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Synthesis, Characterization, and Catalytic Performance of H₃[α-PMo₁₂O₄₀]·nH₂O-TiO₂ in Cyclohexane Oxidation Lingga, Fitra Wahyuni; Jefri, Jefri; Mohadi, Risfidian; Lesbani, Aldes
Indonesian Journal of Material Research Vol. 3 No. 1 (2025): March
Publisher : Magister Program of Material Science Graduate School of Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/ijmr.20253153

Abstract

This study aims to synthesize and characterize the H₃[α-PMo₁₂O₄₀].nH₂O-TiO₂ composite as a heterogeneous catalyst for cyclohexane oxidation using H₂O₂. FT-IR and XRD characterization showed the interaction between POM and TiO₂, with an increase in TiO₂ ratio leading to a decrease in POM crystallinity. Reaction optimization showed that the POM-1.00TiO₂ catalyst gave the highest conversion of 99.95% at 80°C, 2 hours reaction time, 3 mL H₂O₂ volume, and 0.1 g catalyst mass. GC analysis confirmed the formation of cyclohexanol and cyclohexanone, with the optimized conditions resulting in a balanced selectivity of 35.51% for cyclohexanol and 34.69% for cyclohexanone, demonstrating the catalyst's effectiveness in cyclohexane oxidation.
Pembelajaran Modifikasi Nutrasetikal Temu Mangga Menjadi Produk “Temapro” untuk Kesehatan Masyarakat Miksusanti Miksusanti; Risfidian Mohadi; Aldes Lesbani; Nirwan Syarif; Neza Rahayu Palapa; Azhar Kholiq; Syafrina Lamin
Bumi: Jurnal Hasil Kegiatan Sosialisasi Pengabdian kepada Masyarakat Vol. 3 No. 2 (2025): April: Bumi: Jurnal Hasil Kegiatan Sosialisasi Pengabdian kepada Masyarakat
Publisher : Asosiasi Riset Teknik Elektro dan Informatika Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.61132/bumi.v3i2.760

Abstract

This community service program aims to develop nutraceutical-based health products from temu mangga (Curcuma mangga Val.van Zip) and probiotics, called "TEMAPRO". Research and socialization were conducted in Pulau Semambu Village, South Sumatra, targeting village mothers who have limited knowledge about the benefits of herbs and probiotics. Temu mangga, which is traditionally consumed as a salad and herbal medicine, contains various active compounds that have the potential as antioxidants and anti-cancer. Combined with the probiotic Lactobacillus rhamnosus, this product is expected to support digestive health and increase body immunity. Implementation methods include education, training in making temu mangga extract, mixing with probiotics, and product packaging techniques. The results of the activities showed an increase in community understanding and skills in processing local materials into health products with economic value. It is hoped that "TEMAPRO" will not only improve the quality of public health, but also open up business opportunities in the village through local nutraceutical products.
The Potential of Shell Extract as a Hemostasis and Wound Healing Agent: A Literature Review Erlyn, Putri; Irfannuddin, Irfannuddin; Murti, Krisna; Lesbani, Aldes
Jurnal Kedokteran Brawijaya Vol. 33 No. 1 (2024)
Publisher : Fakultas Kedokteran Universitas Brawijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21776/ub.jkb.2023.033.01.6

Abstract

Hemostasis is an emergency medical treatment to reduce pain and patient mortality, therefore research is being developed to find effective hemostasis. The utilization of natural materials for hemostasis and wound healing is rapidly expanding, including chitosan found in shell extracts. Chitosan is obtained from chitin found in the soft shells of marine animals such as squid, shrimp, and crabs, or from hard shells such as clams, crabs, and lobsters. Chitosan offers advantages such as good biodegradability, biocompatibility, and non-toxicity, and has been widely used in biomedical, chemical, food, and cosmetic industries. This literature review aims to investigate the potential of shell extracts, particularly the characteristics of chitosan, in wound healing across hemostasis, inflammation, proliferation, and remodeling stages. The study results indicate that extracts from shells containing chitosan exhibit varying characteristics in terms of molecular weight and degree of deacetylation. Chitosan with higher molecular weight and degree of deacetylation tends to yield better outcomes in hemostasis and wound healing. The material is effective in reducing antithrombin, enhancing blood clotting processes, and aiding clot formation. Increased molecular weight contributes to stimulating various cytokines, such as TNF-α, TGF-ß1, and FGF2, which play a key role in the wound healing process. Additionally, higher degree of deacetylation chitosan is effective in stimulating fibroblast proliferation. Chitosan also influences VEGF in inducing angiogenesis and enhancing neovascularization in bone healing. Chitosan from shell extracts with certain molecular weight characteristics and degree of deacetylation has the potential to be the material of choice for accelerating hemostasis and wound healing.
Treatment of Methylene Blue Using Ni-Al/Magnetite Biochar Layered Double Hydroxides Composite by Adsorption Zahara, Zaqiya Artha; Royani, Idha; Palapa, Neza Rahayu; Mohadi, Risfidian; Lesbani, Aldes
Bulletin of Chemical Reaction Engineering & Catalysis 2023: BCREC Volume 18 Issue 4 Year 2023 (December 2023)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.20049

Abstract

Methylene blue dye is hard to degrade and requires treatment using Ni-Al Layered double hydroxides (LDHs) modified with magnetite biochar (MBC) to form Ni-Al/magnetite biochar composite in overcoming environmental pollution. Material attainment was identified by characterization using X-Ray Diffraction (XRD), Fourier Transform – Infra Red (FT-IR), Branuer Emmet Teller (BET), Scanning Electron Microscopy – Energy Dispersive X-Ray (SEM-EDX) and Vibration Sample Magnetometer (VSM). XRD characterization displays angle 2θ at 11°, 60° is a typical angle of LDH, and angles 22° and 35° of magnetite biochar. FT-IR characterization analysis at wavelength 1381 cm-1 for NO3- group and M-O group at wave number 700 cm-1. C-H group on biochar at 1404 cm-1 and wave number 586 cm-1 for Fe-O group. BET characterization analysis of Ni-Al/MBC has a large surface area and pore volume of 127.310 m²/g and 0.1950 cm³/g. SEM characterization analysis of Ni-Al/MBC has large, coarse pores and non-uniform shape, EDX data shows that there are forming elements such as Ni, Al from LDH and, Fe, C elements from magnetite biochar. pH, kinetics, isotherms, and thermodynamics become influential in adsorption processes. The adsorption capacity of the composite reaches 68.493 mg/g by following the Langmuir equation and adsorption kinetics refers to the Pseudo Second Order (PSO) equation. Adsorption continuity is spontaneous and endothermic. Ni-Al/MBC has stability in the process of adsorbent regeneration up to five adsorption cycles and, therefore can be used as a potential adsorbent in the treatment of methylene blue dye in aqueous environmental pollution. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
Recycle Performance of Heterogeneous Catalyst Metal Oxides-Based Layered Double Hydroxide for Oxidative Desulfurization Process of 4-methyldibenzothiophene Ahmad, Nur; Rohmatullaili, Rohmatullaili; Hanifah, Yulizah; Wibiyan, Sahrul; Amri, Amri; Wijaya, Alfan; Mardiyanto, Mardiyanto; Mohadi, Risfidian; Royani, Idha; Lesbani, Aldes
Bulletin of Chemical Reaction Engineering & Catalysis 2023: BCREC Volume 18 Issue 4 Year 2023 (December 2023)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.20034

Abstract

The desulfurization of oil must be resolved as soon as possible due to a variety of issues, including environmental contamination and protection regulations. It was believed that oxidative desulfurization (ODS) was the most promising method. In this research, metal oxide-based layered double hydroxides (TiO2@Ni-Al and ZnO@Ni-Al) were effectively synthesized for the ODS of 4-methyldibenzothiophene (4-MDBT). TiO2@Ni-Al and ZnO@Ni-Al exhibited superior catalytic performance and high recycling capacity, achieving a 99% removal rate after five reactions in 30 min. The heterogeneous catalyst TiO2@Ni-Al/ZnO@Ni-Al is easy to separate and recover from a reaction system. Increased temperature facilitates the transformation of 4-MDBT into 4-MDBTO2. The influence of H2O2's rapid decomposition rate, which can inhibit oxidation reactions, reduces the catalytic activity as the temperature increases. 4-MDBT Sulphur removal on TiO2@Ni-Al and ZnO@Ni-Al is 99.48 and 99.51%, respectively. TiO2@Ni-Al and ZnO@Ni-Al have great potential for use in the industry based on these results. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
Sosialisasi Aplikasi Pupuk Nanomagnetik Pasir Besi Pada Tanaman Jagung di Desa Pulau Semambu Ogan Ilir Sumatera Selatan Sebagai Integrasi Penelitian dan Perkuliahan Fitri Suryani Arsyad; Dedi Setiabudidaya; Menik Ariani; Idha Royani; Amiruddin Supu; Risfidian Mohadi; Aldes Lesbani; Rakhmawati Farma; Balada Soerya; Siti Nur’aini; Beta Riana Liasari
Riau Journal of Empowerment Vol 7 No 2 (2024)
Publisher : Lembaga Penelitian dan Pengabdian kepada Masyarakat Universitas Riau

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31258/raje.7.2.156-167

Abstract

Socialization activities have been carried out regarding the application of iron sand nanomagnetic fertilizer (Fe3O4) on corn plants to the villagers of Pulau Semambu Ogan Ilir, South Sumatra. This community service activity is part of the integration of the research results that have been carried out. From the results of the study, it was found that at the same growing age, corn added with nano-magnetic iron sand, both simaxx + nanomagnetic iron sand and silica + nanomagnetic iron sand, had a faster growth of about 100 cm compared to corn that was only given simaxx fertilizer. which is about 45-50 cm. Research results and observational data were then collected and analyzed to evaluate the effectiveness of using Fe3O4 nanomagnetic fertilizer on corn plants. Apart from being disseminated to corn farmers, research results are also used as teaching material to be conveyed to students in material physics courses. Integrating research results with community service activities and material physics lectures has increased the practical use of research results and provided wider benefits for society and students.
Co-Authors A. Agnes Abi Sueb Abriyanto, Danang Addy Rachmat Adi Saputra Adi Saputra Adi Saputra Adi Saputra Afifah Rahma Dian Ahmad Fatoni Ahmad Fatoni Alfan Wijaya Alfan Wijaya Alfan Wijaya Amiruddin Supu Amri Amri Amri Andi Wijaya Andreas, Roy Andriani Azora Andriani Azora Anggraini, Ana Arini Fousty Badri Arini Fousty Badri Arison Musri Arison Musri Arsyad, Fitri Suryani Aslihati Aslihati Aslihayati Aslihayati Azhar Kholiq Badri, Arini Fousty Bakri Rio Rahayu Bakri Rio Rahayu Balada Soerya Benyamin Lakitan Beta Riana Liasari Dedi Rohendi Dedi Setiabudidaya Desnelli Desnelli Dian Monariqsa Dian Monariqsa Didi Jasantri Dormian A N Haloho Dormian A N Haloho Eiffel Ostan Jeski Gultom Elfita Elfita . Elfita Elfita Eliza . Eliza Eliza Eliza Eliza Ema Veronika Turnip Endri Junaidi Eriza Sativa Erviana, Desti Fahma Riyanti Fatmawati Fatmawati Ferlinahayati Ferlinahayati Fitri Suryani Arsyad Fitri, Erni Salasia Fitriliana Fitriliana Hanifah, Yulizah Haris Kriswantoro Hermansyah Hermansyah Hermansyah Hermansyah Hesti A. Harahap Hesti A. Harahap, Hesti Hilda Zulkifli Hilda Zulkifli Hilda Zulkifli Hiroshi Nishihara Hitoshi Kondo Idha Royani Intan Permata Sari Irfannuddin Irfannuddin Jasantri, Didi Jefri Jefri Jeri Ramadhan Juleanti, Novie Kiki Anggraini Kiki Anggraini Kiki Anggraini, Kiki Komis Krisna Murti Laila Hanum Leni Sinaga Lestari Simanjuntak Lestari Simanjuntak Lingga, Fitra Wahyuni Lora Vitanesa Lucyanti . Lucyanti Lucyanti Lusi Teresia Mardianto Mardiyanto Mardiyanto Mardiyanto Mardiyanto Mardiyanto Mardiyanto Mardiyanto Mardiyanto Mardiyanto Mardiyanto Mardiyanto Mardiyanto, Marieska Verawaty Mariska Verawaty Melantina Melan Oktriyanti Melwita, Elda Menik Ariani Menik Setyowati Mikha Meilinda Christina Miksusanti Miksusanti Muhammad Imron Muhammad Said Muhammad Said Muhammad Said Najma Annuria Fithri Najma Annuria Fithri Najma Annuria Fithri Najma Annuria Fithri, Najma Annuria Narsito Narsito Neza Rahayu Niken Oktora Niken Oktora Nirwan Syarif Normah Normah Normah Normah, Normah Nova Yuliasari Novie Juleanti Novie Juleanti Novie Juleanti Nur Ahmad Nur Ahmad, Nur Nurlisa Hidayati Nurlisa Hidayati Nurlisa Hidayati Nurlisa Hidayati Nurlisa Hidayati Nurlisa Hidayati Nurlisa Hidayati Nurlisa Hidayati Nurlisa Hidayati Nurlisa Hidayati Nurlisa Hidayati Nyanyu Ummu Hani Palita Tamba Patimah Mega Syah Bahar Nur Siregar Patimah Mega Syah Bahar Nur Siregar Patimah Mega Syah Bahar Nur Siregar Poedji Loekitowati Hariani Putri Erlyn Putri, Bunga Indah R.A. Mika Melviana Rabelia Juladika Sayeri Radja Nardo Purba Rakhmawati Farma Ramadhan, Jeri Rananda Vinsiah Randi O. Saragih Ratna, L.P Ratna, L.P Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risma Kurniawati M Rohmatullaili Rohmatullaili, Rohmatullaili Roy Andreas Sabat Okta Ceria Sitompul, Sabat Okta Ceria Samat Samat Savira, Dila Setiawan Yusuf Setiawati Yusuf Setiawati Yusuf Sherly Agustina, Sherly Siregar, Patimah Mega Syah Bahar Nur Siti Nur’aini Sri Juari Santosa Suheryanto Suheyanto Suheryanto Sumiati Sumiati SUMIATI, Susila Arita Syaflina Lamin Syafrina Lamin, Syafrina Tamizi Taher Tarmizi Taher Welinda Me Wibiyan, Sahrul Wijaya, Alfan Winda Fitriana Yeni Iswanti Yoshinori Yamanoi Yosi Saria Yosi Saria Yosi Saria Yosine Susi Yosine Susie Yunita Irianty Zahara, Zaqiya Artha Zazili Hanafiah Zultriana