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Journal : IPTEK Journal of Proceedings Series

Crystal Growth of IRMOF-3 (Isoreticular Metal-Organic Frameworks-3) Synthesized using Solvothermal Method Pemta Tia Deka; Ratna Ediati; Didik Prasetyoko
IPTEK Journal of Proceedings Series Vol 1, No 1 (2014): International Seminar on Applied Technology, Science, and Arts (APTECS) 2013
Publisher : Institut Teknologi Sepuluh Nopember

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.12962/j23546026.y2014i1.416

Abstract

IRMOF-3 crystals have been synthesized using solvothermal method by reacting zinc nitrate hexahydrate with 2-amino-1,4-benzenedicarboxylic acid in N'N-dimethylformamide ( DMF ) at 100 °C for 18, 24, 48, 72, 120 and 144 h to observe crystal growth . The obtained crystals were characterized using X - ray Diffraction ( XRD ) , SEM ( Scanning Electron Microscopy ) and Scanning Electron Microscopy - Energy Dispersive X-ray ( SEM - EDX ). Diffractograms of crystals synthesized at heating times of 24 and 48 hours showed major peaks at 2θ of 6.8; 9.6 and 13.7, which are the characteristic peaks of an IRMOF-3 crystal. The size of IRMOF-3 crystals observed using SEM increased with the increase in heating time up to 48 h, then decreased at heating times of 72, 120 and 144 h. The largest IRMOF-3 crystal is of cube shape with a particle size of 500 µm. The weight of the resulting crystals increased with the increase in heating time, then remained constant after 72 h.
Synthesis of UiO-66 Using Solvothermal Method at High Temperature Ika Diah Rahmawati; Ratna Ediati; Didik Prasetyoko
IPTEK Journal of Proceedings Series Vol 1, No 1 (2014): International Seminar on Applied Technology, Science, and Arts (APTECS) 2013
Publisher : Institut Teknologi Sepuluh Nopember

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.12962/j23546026.y2014i1.417

Abstract

UiO-66 solids have been synthesized using solvothermal method in which reaction mixtures of zirconium tetrachloride (ZrCl4) and 1,4-benzenedicarboxylic acid (BDC) in N-N'-dimethylformamide (DMF) were heated at 140 °C for 6, 12, 24, 36, 48, 72 and 144 hours, respectively. The weight of reaction products, in the form white powder, increased with the increase in heating time up to 72 hours, then decreased. Characterization results using XRD showed that the diffractogram of the solid obtained at heating time of 6 h had the same pattern to that of reported UiO-66, characterized by a main peak with a high intensity at 2θ of 7.3°, as well as other characteristic peaks with lower intensity at 2θ of 8.4°; 25.6° and 30.6°. The longer the heating time (12 and 24 h), the lower the intensity of the main peak. When the reaction mixtures were heated for 36 h or longer, the obtained solid diffractograms showed that the main peak intensity at 2θ of 7.3° was lower than the second peak, and new peaks appeared at 2θ of 13.8°; 15.8° and 17.5°. SEM micrographs showed that the solid synthesized for 6 h was in the form of clusters of square morphology, whereas solids synthesized for 72 h showed needle-like surface morphology
Co-Authors A'yuni, Qurrota Abdul Hamid Abdul Hamid Abdul Hamid Abdulloh Abdulloh Adi Setyo Purnomo Afifah Rosidah Afifah Rosyidah Ahmad Anwarud Dawam Ahmad Anwarud Dawam Ahmad Anwarud Dawam Ahmad, Shahrul Nizam Aishah Abdul Jalil Aishah Abdul Jalil Aishah Abdul Jalil Aishah Abdul Jalil Alfa Akustia Widati Alya Awinatul Rohmah Amalia Putri Purnamasari Amin Jakfar, S.T.,M.T., Lukman Hadiwijaya, S.T.,M.T. Amirul Mukminin Anil Kumar Anal Anis Farika Anis Farika, Anis Arief Fadlan Arizal Firmansyah Asranudin Asranudin, Asranudin Badzlin Nabilah Bayu Wiyantoko Cepi Kurniawan Che Ku Nor Liana Che Ku Hitam Cholifah Endah Royani Cicik Herlina Yulianti Desy T. Kusumaningtyas Desy Tri Kusumaningtyas Dety Oktavia Sulistiono Dewi, Nita Safira Didi Dwi Anggoro Djoko Hartanto Djoko Hartanto Djoko Hartanto Dyah Ayu Fatmawati Dyah Fitasari Eka Pratiwi Yuniarti Eka Putra Ramdhani Eko Santoso Endang Purwanti Endud, Salasiah F Widhi Mahatmanti Farhanah Thalib Fensia Analda Souhoka Firda, Putri Bintang Dea Futri Wulandari H. Holilah Hadi Nur Hadi Nur Hadi Nur Hamzah Fansuri Haq, Ismi Arinal Harjito - Harjito Harjito Harmami Harmami Hartati Hartati Hartati Hartati Hasliza Bahruji Hasliza Bahruji Hasliza Bahruji Hasliza Bahruji Hellna Tehubijuluw Hendro Nurhadi Ika Diah Rahmawati Ike Dayi Febriana Imroatul Qoniah Imroatul Qoniah Imroatul Qoniah Imroatul Qoniah Imroatul Qoniah Imroatul Qoniah Izzah, Adiba Naila Kris Murwani, Irmina Kurniawati, Puji Kurniawati, Puji Kusumawati, Yuly Le Monde, Brilliant Umara Leaw Wai Loon Lely Dwi Astuti Lisa Amalia Suryana Lukman Atmaja Mardi Santoso Maria Ulfa Maria Ulfa Maria Ulfa Meiske S Sangi Meyga E. F. Sari Meyga Evi Ferama Sari Mohammad Abdullah Mudasir Mudasir Muhammad Lukman Hakim Muhammad Nur Kholis Muhammad Nur Kholis Mulyatun Mulyatun Naimatul Khoiroh Nanik Siti Aminah Nanik Wijayati Neneng Ayunanda Novesar Jamarun Nuni Widiarti Nur, Hadi Nurdiani, Maulida Nurul - Widiastuti Pemta Tiadeka Puji Kurniawati R.Y. Perry Burhan, R.Y. Perry Rahayu, Endah Fitriani Rakhmadi Harsanto Ramli, Zainab Ratna Ediati Ratna Ediati Reva Edra Nugraha Safa Annissa Novianti Salasiah Endud Samuel Budi Wardhana Samuel Budi Wardhana Kusuma Santi Wulan Purnami Sirly Bifadilatur Romaniyah Siti Maryam Subagyo, Riki Suci Indrayani Sugeng Triwahyono Sugeng Triwahyono Sugeng Triwahyono Sugeng Triwahyono Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto, Suprapto Suprapto, Surapto Susi Nurul Khalifah Syafsir Akhlus Syafsir Akhlus, Syafsir Tanti Kartika Dewi Taufiq Rinda Alkas Teguh Endah Saraswati Tikha Reskiani Fauziah Titie Prapti Oetami Titie Prapti Oetami Tri Ana Mulyati Tri Esti Purbaningtias Tri Wahyuni Tri Wahyuni Tri wahyuni Triyono Triyono Triyono Triyono Wahyu Bambang Widayatno Wega Trisunaryanti Wega Trisunaryanti Wega Trisunaryanti Wijianto, Wijianto Wiyantoko, Bayu Wiyantoko, Bayu Yatim Lailun Ni’mah Yoshifumi Chisaki Yulinar Dwi Nur Azizah Yusuf Muhammad Zein Yusuf Muhammad Zein Yuvita Eka Pertiwi Zahrotul Istiqomah Zainab Ramli Zainab Ramli Zainab Ramli Zainab Ramli Zakaria, Zaki Yamani Zeni Rahmawati Zetra, Yulfi