as feedstock were explored. The pre-treatment of CPO involves degumming with acid, washing with water, and bleaching. The enzymatic interesterification was conducted in three-neck flasks using an ultrasonic water bath at 45o C.  Few parameter effects on biodiesel production were also investigated, including the effect of molar ratio of CPO to methyl acetate, the effect amount of lipase, and the reusability of immobilized lipase (CaLA) in the interesterification reaction.  The highest average Biodiesel yield of 80.6% was obtained from pretreated CPO at a molar ratio of 1:9 with 100 mg (1% w/v) of Immobilized CaLA, after three hours of reaction. Further research on the reusability of immobilized CaLA revealed that the yield of biodiesel reduced significantly after the second run. The results of the present study also demonstrated that Immobilized CaLA performed well at low concentrations but had low stability, with productivity decreasing to 92% upon reuse after the initial run. In order to make Immobilized lipase economically viable, further research must be conducted to overcome its low stability in the reaction.
PENERAPAN TEKNOLOGI PENGOLAHAN LIMBAH MINYAK GORENG BEKAS MENJADI SABUN CUCI PIRING UNTUK PENGENDALIAN PENCEMARAN DAN PEMBERDAYAAN MASYARAKAT Ratna Dewi Kusumaningtyas; Nur Qudus; Rr Dewi Artanti Putri; Rini Kusumawardani
Jurnal Abdimas Vol 22, No 2 (2018): December 2018
Publisher : Universitas Negeri Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/abdimas.v22i2.16587

Abstract

Desa Sekaran memiliki Pertumbuhan penduduk, perkembangan industry, restoran dan usaha kuliner pesat karena terdapat universitas yang setiap tahunnya mengalami peningkatan mahasiswa. Hal ini memberikan banyak dampak positif bagi masyarakat, namun di sisi lain juga menimbulkan dampak yang kurang menguntungkan dari sisi lingkungan. Salah satu dampak negatif dari keberadaan usaha kuliner di wilayah Gunungpati adalah volume limbah minyak goreng tinggi. Ini terjadi karena kebanyakan masyarakat, dalam ha1 ini adalah para pedagang membuang limbah minyak goreng begitu saja. limbah minyak goreng tersebut apabila tidak dikelola dengan baik akan menimbulkan masalah bagi lingkungan, yaitu menjadikan lingkungan kotor dan dapat menemari air serta tanah.  Untuk mengatasi masalah itu, perlu adanya inovasi dalam pengelolaan limbah minyak goreng dengan melibatkan masyarakat luas sehingga limbah minyak goreng dapat dimanfaatkan menjadi produk yang bernilai ekonomis.Salah satu potensi limbah minyak goreng adalah kandungan asam lemak dari minyak nabati yang tinggi sehingga dapat dimanfaatkan menjadi sabun cuci piring yang ramah lingkungan. Oleh karena itu, untuk mengatasi masalah volume limbah minyak goreng  yang tinggi, dilakukan kegiatan pengabdian masyarakat yang bertujuan untuk meningkatkan nilai tambah bagi limbah minyak goreng dengan jalan mengolah limbah minyak goreng  menjadi sabun cuci piring. Pelatihan ketrampilan mengenai pengolahan limbah minyak goreng  menjadi sabun cuci piring ramah lingkungan telah dilaksanakan bagi masyarakat di desa Sekaran wilayah Gunungpati. Pengabdian masyarakat ini memberikan manfaat: 1) Masyarakat mengetahui dampak negative minyak goreng bekas terhadap kesehatan dan lingkungan, 2) Masyarakat mengetahui dan terampil mengaplikasikan teknologi tepat guna pengolahan minyak jelantah menjadi sabun cuci piring, 3) Masyarakat mengetahui potensi ekonomis limbah minyak goreng bekas, 4) Mendorong pemberdayaan masyarakat melalui penerapan teknologi tepat guna.
Tin (II) Chloride Catalyzed Esterification of High FFA Jatropha Oil: Experimental and Kinetics Study Ratna Dewi Kusumaningtyas; Prima Astuti Handayani; Rochmadi Rochmadi; Suryo Purwono; Arief Budiman
International Journal of Renewable Energy Development Vol 3, No 2 (2014): July 2014
Publisher : Center of Biomass & Renewable Energy, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/ijred.3.2.75-81

Abstract

Biodiesel is one of the promising energy source alternatives to fossil fuel. To produce biodiesel in a more economical way, the employment of the low-cost feed stocks, such as non-edible oils with high free fatty acid (FFA), is necessary. Accordingly, the esterification reaction of FFA in vegetable oils plays an important role in the biodiesel production. In this work, esterification of FFA contained in Crude Jatropha Oil (CJO) in the presence of tin (II) chloride catalyst in a batch reactor has been carried out. The esterification reaction was conducted using methanol at the temperature of 40-60 °C for 4 hours. The effect of molar ratio of methanol to oil was studied in the range 15:1 to 120:1. The influence of catalyst loading was investigated in the range of 2.5 to 15% w/w oil. The optimum reaction conversion was obtained at 60 °C with the catalyst loading of 10% w/w oil and molar ratio of methanol to oil of 120:1. A pseudo-homogeneous reversible second order kinetic model for describing the esterification of FFA contained in CJO with methanol over tin (II) chloride catalyst was developed based on the experimental data. The kinetic model can fit the data very well.
Enzymatic Interesterification of Crude Palm Oil with Methyl acetate: Effect of Pre-treatment, Enzyme’s Dosage and Stability Muhammad Zarin Amin Zainal; Harumi Veny; Fazlena Hamzah; Miradatul Najwa Muhd Rodhi; Andri Cahyo Kumoro; Ratna Dewi Kusumaningtyas; Haniif Prasetiawan; Dhoni Hartanto
Bulletin of Chemical Reaction Engineering & Catalysis 2023: BCREC Volume 18 Issue 2 Year 2023 (August 2023)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.17763

Abstract

In the present study, biodiesel was produced via the enzymatic interesterification of Crude Palm Oil (CPO) and methyl acetate within ultrasonic condition. In contrast to alcohol, methyl acetate as an acyl acceptor does not inhibit lipase activity and can create triacetin as a useful byproduct.  In this work, Immobilized lipase from Candida Antartica A (CaLA) was utilized as biocatalyst and the effect of using non-pretreated CPO and pre-treated CPO as feedstock were explored. The pre-treatment of CPO involves degumming with acid, washing with water, and bleaching. The enzymatic interesterification was conducted in three-neck flasks using an ultrasonic water bath at 45o C.  Few parameter effects on biodiesel production were also investigated, including the effect of molar ratio of CPO to methyl acetate, the effect amount of lipase, and the reusability of immobilized lipase (CaLA) in the interesterification reaction.  The highest average Biodiesel yield of 80.6% was obtained from pretreated CPO at a molar ratio of 1:9 with 100 mg (1% w/v) of Immobilized CaLA, after three hours of reaction. Further research on the reusability of immobilized CaLA revealed that the yield of biodiesel reduced significantly after the second run. The results of the present study also demonstrated that Immobilized CaLA performed well at low concentrations but had low stability, with productivity decreasing to 92% upon reuse after the initial run. In order to make Immobilized lipase economically viable, further research must be conducted to overcome its low stability in the reaction.
Co-Authors Achmad Bachtiar Agung Ari Wibowo Ahmad Afwan Fathoni Ajeng Riswanti Wulandari Akbar, Muhammad Hafizt Andri Cahyo Kumoro Anugrahani, Viona Widya Anwaruddin Hisyam Anwaruddin Hisyam Arief Budiman Arief Budiman Arief Budiman Ashroful In'am Atuzzuhro, Qoni' Ayu Fadilah Wahid Aza Putri Anisa Bachtiar, Achmad Bahlawan, Zuhriyan Ash Shiddieqy Barita, Asyera Dewi Bayu Triwibowo Cahya Wulandari Catur Rini Widyastuti, Catur Rini Chafidz, Achmad Daniel Setiyo Nugroho Daniel Setiyo Nugroho, Daniel Setiyo Dewi Selvia Fardhyanti Dewi Trisnani Dhoni Hartanto Dimas Rahadian Aji Muhammad, Dimas Rahadian Aji Dody Herdian Saputra Riyadi Dody Herdian Saputra Riyadi Dwi Fibriyani Dwi Widjanarko Evi Widowati Fathoni, Ahmad Afwan Fauzi, Dinda Adelia Fazlena Hamzah Fazlena Hamzah Fera Arinta Fidyawati, F Fitra Aulia Rahma H Hadiyanto Hadikawuryan, Danang Subarkah Hamzah, Fazlena Handri Rama Pradani Haniif Prasetiawan Hardi Suyitno Harumi Veny Harumi Veny Heri Yudiono I. Istadi Ichwan, Rizky Imam Novrizal Aji Imani, Nadya Alfa Cahaya Irene Nindita Pradnya Jannah, Reni Ainun Khoiroh, Ianatul Kun, Stefania Orance Kusuma, Andre Dianata Hogi Laila, Rachma Akmila Lestari, Yanesti Nur Avianda Loveyanto, Rendy Okta M Nasikin Maftukhaturrizqiyah, Maftukhaturrizqiyah Maksiola, Masni Megawati Megawati Mezaki, Naufal Mudrik Miradatul Najwa Muhd Rodhi Miradatul Najwa Muhd Rodhi Mohamad Nor, Nur Fatin Syafiqah Muhammad Fikri Al Ghifari Muhammad Zarin Amin Zainal Muhd Rodhi, Miradatul Najwa Mustofa Mustofa Mutaqin, Afrizal Mai Nadya Alfa Cahaya Imani Nana Kariada Trimartuti Nathaniela, Regina Marsha Nina Hartini Nina Hartini Nindita, Ariana Eka Nur Qudus Oktafiani Oktafiani, Oktafiani Oktafiani, Oktafiani Oktafiani, Oktafiani Pradnya, Irene Nindita Prima Astuti Handayani Purwana, Yulian Candra Putri, Silvia Nouvelia Putut Marwoto Rachmadi, Moch Faizal Radenrara Dewi Artanti Putri, Radenrara Dewi Artanti Rahmah, Aisyah Khalimatur Rahmat, Sultan Aulia Reshita Amalia Ramadhani Reshita Amalia Ramadhani Ria Wulansarie, Ria Rini Kusumawardani, Rini Riza Mazidu Sholihin Rochmadi Rochmadi Rochmadi Rochmadi Rr. Dewi Artanti Putri, Rr. Dewi Artanti S Mursiti S., Syifa Azzahra Putri Sabirin Matsjeh Salsabila, Anida Salsabila, Annisa Putri Santi Wijayanti, Dwi Gansar Sarina Sulaiman Sazali, Rozana Azrina Siti Salwa Azzahra Nurazizah Nuruljannah Sunyoto Sunyoto Suryo Purwono Sutrisno, Akhmad Syah, Ahmad Faiz Armiano Syamrizal, Zakky Syarifatur Richana Syarifatur Richana Syifa Karimah Tyas Samesti Ummi Nur Laila Sulistyani Veny, Harumi Wandah Wibawanto Wara Dyah Pita Rengga Wicaksono, Dino Widi Astuti Widya Hary Cahyati Wijayanti, Reni Titis Wulandari, Ajeng Riswanti Wulansari, Durroti Zuhriah Zakaria, Zainul Akmar