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All Journal VALENSI Reaktor Jurnal Ilmu Dasar IPTEK Journal of Proceedings Series IPTEK The Journal for Technology and Science Jurnal Sains dan Teknologi Jurnal Bahan Alam Terbarukan Journal of Mathematical and Fundamental Sciences Alchemy Jurnal Penelitian Kimia Jurnal Zeolit Indonesia ALCHEMY Jurnal Penelitian Kimia Indonesian Journal of Chemistry Akta Kimia Indonesia Chemistry Indonesian Journal of Chemical Research QARDHUL HASAN: MEDIA PENGABDIAN KEPADA MASYARAKAT Walisongo Journal of Chemistry Automotive Experiences Makara Journal of Science Sewagati International Journal of Renewable Energy Development Bulletin of Chemical Reaction Engineering & Catalysis
Didik Prasetyoko
Institut Teknologi Sepuluh Nopember
Aerospace Engineering Agriculture, Biological Sciences & Forestry Arts Humanities Astronomy Automotive Engineering Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Computer Science & IT Control & Systems Engineering Earth & Planetary Sciences Education Electrical & Electronics Engineering Energy Engineering Environmental Science Languange, Linguistic, Communication & Media Materials Science & Nanotechnology Mathematics Mechanical Engineering Physics Public Health Social Sciences Other

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AMOKSIMASI SIKLOHEKSANON DENGAN KATALIS MoO3/TS-1 MENGGUNAKAN HIDROGEN PEROKSIDA SEBAGAI AGEN PENGOKSIDASI Rakhmadi Harsanto; Imroatul Qoniah; Didik Prasetyoko; Ratna Ediati
Reaktor Volume 16 No.1 Maret 2016
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (503.686 KB) | DOI: 10.14710/reaktor.16.1.41-48

Abstract

AMMOXIMATION OF CYCLOHEXANONE OVER Mo-IMPREGNATED TITANIUM SILICALITE USING HYDROGEN PEROXIDE AS AN OXIDANT. Ammoximation of cyclohexanone reaction using 1% MoO3/TS-1 catalyst have been made with hydrogen peroxide as an oxidant. Reaction carried out with the batch method using methanol and acetonitrile as solvent. Reaction products analyzed using gas chromatography. The 1% MoO3/TS-1 catalyst shows the highest activity than the TS-1. The increased of 1% MoO3/TS-1 catalytic activity due to hydrophilicity properties higher than TS-1. Reaction using methanol shows the highest activity compared with reactions using acetonitrile. The optimum calcination temperature for 1% MoO3/TS-1 catalyst to gives the highest activity is 400 ºC.   Keywords: ammoximation of cyclohexanone; TS-1; 1% MoO3/ TS-1 Abstrak Amoksimasi sikloheksanon menggunakan katalis 1% MoO3/TS-1 telah dilakukan dengan menggunakan hidrogen peroksida sebagai agen pengoksidasi. Reaksi dilakukan dengan metode batch menggunakan pelarut metanol dan asetonitril. Produk reaksi dianalisis dengan kromatografi gas. Katalis 1% MoO3/TS-1 menunjukkan aktivitas katalitik yang lebih tinggi daripada katalis TS-1. Peningkatan aktivitas katalitik 1% MoO3/TS-1 dikarenakan sifat hidrofilisitasnya lebih tinggi dibandingkan TS-1. Reaksi katalisis yang menggunakan pelarut metanol memberikan aktivitas katalitik lebih tinggi daripada reaksi yang menggunakan pelarut asetonitril. Suhu kalsinasi paling optimum pada katalis 1% MoO3/TS-1 untuk memberikan aktivitas katalitik tertinggi adalah 400ºC. Kata kunci: amoksimasi sikloheksanon; TS-1; 1 % MoO3/ TS-1 
Nanoporous Carbon Prepared with MOF-5 as a Template and Activated using KOH for Hydrogen Storage Ratna Ediati; Tri Ana Mulyati; Amirul Mukminin; Dety Oktavia Sulistiono; Naimatul Khoiroh; Hamzah Fansuri; Didik Prasetyoko
Jurnal Kimia Valensi Jurnal Kimia VALENSI Volume 6, No. 1, May 2020
Publisher : Syarif Hidayatullah State Islamic University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1411.972 KB) | DOI: 10.15408/jkv.v6i1.13621

Abstract

A series of nanoporous carbon was prepared with MOF-5 as a template and furfuryl alcohol as an additional carbon source by carbonation at temperatures of 550 °C and 900 °C, respectively, with and without activation using KOH. XRD patterns of the obtained carbons before and after the activation process showed characteristic peaks at the same 2θ values, which corresponded to the XRD pattern of a ZnO. The Surface morphology of the MOF-5 templated carbon with a carbonation temperature of 550 °C was in the form of a cube. In contrast, the one carbonated at 900 °C had a cubic and circular morphology. The N2 adsorption-desorption isothermal showed that MOF-5 templated carbon had a larger specific surface area, pore diameter, and pore volume than those of the original MOF-5. Activation of the MOF-5 templated carbon using KOH resulted in a decrease in surface area and pore volume. All the materials were measured for their hydrogen adsorption at room temperature and atmospheric pressure using a gravimetric method.
THE PHENOL HYDROXYLATION USING A MoO3/TS-1 CATALYST THAT CALCINED ON THE VARIOUS TEMPERATURE Anis Farika; Syafsir Akhlus; Didik Prasetyoko
Jurnal Zeolit Indonesia Vol. 9 No. 2 (2010)
Publisher : Jurnal Zeolit Indonesia

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Abstract

MoO3/TS-1 catalyst has been proven have a higher catalityc activity rather than TS-1 on phenol hydroxylation reaction become a hydroquinone. Preparation catalyst using a impregnasi technique with ammonium molbidate as a precursor. Catalyst calcined at temperature 400-800°C and characterized by X-Ray Diffraction (XRD), pyridin adsorption, and hydrophilicity test. Calcinations temperature affects a catalyst characteristic and related to catalyst activity. MoO3/TS-1 catalyst has been calcined at temperature 400°C showed a higher hydrophilicity rather than TS-1, a faster speed reaction on phenol hydroxylation, and increasing of catalyst activity rather than initial catalyst, TS-1.
SYNTHESIS AND CHARACTERIZATION OF ZSM-5 MESOPOROUS WITH VARIATION RATIOS OF SiO2/Al2O3 Susi Nurul Khalifah; Didik Prasetyoko
Jurnal Zeolit Indonesia Vol. 7 No. 2 (2008)
Publisher : Jurnal Zeolit Indonesia

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Abstract

ZSM-5 Mesoporous with variation ratios of SiO2/Al2O3 20, 35, 50, and 100 have been successfully synthesized. Phase of mesoporous created using Cetyltrimethylammonium bromide (CTABr) templates. Crystal obtained has an acidity and higher thermal stability. Diffraction peaks typical of ZSM-5 appeared at 2θ = 7-9 ° and 2 θ = 23.02 °, while typical peak of mesoporous materi als appeared on 2θ
Crystal Growth of IRMOF-3 (Isoreticular Metal-Organic Frameworks-3) Synthesized using Solvothermal Method Pemta Tia Deka; Ratna Ediati; Didik Prasetyoko
IPTEK Journal of Proceedings Series Vol 1, No 1 (2014): International Seminar on Applied Technology, Science, and Arts (APTECS) 2013
Publisher : Institut Teknologi Sepuluh Nopember

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.12962/j23546026.y2014i1.416

Abstract

IRMOF-3 crystals have been synthesized using solvothermal method by reacting zinc nitrate hexahydrate with 2-amino-1,4-benzenedicarboxylic acid in N'N-dimethylformamide ( DMF ) at 100 °C for 18, 24, 48, 72, 120 and 144 h to observe crystal growth . The obtained crystals were characterized using X - ray Diffraction ( XRD ) , SEM ( Scanning Electron Microscopy ) and Scanning Electron Microscopy - Energy Dispersive X-ray ( SEM - EDX ). Diffractograms of crystals synthesized at heating times of 24 and 48 hours showed major peaks at 2θ of 6.8; 9.6 and 13.7, which are the characteristic peaks of an IRMOF-3 crystal. The size of IRMOF-3 crystals observed using SEM increased with the increase in heating time up to 48 h, then decreased at heating times of 72, 120 and 144 h. The largest IRMOF-3 crystal is of cube shape with a particle size of 500 µm. The weight of the resulting crystals increased with the increase in heating time, then remained constant after 72 h.
Synthesis of UiO-66 Using Solvothermal Method at High Temperature Ika Diah Rahmawati; Ratna Ediati; Didik Prasetyoko
IPTEK Journal of Proceedings Series Vol 1, No 1 (2014): International Seminar on Applied Technology, Science, and Arts (APTECS) 2013
Publisher : Institut Teknologi Sepuluh Nopember

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.12962/j23546026.y2014i1.417

Abstract

UiO-66 solids have been synthesized using solvothermal method in which reaction mixtures of zirconium tetrachloride (ZrCl4) and 1,4-benzenedicarboxylic acid (BDC) in N-N'-dimethylformamide (DMF) were heated at 140 °C for 6, 12, 24, 36, 48, 72 and 144 hours, respectively. The weight of reaction products, in the form white powder, increased with the increase in heating time up to 72 hours, then decreased. Characterization results using XRD showed that the diffractogram of the solid obtained at heating time of 6 h had the same pattern to that of reported UiO-66, characterized by a main peak with a high intensity at 2θ of 7.3°, as well as other characteristic peaks with lower intensity at 2θ of 8.4°; 25.6° and 30.6°. The longer the heating time (12 and 24 h), the lower the intensity of the main peak. When the reaction mixtures were heated for 36 h or longer, the obtained solid diffractograms showed that the main peak intensity at 2θ of 7.3° was lower than the second peak, and new peaks appeared at 2θ of 13.8°; 15.8° and 17.5°. SEM micrographs showed that the solid synthesized for 6 h was in the form of clusters of square morphology, whereas solids synthesized for 72 h showed needle-like surface morphology
Synthesis and Characterization of Low Loading MoO3/Ts-1 Catalyst Suci Indrayani; Didik Prasetyoko
IPTEK The Journal for Technology and Science Vol 19, No 4 (2008)
Publisher : IPTEK, LPPM, Institut Teknologi Sepuluh Nopember

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.12962/j20882033.v19i4.144

Abstract

Abstract⎯Molybdenum oxide (MoO3) have been introduced to titanium silicalite (TS-1) by impregnation methode and have been characterized with X-ray diffraction (XRD), infrared spectroscopy, nitrogen and pyridine adsorption. The results show that TS-1 and XMoO3/TS-1 have orthorhombic structure and MFI framework structure type. 0,5% MoO3/TS-1, dan 1% MoO3/TS-1 catalyst have not been yet Brønsted acid site, while Brønsted acidity increased from 2% MoO3/TS-1 to 4% MoO3/TS-1 respectively.
Pore Structure and Morphology Characterizations of Mesoporous ZSM-5 Synthesized at Various Aging Time Djoko Hartanto; Tri Esti Purbaningtias; Hamzah Fansuri; Didik Prasetyoko
Jurnal ILMU DASAR Vol 12 No 1 (2011)
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Jember

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (473.394 KB)

Abstract

Mesoporous ZSM-5 has been successfully synthesized at various aging time of 6, 12 and 24 h. Mesoporous ZSM-5 was synthesized using cetyltrimethylammonium bromide (CTABr) as a template. Synthesis was carried out hydrothermally with aging and crystallization temperature at 60oC and 150oC. XRD patterns of the resulted material showed diffraction lines at 2θ = 23o and at small angle (2θ < 5o) which is characteristic of the structure of ZSM-5 and the existing of the mesoporous material. It was found that crystallinity of the sample increased at longer aging time. The result of nitrogen gas sorption analysis showed that all samples have pore size about 3,8 nm. The porosity of ZSM-5 decreased with shorter of aging time. ZSM-5 synthesized at 6 h aging time has the highest porosity of 72.57%. Aging time also affected the particle size, the longer the aging time, the smaller the particle size. The particle size was ranging 1.25 – 1.0 μm.
Phase Transformation of Rice Husk Ash in the Synthesis of ZSM-5 without Organic Template Didik Prasetyoko; Neneng Ayunanda; Hamzah Fansuri; Djoko Hartanto; Zainab Ramli
Journal of Mathematical and Fundamental Sciences Vol. 44 No. 3 (2012)
Publisher : Institute for Research and Community Services (LPPM) ITB

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/itbj.sci.2012.44.3.5

Abstract

Phase transformation of rice husk ash in the synthesis of ZSM-5 without organic template at various crystallization times has been studied. Zeolite has been synthesized using the hydrothermal method at 175 °C with molar ratio 10Na2O : 100SiO2 : 2Al2O3 : 1800H2O with addition of silicalite-1 as seed. Solids were characterized using X-ray diffraction (XRD), infrared (IR) spectroscopy and scanning electron microscopy (SEM) techniques. Analysis of the results of XRD and IR spectroscopy indicated that ZSM-5 crystalstarted to form at 12 h of crystallization time, reaching high crystallinity after 24 h. With a crystallization time of more than 48 h, the ZSM-5 crystals had completely transformed into more stable quartz phase. Results indicated that phase transformation has occurred, in which an amorphous phase of rice husk ash has been transformed to ZSM-5 crystal phase during the early crystallization stage and continued to transform to disordered α-cristobalite phase and lastly quartz phases. SEM showed that the morphology of the ZSM-5 crystal was of an irregular hexagonal shape with particle size distribution around 3-7 μm.
Influence of TiO2/TS-1 Calcination on Hydroxylation of Phenol Ratna Ediati; Maria Ulfa; Hamzah Fansuri; Zainab Ramli; Hadi Nur; Didik Prasetyoko
Journal of Mathematical and Fundamental Sciences Vol. 46 No. 1 (2014)
Publisher : Institute for Research and Community Services (LPPM) ITB

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/j.math.fund.sci.2014.46.1.7

Abstract

Titanium oxide (TiO2) was impregnated on the surface of titanosilicate-1 (TiO2/TS-1) and used as catalyst for hydroxylation of phenol with hydrogen peroxide. Calcination was conducted at various temperatures (400, 500, 600 and 700°C)in order to observe the effect on the structure and physicochemical properties towards catalytic activity for producing hydroquinone. The structure and physicochemical properties of the TiO2/TS-1 catalyst were characterized by several techniques, such as X-ray diffraction (XRD), infrared spectroscopy, nitrogen adsorption, pyridine adsorption and hydrophilic measurement. The results show that by increasing the calcination temperature,the surface acidity of the catalyst was also increased.TheTiO2/TS-1 catalyst calcined at 500°Cproved to be optimal for hydroquinone production, in which the anatase-rutile phase may be present dispersed on the MFI framework.
Co-Authors Abdul Hamid Abdul Hamid Abdul Hamid Abdulloh Abdulloh Adi Setyo Purnomo Afifah Rosidah Afifah Rosyidah Ahmad Anwarud Dawam Ahmad Anwarud Dawam Ahmad Anwarud Dawam Ahmad, Shahrul Nizam Aishah Abdul Jalil Aishah Abdul Jalil Aishah Abdul Jalil Aishah Abdul Jalil Alfa Akustia Widati Alya Awinatul Rohmah Amalia Putri Purnamasari Amin Jakfar, S.T.,M.T., Lukman Hadiwijaya, S.T.,M.T. Amirul Mukminin Anil Kumar Anal Anis Farika Anis Farika, Anis Arief Fadlan Arizal Firmansyah Asranudin Asranudin, Asranudin Badzlin Nabilah Bayu Wiyantoko Cepi Kurniawan Che Ku Nor Liana Che Ku Hitam Cholifah Endah Royani Cicik Herlina Yulianti Desy T. Kusumaningtyas Desy Tri Kusumaningtyas Dety Oktavia Sulistiono Dewi, Nita Safira Didi Dwi Anggoro Djoko Hartanto Djoko Hartanto Djoko Hartanto Dyah Ayu Fatmawati Dyah Fitasari Eka Pratiwi Yuniarti Eka Putra Ramdhani Eko Santoso Endang Purwanti Endud, Salasiah F Widhi Mahatmanti Farhanah Thalib Fensia Analda Souhoka Firda, Putri Bintang Dea Futri Wulandari H. Holilah Hadi Nur Hadi Nur Hadi Nur Hamzah Fansuri Haq, Ismi Arinal Harjito - Harjito Harjito Harmami Harmami Hartati Hartati Hartati Hartati Hasliza Bahruji Hasliza Bahruji Hasliza Bahruji Hasliza Bahruji Hellna Tehubijuluw Hendro Nurhadi Ika Diah Rahmawati Ike Dayi Febriana Imroatul Qoniah Imroatul Qoniah Imroatul Qoniah Imroatul Qoniah Imroatul Qoniah Imroatul Qoniah Izzah, Adiba Naila Kris Murwani, Irmina Kurniawati, Puji Kurniawati, Puji Kusumawati, Yuly Le Monde, Brilliant Umara Leaw Wai Loon Lely Dwi Astuti Lisa Amalia Suryana Lukman Atmaja Mardi Santoso Maria Ulfa Maria Ulfa Maria Ulfa Meiske S Sangi Meyga E. F. Sari Meyga Evi Ferama Sari Mohammad Abdullah Mudasir Mudasir Muhammad Lukman Hakim Muhammad Nur Kholis Muhammad Nur Kholis Mulyatun Mulyatun Naimatul Khoiroh Nanik Siti Aminah Nanik Wijayati Neneng Ayunanda Novesar Jamarun Nuni Widiarti Nur, Hadi Nurdiani, Maulida Nurul - Widiastuti Pemta Tiadeka Puji Kurniawati Qurrota A’yuni R.Y. Perry Burhan, R.Y. Perry Rahayu, Endah Fitriani Rakhmadi Harsanto Ramli, Zainab Ratna Ediati Ratna Ediati Reva Edra Nugraha Safa Annissa Novianti Salasiah Endud Samuel Budi Wardhana Samuel Budi Wardhana Kusuma Santi Wulan Purnami Sirly Bifadilatur Romaniyah Siti Maryam Subagyo, Riki Suci Indrayani Sugeng Triwahyono Sugeng Triwahyono Sugeng Triwahyono Sugeng Triwahyono Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto Suprapto, Suprapto Suprapto, Surapto Susi Nurul Khalifah Syafsir Akhlus Syafsir Akhlus, Syafsir Tanti Kartika Dewi Taufiq Rinda Alkas Teguh Endah Saraswati Tikha Reskiani Fauziah Titie Prapti Oetami Titie Prapti Oetami Tri Ana Mulyati Tri Esti Purbaningtias Tri Wahyuni Tri Wahyuni Tri wahyuni Triyono Triyono Triyono Triyono Wahyu Bambang Widayatno Wega Trisunaryanti Wega Trisunaryanti Wega Trisunaryanti Wijianto, Wijianto Wiyantoko, Bayu Wiyantoko, Bayu Yatim Lailun Ni’mah Yoshifumi Chisaki Yulinar Dwi Nur Azizah Yusuf Muhammad Zein Yusuf Muhammad Zein Yuvita Eka Pertiwi Zahrotul Istiqomah Zainab Ramli Zainab Ramli Zainab Ramli Zainab Ramli Zakaria, Zaki Yamani Zeni Rahmawati Zetra, Yulfi