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PENURUNAN KADAR LOGAM KADMIUM MENGGUNAKAN ADSORBEN NANO ZEOLIT ALAM ACEH Cut Raziah, Zerlinda Putri, Atika Rahmi Lubis, Sofyana, Zuhra, Suhendrayatna, Sri Mulyati
Jurnal Teknik Kimia USU Vol 6, No 1 (2017)
Publisher : Universitas Sumatera Utara

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (304.913 KB) | DOI: 10.32734/jutek.v6i1.15857

Abstract

The presence of Cadmium (Cd) in groundwater is an issue that needs serious handling as it causes problems to human health. The removal of Cadmium (Cd) can be done by various methods such as adsorption, oxidation, filtration, and many more. In this study, the method used was adsorption using Aceh natural zeolite. This process was expected to reduce Cd metal as effectively as possible. The adsorption was conducted by varying contact time, adsorbent dosage, pH and initial concentration of Cd metal. The crystallized Aceh natural zeolite was characterized by X-Ray Fluorescence (XRF) with Si/Al zeolite ratio of 4.36 %. The concentration of Cadmium in water was analyzed by means of Atomic Adsorption Spectrophotometer (AAS) standard AA 630. The results showed that the adsorption of cadmium in water solution by Aceh natural zeolite occurred according to   the Freundlich adsorption model. While the adsorption kinetic from the process was found to be a pseudo second order with k2 value of 1.53.
PENYISIHAN ION LOGAM MERKURI (Hg2+) MENGGUNAKAN ADSORBEN BERBAHAN BAKU LIMBAH PERTANIAN DAN GULMA TANAMAN Miftahurrahmah, Suhendrayatna, Muhammad Zaki
Jurnal Teknik Kimia USU Vol 6, No 1 (2017)
Publisher : Universitas Sumatera Utara

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (404.049 KB) | DOI: 10.32734/jutek.v6i1.15933

Abstract

This research was conducted to prepare adsorbents from agricultural and weeds waste biomass to remove Hg2+ metal ions from water phase. Water hyacinth biomass (agricultural waste) and rice husk (weed) was cleaned, dried in an oven dryer, and carbonized in a furnace at 500oC for 2 hours. Then, dried carbon was milled to get 100 mesh of size and was followed by activation using 0.5 N NaOH. The adsorption process was conducted by mix 1 gram of activated adsorbent on a 100 ml water containing 3 ppm Hg2+ metal ions at 100 rpm, pH 5, and 30oC. Hg2+ concentration in water phase were analyzed using AAS, Shimadzu AA-6300 for a specified time within a period of 20-100 minutes. This study shows that at the beginning process of adsorption, adsorbent from rice husk has ability to decrease 69.91% concentration of Hg2+ for 20 minutes, while adsorbent from water hyacinth reaches to 94.26%. The characterization results of FTIR spectra and SEM shows that adsorbent from water hyacinth was able to absorb more Hg2+ metal ions in a short time because it has a functional group that was able to bind heavy metals, and also has a random surface structure, compared with the adsorbent from rice husks that has less functional groups with uniform morphology structure
Pengarusutamaan Gender dalam Kebijakan Jenjang Kepangkatan di Universitas Syiah Kuala Rita Andini; Rini Safitri; Ade T; Muhammad Ikhsan Sulaiman; Monita Olivia; Erika L; Pardede Pardede; Muhammad Afifuddin; Suhendrayatna Suhendrayatna; Darusman Darusman
Jurnal Pemerintahan dan Kebijakan (JPK) Vol 3, No 2 (2022): April
Publisher : Universitas Muhammadiyah Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.18196/jpk.v2i3.12665

Abstract

Penelitian ini bertujuan untuk mengidentifikasi faktor-faktor yang mempengaruhi sivitas akademika Universitas Syah Kuala untuk mencapai jenjang Kepala Dosen (LK) dan Guru Besar/Guru Besar. Hasil penelitian ini berkontribusi dalam menentukan kebijakan tingkat kepangkatan berdasarkan Pengarusutamaan Gender (PUG). Program PUG yang telah dilaksanakan secara eksplisit dalam 'Gender Equality Plans in (Marine) Research Projects' atau disingkat Baltic Gender yang didanai dari program Horizon 2020 Uni-Europe dapat dijadikan acuan sebagai program 'stimulasi' bagi dosen perempuan dan peneliti untuk dapat mengembangkan kapasitas dan daya saingnya. Fasilitas kelembagaan yang mempertimbangkan beban ganda bagi dosen perempuan dapat ditindaklanjuti dengan memberikan fasilitas 'penitipan anak' hingga jam kerja normal, bagi dosen dan staf yang memiliki anak usia pra sekolah sehingga dosen perempuan juga dapat terlibat aktif dalam kegiatan produktif. dan kegiatan penelitian yang dinamis. . Selain itu, program insentif dana penelitian yang mempertimbangkan 'insentif' untuk pembayaran fasilitas penitipan anak selain insentif tambahan untuk dana penelitian dan publikasi juga dapat dipertimbangkan untuk dosen perempuan dengan beban ganda; khususnya yang berstatus single parent dengan jabatan Ketua Lektor. Namun, 'creme de la-creme' adalah semua kebijakan yang tertulis secara eksplisit ramah gender bagi dosen perempuan yang memiliki kekuatan hukum tetap dan ditandatangani oleh pimpinan tertinggi yang mengikat mereka pada jenjang turunannya tanpa mengurangi kondusifitas akademik (penelitian dan pendidikan) suasana. Karena sebuah kematian tanpa aturan yang mengikat secara formal dari sebuah institusi sangat penting untuk keberlangsungan di masa yang akan datang (sustainability). Hal ini dapat dikategorikan sebagai bentuk transformasi kelembagaan sekaligus sebagai bentuk nyata kepedulian para pemimpin tingkat tinggi, tentunya akan berdampak positif dalam jangka panjang terkait dengan target Unsyiah untuk mencapai World Class University Based Imtaq.
The Effect of Administrative Implementation Principles towards the Effectiveness of Government Services Halik Halik; Suhendrayatna Suhendrayatna; Irma Yurni; Halimah Halimah
Budapest International Research and Critics Institute (BIRCI-Journal): Humanities and Social Sciences Vol 3, No 1 (2020): Budapest International Research and Critics Institute February
Publisher : Budapest International Research and Critics University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33258/birci.v3i1.714

Abstract

The purpose of this study is to find out the implementation of the principles of public administration, and see the obstacles experienced by the Camat and sub-district staff in implementing the principles of public administration. This study reviews the policy of implementing administrative principles on the effectiveness of government services. Using descriptive-quantitative methods, the sample are 32 employees of the Tiro sub-district office. the results showed that the policy of implementing administrative principles on the effectiveness of the service of the sub-district government had run effectively and good coordination in the field of duties and functions of each employee.
Analisis Tingkat Pencemaran Air Sungai Krueng Tamiang Terhadap COD, BOD dan TSS Bahagia Bahagia; Suhendrayatna Suhendrayatna; Zulkifli Ak
Jurnal Serambi Engineering Vol 5, No 3 (2020)
Publisher : Fakultas Teknik

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32672/jse.v5i3.2073

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Industrial waste is a factor influencing the pollution of the Krueng Tamiang river. The purpose of this study was to analyze the level of water pollution in the Krueng Tamiang river with the parameters of Biochemical Oxygen Demand (BOD), Chemical Oxygen Demand (COD) and Total suspended Solid (TSS) parameters. The results showed the highest BOD parameter test results came from location 2 (Seumadam Bridge) of 3.63 mg / L at stage IV and the lowest BOD value at locations 1 and 6 (Kaloy Village and Alur Manis Bridge) at stage I of 2 mg / L. The highest COD parameter test results came from location 5 (Kota Lintang Bridge) of 21.0 mg / L at stage III and the lowest COD value at location location 1 (Kaloy Village) at stage III, points 1, 3 and 6 (Kaloy Village, Kebon Tengah Suspension Bridge and Alur Manis Bridge) at stage IV of 17.0 mg / L. The highest TSS parameter test results came from location 7 (Peukan Seuruway), namely 295 mg / L phase I in the dry season, and the lowest TSS value at location 1 (Kaloy Village), which was 11 mg / L in stage III during the rainy season.
Penyerapan Ion Logam Merkuri Hg(II) oleh Biosorben dari Daun Lidah Mertua (Sansivieria sp.) Elvitriana Elvitriana; Kasturi Kasturi; H Murni; Suhendrayatna Suhendrayatna
Jurnal Serambi Engineering Vol 7, No 4 (2022): Oktober 2022
Publisher : Fakultas Teknik

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32672/jse.v7i4.4926

Abstract

The aim of this study was to apply a biosorbent from the leaves of Lidah Mertua (Sansivieria sp.) which were activated by 4M HCl to remove mercury metal ions Hg(II). The leaves of Sansivieria sp. were cleaned, dried in an oven, and carbonized in a furnace at a temperature of 450 oC for 1.5 hours. After grinding to a size of 50 mesh, the resulting carbon was activated using 4 M HCl for 24 hours and dried at 110 oC for 2 hours. The absorption ability test of biosorbents was carried out by mixing 2, 3, and 4 grams activated biosorbent in 200 ml of water containing 0.15 mg-Hg/L metal ions Hg(II). The mixture was stirred using an incubator shaker with variated contact times of 0, 4, and 6 days. Mercury metal ions concentration were analyzed using AAS, Shimadzu AA-6300. The results showed that activation using 4 M HCl can open the pores of the biosorbent. Compared to the inactivated biosorbent, the characteristics of this activated biosorbent were better with lower water content (2%), higher ash content (9.9%), greater iodine absorption (1259.14 mg/g), and higher carbon content (89%). Based on SNI.06-3730-1995 Standard, the resulting biosorbent was close to qualified as activated carbon. The highest absorption efficiency of ion Hg(II) was 99.6% which was achieved for 6 days with a 4 grams of biosorbent. The results of this study concluded that the leaves of (Sansivieria sp.) activated by 4M HCl could absorb metal ions Hg(II) well.
Akumulasi Logam Berat pada Tanaman Pepaya (Carica papaya) Akibat Penggunaan Air Limbah Rumah Sakit sebagai Media Tumbuh Suhendrayatna Suhendrayatna; Elviani Elviani; Elvitriana Elvitriana
Jurnal Serambi Engineering Vol 7, No 3 (2022): Juli 2022
Publisher : Fakultas Teknik

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32672/jse.v7i3.4639

Abstract

Wastewater from the outlet of hospital's Wastewater Treatment Plant (WWTP) is expected to be used for watering plants as an effort to water use efficiently. To answer this assumption, this research was carried out to examine the effects of hospital wastewater as a plant growth medium on the accumulation of pollutants in papaya (Carica papaya) leaves and fruit. Local papaya seeds were grown on the land around the hospital's WWTP and the plants were watered every day with wastewater. Plants were well cared for without adding other additives as fertilizer and their growth was observed. After 8 months of treatment, the fruits and leaves of plants were harvested and destructed using HNO3 and H2SO4 to measure the heavy metal content using the Atomic Absorption Spectrophotometer, Shimadzu A630. Results showed that when wastewater was used as a growth medium, metals Hg, Cd, and Pb were found to accumulate in papaya fruit with a concentration of 0.179; 0.582; and 2,327 mg/kg, while other metals such as Cr and As were not found to accumulate in papaya fruit. Metal accumulation was also found in papaya leaves with Hg content of 0.739 mg/kg and Cd of 0.582 mg/kg, while others metals Cr, Pb, and As were not found in the papaya leaves. These results indicate that the main source of heavy metal accumulation in papaya plants came from wastewater from the WWTP outlet containing heavy metals.
Analisis Kualitas Air Permukaan DAS Alas-Singkil Untuk Monitoring Tingkat Pencemaran Air Permukaan Zulkifli AK; Bahagia Bahagia; Suhendrayatna Suhendrayatna; Vera Viena
Jurnal Nasional Komputasi dan Teknologi Informasi (JNKTI) Vol 4, No 6 (2021): Desember 2021
Publisher : Program Studi Teknik Informatika, Fakultas Teknik. Universitas Serambi Mekkah

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32672/jnkti.v4i6.4660

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Abstrak -  Kualitas air permukaan yang mengalir di Daerah Aliran Sungai (DAS)Alas Singkil perlu dilakukan analisis komponen/indikator lingkungannya. Pengukuran kualitas air sungai akibat adanya pencemaran. DAS Alas Singkil menaungi delapan sungai di Kota Subulussalam yang bergabung membentuk sungai. Tujuan penelitian adalah untuk menganalisis tingkat pencemaran air sungai Wilayah Sungai (WS) Alas-Singkil dengan parameter uji Total suspended Solid (TSS), pH, kandungan oksigen dan kadar logam. Hasil penelitian menunjukkan suhu daerah aliran sungai (DAS) Alas Singkil menunjukkan kisaran antara 27,4 – 29,1 °C. Suhu dapat mempengaruhi fotosintesis di sungai wilayah Alas Singkil baik secara langsung maupun tidak langsung. Hasil uji TDS menunjukkan nilai 23,9 mg/L - 97,5 mg/L yang masih berada dibawah baku mutu. Lokasi paling tinggi TDS berada pada titik Sungai Lae Kombih (AP2) dan nilai paling rendah pada lokasi Sungai Lae Soraya (AP1). Hasil uji menunjukkan bahwa  nilainya masih dibawah baku mutu yaitu 1.000 mg/L. Hasil uji TSS antara  4 -36 mg/L. Konsentrasi TSS semua lokasi tidak melebihi baku mutu yang telah ditetapkan oleh Peraturan Pemerintah RI No. 22 Tahun 2021 tentang Penyelenggaraan Perlindungan dan Pengelolaan Lingkungan Hidup untuk Kelas Air II.  Hasil uji pH lebih stabil dan berada dalam kisaran yang sempit yaitu 6,82–8,86 pH karena dipengaruhi oleh kapasitas penyangga (buffer) yaitu adanya sedimentasi aliran sungai.  Hasil uji kadar logam : tembaga (CU), Timbal (Pb), Cadmium (Cd) dan Seng (Zn) pada Daerah Aliran Sungai (DAS) Alas  Singkil menunjukkan masih barada dalam ambang batas dengan hasil uji Laboratoirum dibawah baku mutu yaitu 0,0008 b , 0,0001 b , 0,0004 b dan 0,0001 b  (Tidak terdeteksi karena berada di bawah Batas Minimum Deteksi Alat Uji).  Kata kunci : Air permukaan, DAS, kualitas, pencemaran air sungai, pemantauan dan penertiban.  Abstract –  The quality of surface water flowing in the Alas Singkil Watershed (DAS) needs to be analyzed for environmental components/indicators. Measurement of river water quality due to pollution. The Alas Singkil watershed covers eight rivers in Subulussalam City which combine to form rivers. The purpose of the study was to analyze the level of water pollution of the Alas-Singkil River Basin (WS) with the test parameters of Total suspended Solid (TSS), pH, oxygen content and metal content. The results showed that the temperature of the Alas Singkil watershed showed a range between 27.4 – 29.1 °C. Temperature can affect photosynthesis in the Alas Singkil river area either directly or indirectly. The TDS test results showed a value of 23.9 mg/L - 97.5 mg/L which was still below the quality standard. The highest location for TDS is at the point of the Lae Kombih River (AP2) and the lowest value is at the location of the Lae Soraya River (AP1). The test results show that the value is still below the quality standard of 1000 mg/L. TSS test results between 4 -36 mg/L. The concentration of TSS in all locations does not exceed the quality standard set by the Government of Indonesia Regulation No. 22 of 2021 concerning the Implementation of Environmental Protection and Management for Water Class II. The pH test results are more stable and are in a narrow range of 6.82-8.86 pH because it is influenced by the buffer capacity, namely the presence of river flow sedimentation. The test results for the levels of metals: copper (CU), Lead (Pb), Cadmium (Cd) and Zinc (Zn) in the Alas Singkil Watershed (DAS) showed that they were still within the threshold with the Laboratory test results below the quality standard, namely 0, 0008 b , 0.0001 b , 0.0004 b and 0.0001 b (Not detected because it is below the Minimum Detection Limit for Test Equipment).Keywords: Surface water, watershed, quality, river water pollution, monitoring and control.
Adsorption Of Cd(II) Ions From Aqueous Solution By A Low-Cost Biosorbent Prepared From Ipomea Pes-Caprae Stem Thaharah Ramadhani; Faisal Abdullah; Indra Indra; Abrar Muslim; Suhendrayatna Suhendrayatna; Hesti Meilina; Saiful Saiful
Aceh International Journal of Science and Technology Vol 9, No 3 (2020): December 2020
Publisher : Graduate Program of Syiah Kuala University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (682.648 KB) | DOI: 10.13170/aijst.9.3.18256

Abstract

The use of a low-cost biosorbent prepared from Ipomoea pes-caprae stem for the adsorption of Cd(II) ions from aqueous solution at different contact times, biosorbent sizes, pH values, and initial Cd(II) ions concentration solution was investigated. The biosorbent was analyzed using Fourier-transform infrared spectroscopy (FT-IR) to find important IR-active functional groups. A scanning electron microscope (SEM) was used to examine the biosorbent morphology. The experimental results showed the highest Cd(II) ions adsorption was 29.513 mg/g  under an optimal condition as initial Cd(II) ions concentration of 662.77 mg/L, 1 g dose, 80-min contact time, pH 5, 75 rpm of stirring speed, 1 atm, and 30 oC. Cd(II) ions' adsorption kinetics obeys the linearized pseudo-second-order kinetics (R2 = 0.996), and the adsorption capacity is based on the optimal condition, and the rate attained was 44.444 mg/g and 0.097 g/mg. Min, respectively. Besides, the adsorption isotherms were very well fitted by the linearized Langmuir isotherm model, and the monolayer adsorption capacity and pore volume determined was 30.121 mg/g and 0.129 L/mg, respectively. These results indicated the chemisorption nature
Study on the optimization of mercury ion (II) adsorption with activated carbon from a biomass combination of palm bunches and rice husk Suhendrayatna Suhendrayatna; Abdurrahman Abdurrahman; Elvitriana Elvitriana
Aceh International Journal of Science and Technology Vol 8, No 3 (2019): December 2019
Publisher : Graduate Program of Syiah Kuala University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (799.769 KB) | DOI: 10.13170/aijst.8.3.15160

Abstract

This research deals with the adsorption of mercury ions [Hg (II)] using a combination of natural biomass between oil palm bunches and rice husks (PB-RH). After drying at 40oC, PB-RH biomass was carbonized by using a tube furnace for 2 hours at 500 °C and followed chemical activation with citric acid. Activated carbon formed was contacted with an aqueous solution containing Hg (II) ion and stirred at a constant rate of 150 rpm. The concentration of Hg (II) ions in the aqueous phase were analyzed with Atomic Absorption Spectrophotometer (AAS) and the Central Composite Design (CCD) method with Design-Expert software version 6.0.8 was conducted to calculate the optimization of adsorption capacity for mercury ion. The Hg ion adsorption capacity was estimated to observe the performance of the PB-RH biomass combination on the adsorption of Hg (II) ions with some variables, such as contact time, biomass weight, and activator concentration. Results showed that all variable response, contact time, biomass weight, and activator concentration influenced the mercury (II) ion adsorption capacity. The optimum condition of Hg (II) ion adsorption occurred at 30 g of activated PB-RH biomass with 0.6 mole/L concentration of activator during 99.88 minutes with 99.42 mg/L initial concentration of Hg (II). The adsorption capacity occurred at 10.1 mg/g as the optimum condition for the adsorption of Hg (II) ions by PB-RH.
Co-Authors . Bahagia . Elvitriana . Marwan A.A. Ketut Agung Cahyawan W Abd Rahman, Sunarti Abdul Gani ABDUL GANI Abdurahman Abdurrahman Abrar Muslim Abrar Muslim Abrar Muslim Ade T Afifuddin, Muhammad Al Harist, Al Harist Ali Sarong Aman Yaman Asmaul Husna Asmaul Husna Aulia, Muhammad Bahagia Bahagia Bahagia Bahagia Bahagia Bahagia Darusman Darusman Dedi Sofriadi Donny Avrilan Edi Munawar Edi Munawar Eko Suhartono Eldina Fatimah Ellysa Ellysa Elviani Elviani Erika L Faisal Abdullah Faisal Abdullah Fandana, Lisa Febriani Febriani Fredinan Yulianda Ghazi Mauer Idroes H Murni Halik Halimah Halimah Henny Marlina Heri Afriadi Aka Hesti Meilina Hesti Meilina Hesti Meilina Husni Husni Ichwana Ichwana Idroes, Ghalieb Mutig Indra Indra Iqbalul Hadi Irhamni Irhamni Irma Yurni Irza, Tsaqif Aufa Jayawarsa, A.A. Ketut Kasturi Kasturi Khairan Khairan Kiman Siregar* Kusumo, Fitranto L, Erika Laksono Trisnantoro M. Nasir Mahidin Mahidin Marwan Abu Bakar Marwan Marwan Marwan Marwan Maulana, Aga Medyan Riza Miftahurrahmah Miftahurrahmah, Miftahurrahmah Monita Olivia Muammar Khadafi Muhammad Afifuddin Muhammad Ikhsan Sulaiman Muhammad Irham Muhammad Syukri Muhammad Zaki Muhammad Zaki Muhammad Zaki Muhammad Zaki, Muhammad Zaki Mulyadi Mulyadi Muslim*, Abrar Nizariah, Nizariah Novia Novia Novia Novia Nurlaili Nurlaili Pardede Pardede Pardede, Pardede Prasetio, Rasi Putri Nurmala Rahmawati, Sri Rini Ermiana* Rini Safitri Rini Safitri Rita Andini RITA ANDINI Sabrina Hayatun Nufus Saiful Saiful Sofia Sofia Sri Adelila Sari Sugianto Sulastri Sulastri Syafrizal Syafrizal Syaiful Huzni Syaubari Syaubari T, Ade Teuku Rizky Noviandy Thaharah Ramadhani Vera Viena Wilda Khairuna Yundari, Yundari Zahriah, Zahriah Zainal Abidin Muchlisin Ziana Ziana Zuchra Helwani, Zuchra Zuhri, Sarika Zulkifli Ak Zulkifli AK