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Adsorption of Cadmium(II) Using Ca/Al Layered Double Hydroxides Intercalated with Keggin Ion Tarmizi Taher; Yunita Irianty; Risfidian Mohadi; Muhammad Said; Roy Andreas; Aldes Lesbani
Indonesian Journal of Chemistry Vol 19, No 4 (2019)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (375.644 KB) | DOI: 10.22146/ijc.36447

Abstract

Ca/Al layered double hydroxides (Ca/Al LDH) was synthesized using co-precipitation method following calcination at 800 °C and was intercalated with Keggin ion [α-SiW12O40]4– to form intercalated Ca/Al LDH. Materials were characterized using XRD and FTIR spectrophotometer. Furthermore, materials were used as an adsorbent of cadmium(II) from solution. The results showed that layer material was formed completely after calcination which was indicated at diffraction 20° due to loss of water in the interlayer space. Ca/Al LDH after calcination was intercalated with [α-SiW12O40]4– ion and interlayer distance was increased from 4.25 to 4.41 Å showed that intercalation process was successfully conducted. Adsorption of cadmium(II) using Ca/Al LDH was conducted at pH 9 and intercalated Ca/Al LDH at pH 8 showed that intercalated material has slightly faster than Ca/Al LDH without intercalation probably due to slightly increasing interlayer distance of Ca/Al LDH after intercalation. The adsorption capacity of intercalated Ca/Al LDH was higher than Ca/Al LDH without intercalation at the temperature range of 30–50 °C.
High Reusability of NiAl LDH/Biochar Composite in the Removal Methylene Blue from Aqueous Solution Aldes Lesbani; Neza Rahayu Palapa; Rabelia Juladika Sayeri; Tarmizi Taher; Nurlisa Hidayati
Indonesian Journal of Chemistry Vol 21, No 2 (2021)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.56955

Abstract

Ni/Al layered double hydroxide was used as a starting material for composite formation with biochar as a matrix. The materials were characterized using X-ray, FTIR, nitrogen adsorption-desorption, thermal, and morphology analyses. The NiAl LDH/Biochar material is then used as an adsorbent of methylene blue from an aqueous solution. The factor that was influencing adsorption such as pH, time, methylene blue concentration, and temperature adsorption was studied systematically. The regeneration of adsorbent was performed to know the stability of NiAl LDH/Biochar under several cycle adsorption processes. The results showed that NiAl LDH/Biochar has a specific diffraction peak at 11.63° and 22.30°. NiAl LDH/Biochar has more than ten-fold surface area properties (438,942 m2/g) than biochar (50.936 m2/g), and Ni/Al layered double hydroxide (92.682 m2/g). The methylene blue adsorption on NiAl LDH/Biochar follows a pseudo-second-order kinetic adsorption model and classify as physical adsorption. The high reusability properties were found for NiAl LDH/Biochar, which was largely different from biochar and Ni/Al layered double hydroxide.
NiAl Layered Double Hydroxide/Rice Husk Composite for the Efficient Removal of Malachite Green Neza Rahayu Palapa; Tarmizi Taher; Normah Normah; Aldes Lesbani
Indonesian Journal of Chemistry Vol 22, No 1 (2022)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.68021

Abstract

Rice husk biochar (BC) loaded NiAl layered double hydroxide (LDH) has been synthesized to form NiAl LDH/BC composite through a co-precipitation method. NiAl LDH/BC has been used as an adsorbent to remove malachite green from water efficiently. The specific surface area analysis revealed that the surface area of NiAl LDH/BC composite increased five times, from 92.6 to 438.9 m2/g, compared to the original NiAl LDH. The adsorption studies revealed that NiAl LDH/BC composite followed the pseudo-second-order kinetic adsorption model while the isotherm followed the Langmuir monolayer adsorption model. The maximum adsorption capacity of NiAl LDH/BC composite prepared with a ratio of 1:1 and 1:0.5 achieved 185.1 mg/g and 142.9 mg/g, respectively, which is twice higher than the pristine ones (NiAl LDH). The thermodynamic parameters, determined at 303, 313, 323, and 333 K, revealed that the adsorption process was spontaneous and endothermic. The NiAl LDH/BC composite was tested for three consecutive adsorption-desorption cycles to investigate its reusability performance. It is found that their adsorption performance slightly decreased to 71.8% and 68.3% for NiAl LDH/BC composite 1:0.5 and 1:1, respectively. Therefore, it could be considered that the synthesized NiAl LDH/BC exhibited a good and efficient adsorbent for malachite greed removal.
Comparison of the Adsorption Ability of MgAl-HC, CaAl-HC, and ZaAl-HC Composite Materials Based on Duku Peel Hydrochar in Adsorption of Direct Green Anionic Dyes Novie Juleanti; Normah Normah; Patimah Mega Syah Bahar Nur Siregar; Alfan Wijaya; Neza Rahayu Palapa; Tamizi Taher; Nurlisa Hidayati; Risfidian Mohadi; Aldes Lesbani
Indonesian Journal of Chemistry Vol 22, No 1 (2022)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.68719

Abstract

Preparation of composite material from layered double hydroxide (LDH) with hydrochar (HC) from duku peel produces CaAl-HC, MgAl-HC, and ZnAl-HC have shown the success of the preparation process as evidenced by characterizations such as XRD and FT-IR. The XRD characterization data evidenced the typical diffraction of the hydrochar around 2θ = 20° in the composite material. FTIR analysis is a characterization that supports the success of composite materials, which showed the presence of typical vibrations of HC at 3245, 2931, and 1635 cm–1 contained in the composite spectrum. The application of MgAl-HC, CaAl-HC, and ZnAl-HC composites as adsorbents showed Qmax (adsorption ability) values of 94.340 mg/g, 128.205 mg/g, and 89.286 mg/g. Overall the adsorption process is endothermic with a positive enthalpy value, and a negative Gibbs free energy value indicates a spontaneous adsorption process. The isotherm model of MgAl-HC, CaAl-HC, and ZnAl-HC show that the Langmuir isotherm model is more dominant, as indicated by the R2 value closer to 1 which indicates that the adsorption process takes place in a monolayer.
The Relationship of Culture Media Composition and Chemical Composition on Spirulina sp for Metal Ion Adsorbent Hilda Zulkifli; Zazili Hanafiah; Didi Jasantri; Aldes Lesbani
Sriwijaya Journal of Environment Vol 1, No 3 (2016): Biodiversity
Publisher : Program Pascasarjana Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (601.519 KB) | DOI: 10.22135/sje.2016.1.3.68-71

Abstract

The analysis relationship of Spirulina sp medium with chemical composition has been conducted. Chemical analysis was performed using X-Ray Fluorescence analysis. Furthermore, potention of Spirulina sp as adsorbent of metal ions was analyzed using FTIR spectroscopy. The results showed that metals such as Zn, Fe, Mn, Ca, Cu, and Mo were mainly metals in Spirulina sp. These metals were not correlated with cultivated medium of Spirulina sp. Analysis of potention Spirulina sp as metal ions adsorbent showed that Spirulina sp has functional groups –C=O and –OH as ligand. Intercation of metal ions Cu(II) and Cr(III) with Spirulina sp indicated that metal ions bond to –C=O functional group.Keywords: Spirulina sp, media composition, chemical content, metal ion, adsorptionAbstrak (Indonesian): Telah dilakukan analisis hubungan komposisi media Spirulina sp dengan kandungan kimia yang dimilikinya. Analisis kandungan kimia dilakukan dengan X-Ray Fluorescence. Selanjutnya potensi Spirulina sp sebagai adsorben dalam mengikat ion-ion logam dianalisis menggunakan spektroskopi FTIR. Hasil penelitian menunjukkan bahwa logam Zn, Fe, Mn, Ca, Cu, dan Mo merupakan logam utama yang terkandung dalam Spirulina sp. Logam-logam tersebut diasumsikan tidak berasal dari medium tumbuh Spirulina sp. Analisis terhadap potensi Spirulina sp sebagai adsorben logam berat menunjukkan bahwa Spirulina sp memiliki gugus fungsional -C=O dan –OH yang potensial sebagai ligan. Interaksi ion logam Cu(II) dan Cr(III) dengan Spirulina sp menunjukkan bahwa ion logam terikat pada gugus –C=O.Kata kunci: Spirulina sp, komposisi media, kandungan kimia, ion logam, adsorpsi
Transesterification of Tropical Edible Oils to Biodiesel Using Catalyst From Scylla serrata Risfidian Mohadi; Hesti A. Harahap; Nurlisa Hidayati; Aldes Lesbani
Sriwijaya Journal of Environment Vol 1, No 2 (2016): Developing Without Destruction
Publisher : Program Pascasarjana Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (342.181 KB) | DOI: 10.22135/sje.2016.1.2.24-27

Abstract

Abstract: Scylla serata shell was decomposed at various temperatures ranging from 700-1100 oC to obtain calcium oxide. Calcium oxide from decomposed Scylla serrata shell was characterized through X-Ray analysis, FTIR spectroscopy, and morphology analysis. Furthermore, decomposed Scylla serrata shell was used as catalyst for transesterification of tropical edible oils to form biodiesel. Biodiesel was characterized through density, viscosity, fatty acid value, and iodine number. The results showed that decomposed Scylla serrata shell at 900 oC could produce calcium oxide similar with standard, which was indicated from X-ray powder diffraction pattern of decomposed shell with JCPDS data. FTIR spectrum showed that main vibration of calcium oxide was observed at 393 cm-1. Morphology analysis using SEM indicated that uniform calcium oxide was obtained after decomposition. The use of decomposed shell as base catalyst for transesterification of tropical edible oils resulted biodiesel with density, viscosity, fatty acid value, and iodine number appropriated with SNI standard.Keywords: transesterification, edible oils, biodiesel, Scylla serrataAbstrak (Indonesian): Scyalla serrata telah didekomposisi pada berbagai suhu dari 700-1100 oC untuk diperoleh kalsium oksida. Kalsium oksida hasil dekomposisi dari cangkang Scylla serrata dikarakterisasi melalui pengukuran sinar X, analisis FTIR, dan analisis morfologi. Lebih lanjut, dekomposisi cangkang Scylla serrata digunakan sebagai katalis transesterifikasi minyak yang dimakan dari daerah tropis menjadi biodisel. Biodiesel dikarakterisasi melalui penentuan densitas, viskositas, nilai asam lemak, dan bilangan iod. Hasil penelitian menunjukkan bahwa dekomposisi cangkang Scylla serrata pada 900 oC dapat menghasilkan kalsium oksida mirip kalsium oksida standar yang diindikasikan dari pola difraksi XRD yang mirip data JCPDS. Spektrum FTIR menunjukkan vibrasi utama kalsium oksida teramati pada bilangan gelombang 393 cm-1. Analisis morfologi menggunakan SEM menunjukkan bahwa bentuk yang lebih seragam diperoleh setelah proses dekomposisi. Penggunaan cangkang hasil dekomposisi sebagai katalis basa untuk transesterifikasi minyak yang dimakan dari daerah tropis menghasilkan biodisel dengan densitas, viskositas, nilai asam lemak, dan bilangan iod yang sesuai dengan standar SNI.Kata kunci: transesterifikasi, minyak yang dimakan dari daerah tropis, biodiesel, Scylla serrata
Preparation Calcium Oxide From Chicken Eggshells Risfidian Mohadi; Kiki Anggraini; Fahma Riyanti; Aldes Lesbani
Sriwijaya Journal of Environment Vol 1, No 2 (2016): Developing Without Destruction
Publisher : Program Pascasarjana Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (407.883 KB) | DOI: 10.22135/sje.2016.1.2.32-35

Abstract

Abstract: The preparation of metal oxide CaO from chicken eggshell has been carried out by decomposition at various temperatures 600, 700, 800, 900, and 1000oC. The metal oxide CaO was characterized using XRD. Furthermore, The optimum temperature for preparation of CaO was determined based on the XRD pattern, then the characterization of CaO was extended using FT-IR spectrophotometer and BET analysis. The results show that the optimum temperature for preparation of CaO from chicken eggshell is 900oC with peak of 2Ө at 32.3o, 37.4o, 53.9o, 64.2o and 67.5o, respectively. The FT-IR spectrums show the unique vibration for Ca-O at 393 cm-1. The BET analysis show that CaO has surface area 68 m2/g with pore volume 1.65 cm3/g and pore size 6.6 nm which can be classified as mesoporous.Keywords: eggshell, base catalyst, CaO, BET, mesoporous Abstrak (Indonesian): Pembuatan oksida logam CaO dari cangkang telur ayam telah dilakukan melalui dekomposisi pada berbagai suhu 600, 700, 800, 900, dan 1000°C. Oksida logam CaO dikarakterisasi dengan XRD. Selanjutnya, Suhu optimum untuk persiapan CaO ditentukan berdasarkan pola XRD, setelah itu karakterisasi CaO dilanjutkan menggunakan FT-IR spektrofotometer dan analisis BET. Hasil penelitian menunjukkan bahwa suhu optimum untuk pembentukan CaO dari cangkang telur ayam adalah 900°C dengan puncak 2Ө muncul di 32.3°, 37.4°, 53.9°, 64.2° dan 67.5°. Spektrum FT-IR menunjukkan vibrasi unik untuk Ca-O di 393 cm-1. Analisis dengan BET menunjukkan bahwa CaO memiliki luas permukaan 68 m2/g dengan volume pori 1,65 cm3/g dan ukuran pori 6,6 nm yang dapat diklasifikasikan sebagai mesopori.Kata kunci: kulit telur, katalis basa, CaO, BET, mesopori
Adsorption of Procion Red on Natural Bentonite : Kinetic Studies Tarmizi Taher; Aldes Lesbani
Sriwijaya Journal of Environment Vol 1, No 1 (2016): The First Issue: Green Environment for Future Life
Publisher : Program Pascasarjana Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (393.317 KB) | DOI: 10.22135/sje.v1i1.1

Abstract

Abstract: Adsorption of procion red on natural bentonite was studied by kinetic study to know the reactivity of procion red. Kinetic adsorption was determined using batch adsorption system at various times in several concentrations of procion red. Time of adsorption was investigated at 5, 10, 20, 30, 45, 60, 90, and 120 minutes in 10, 25, 50, and 75 mg/L of procion red. The data was calculated using Langmuir-Hinshelwood kinetic equation. The diffusions process of procion red into bentonite at lower concentration was faster than at higher concentration in general with fit correlation between [(ln(Co/C))/C] vs t/C from Langmuir-Hinshelwood data. The adsorption procion red on bentonite data at various times shows Langmuir monolayer adsorption process in the surface of bentonite.Keyword: adsorption, procion red, natural bentonite, kineticAbstrak (Indonesian): Adsorpsi procion merah pada bentonit alam telah dipelajari melalui studi kinetik untuk mengetahui reaktivitas procion merah. Kinetika adsorpsi ditentukan menggunakan sistem adsorpsi simultan pada berbagai waktu dalam beberapa konsentrasi procion merah. Waktu adsorpsi dipelajari pada 5, 10, 20, 30, 45, 60, 90, dan 120 menit pada konsentrasi procion merah 10, 25, 50, dan 75 mg/L. Data dihitung menggunakan persamaan kinetika Langmuir-Hinshelwood. Proses difusi procion merah ke dalam bentonit pada konsentrasi rendah lebih cepat dibanding pada konsentrasi lebih tinggi secara umum dengan hubungan korelasi yang lurus antara [(ln(Co/C))/C] versus t/C dari data Langmuir-Hinshelwood. Adsorpsi procion merah pada bentonit dengan berbagai variasi waktu adsorpsi menunjukkan proses adsorpsi satu lapisan pada permukaan bentonit. Katakunci: adsorpsi, procion merah, bentonit alam, kinetik 
Production of Adipic Acid from Mixtures of Cyclohexanol-Cyclohexanone using Polyoxometalate Catalysts Lesbani, Aldes; Sumiati,; Mardiyanto,; Fithri, Najma Annuria; Mohadi, Risfidian
Makara Journal of Science Vol. 19, No. 2
Publisher : UI Scholars Hub

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Abstract

Adipic acid production through catalytic conversion of cyclohexanol-cyclohexanone using polyoxometalate H5[a-BW12O40] and H4[a-SiW12O40] as catalysts was carried out systematically. Polyoxometalates H5[a-BW12O40] and H4[a-SiW12O40] were synthesized using an inorganic synthesis method and were characterized using Fourier transform infrared spectroscopy (FTIR). Adipic acid was formed from conversion of cyclohexanol-cyclohexanone and was characterized by using melting point measurement, identification of functional group using FTIR spectrophotometer, analysis of gas chromatography-mass spectrometry (GC-MS), and 1H and 13C NMR (nuclear magnetic resonance) spectrophotometer. This research investigated the influence of reaction time and temperature on the conversion. The results showed that adipic acid was formed successfully with a yield of 68% by using H5[a-BW12O40] as the catalyst with a melting point of 150-152 °C after optimization. In contrast, using H4[a-SiW12O40] as the catalyst, the formation was only 3.7%. Investigation of time and temperature showed 9 h as the optimum reaction time and 90 °C as the optimum temperature for conversion of up to 68%. Identification using FTIR, 1H, and 13C NMR showed that the adipic acid from conversion of cyclohexanol-cyclohexanone was in agreement with the standard adipic acid data in the literatures. GC-MS analysis indicated that several by-products were formed in conversion of cyclohexanol-cyclohexanone using H5[a-BW12O40] and H4[a-SiW12O40] as the catalysts.
Preparation of Zn/Al-chitosan Composite for the Selective Adsorption of Methylene Blue Dye in Water Mohadi, Risfidian; Siregar, Patimah Mega Syah Bahar Nur; Palapa, Neza Rahayu; Lesbani, Aldes
Makara Journal of Science Vol. 26, No. 2
Publisher : UI Scholars Hub

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Abstract

Layered double hydroxide (LDHs) are widely used adsorbents for methylene blue removal. However, LDHs have a perishable structure that cannot be used repeatedly. Modifying LDHs with chitosan produces a strong material with a large surface area for methylene blue adsorption. Adsorption conditions were optimized by determining the adsorption isotherms and the adsorbent regeneration process. Results showed that the adsorption process was balanced in 90 min with maximum adsorption capacities of 86.207 mg/g, 35.336 mg/g, and 98.039 mg/g for Zn/Al, chitosan, and Zn/Al-chitosan, respectively. The adsorption in this study followed the Freundlich isotherm model. Regeneration analysis of the adsorbent showed that Zn/Al-chitosan can be used repeatedly in methylene blue adsorption.
Co-Authors A. Agnes Abi Sueb Abriyanto, Danang Addy Rachmat Adi Saputra Adi Saputra Adi Saputra Adi Saputra Afifah Rahma Dian Ahmad Fatoni Ahmad Fatoni Alfan Wijaya Alfan Wijaya Alfan Wijaya Amiruddin Supu Amri Amri Amri Andi Wijaya Andreas, Roy Andriani Azora Andriani Azora Anggraini, Ana Arini Fousty Badri Arini Fousty Badri Arison Musri Arison Musri Arsyad, Fitri Suryani Aslihati Aslihati Aslihayati Aslihayati Azhar Kholiq Badri, Arini Fousty Bakri Rio Rahayu Bakri Rio Rahayu Benyamin Lakitan Dedi Rohendi Dedi Setiabudidaya Desnelli Desnelli Dian Monariqsa Dian Monariqsa Didi Jasantri Dormian A N Haloho Dormian A N Haloho Eiffel Ostan Jeski Gultom Elfita Elfita . Elfita Elfita Eliza . Eliza Eliza Eliza Eliza Ema Veronika Turnip Endri Junaidi Eriza Sativa Erviana, Desti Fahma Riyanti Fatmawati Fatmawati Ferlinahayati Ferlinahayati Fitri Suryani Arsyad Fitri, Erni Salasia Fitriliana Fitriliana Hanifah, Yulizah Haris Kriswantoro Hermansyah Hermansyah Hermansyah Hermansyah Hesti A. Harahap Hesti A. Harahap, Hesti Hidayatullah, Muhammad Hilda Zulkifli Hilda Zulkifli Hilda Zulkifli Hiroshi Nishihara Hitoshi Kondo Idha Royani Intan Permata Sari Irfannuddin Irfannuddin Jasantri, Didi Jefri Jefri Jeri Ramadhan Juleanti, Novie Kiki Anggraini Kiki Anggraini Kiki Anggraini, Kiki Komis Krisna Murti Laila Hanum Leni Sinaga Lestari Simanjuntak Lestari Simanjuntak Liasari, Beta Riana Lingga, Fitra Wahyuni Lora Vitanesa Lucyanti . Lucyanti Lucyanti Lusi Teresia Mardianto Mardiyanto Mardiyanto Mardiyanto Mardiyanto Mardiyanto Mardiyanto Mardiyanto Mardiyanto Mardiyanto Mardiyanto Mardiyanto Mardiyanto, Marieska Verawaty Mariska Verawaty Melantina Melan Oktriyanti Melwita, Elda Menik Setyowati Mikha Meilinda Christina Miksusanti Miksusanti Muhammad Imron Muhammad Said Muhammad Said Muhammad Said MUHAMMAD SAID Najma Annuria Fithri Najma Annuria Fithri Najma Annuria Fithri Najma Annuria Fithri, Najma Annuria Narsito Narsito Neza Rahayu Niken Oktora Niken Oktora Nirwan Syarif Normah Normah Normah Normah, Normah Nova Yuliasari Novie Juleanti Novie Juleanti Novie Juleanti Nur Ahmad Nur Ahmad, Nur Nurlisa Hidayati Nurlisa Hidayati Nurlisa Hidayati Nurlisa Hidayati Nurlisa Hidayati Nurlisa Hidayati Nurlisa Hidayati Nurlisa Hidayati Nurlisa Hidayati Nurlisa Hidayati Nurlisa Hidayati Nur’aini, Siti Nyanyu Ummu Hani Palita Tamba Patimah Mega Syah Bahar Nur Siregar Patimah Mega Syah Bahar Nur Siregar Patimah Mega Syah Bahar Nur Siregar Poedji Loekitowati Hariani Putri Erlyn Putri, Bunga Indah R.A. Mika Melviana Rabelia Juladika Sayeri Radja Nardo Purba Rakhmawati Farma Ramadhan, Jeri Rananda Vinsiah Randi O. Saragih Ratna, L.P Ratna, L.P Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risfidian Mohadi Risma Kurniawati M Rohmatullaili Rohmatullaili, Rohmatullaili Roy Andreas Sabat Okta Ceria Sitompul, Sabat Okta Ceria Samat Samat Savira, Dila Setiawan Yusuf Setiawati Yusuf Setiawati Yusuf Sherly Agustina, Sherly Siregar, Patimah Mega Syah Bahar Nur Sitanggang, Jonra P. Soerya, Balada Sri Juari Santosa Suheryanto Suheyanto Suheryanto Sumiati Sumiati SUMIATI, Susila Arita Syaflina Lamin Syafrina Lamin, Syafrina Tamizi Taher Tarmizi Taher Welinda Me Wibiyan, Sahrul Wijaya, Alfan Winda Fitriana Yeni Iswanti Yoshinori Yamanoi Yosi Saria Yosi Saria Yosi Saria Yosine Susi Yosine Susie Yunita Irianty Zahara, Zaqiya Artha Zazili Hanafiah Zultriana