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Journal : International Journal of Renewable Energy Development

Nickel-vanadium impregnated to hydrotalcite for hydrocracking of waste cooking oil Marlinda, Lenny; Priyanto, Sugeng; Oktiarmi, Peri; Marbun, Maja Pranata; Dewi, Aisha Andini Indira; Sudibyo, Sudibyo; Yati, Indri; Aziz, Abdul; Nugraha, Reva Edra; Al Muttaqii, Muhammad
International Journal of Renewable Energy Development Vol 15, No 3 (2026): May 2026
Publisher : Center of Biomass & Renewable Energy (CBIORE)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.61435/ijred.2026.61972

Abstract

Hydrotalcite (HT) is a type of clay mineral belonging to the group of layered double hydroxides (LDHs) or anionic clays, which has a layered structure like brucite (Mg(OH)₂), but some of the divalent cations (such as Mg²⁺) are replaced by trivalent cations (such as Al³⁺). HT as a heterogeneous catalyst is particularly attractive because it is easy to separate and resistant to high temperatures. HT as a catalyst can be used in hydrocracking reaction to produce biofuel. Metal impregnation on HT is very promising to enhance catalytic activity especially with the bifunctional mechanism of catalyst. Ni-V metal impregnation has been successfully carried out on HTc using wet impregnation method which is indicated by the results of X-Ray Diffraction (XRD) which shows the emergence of typical peaks of both metals and HTc in 2θ = 35‒70⁰ for HTc, 2θ = 37.22⁰ (NiO) and 37.35⁰ (V2O5) regions, 2θ = 43.58⁰ for NiO, 2θ = 61.26⁰ (V) and 63.07⁰ (Ini). Scanning Electron Microscopy-Energy Dispersive X-ray (SEM-EDX) show a shape that is consistent with the characteristics of HT, namely the shape of the particles layered overlapping each other. In addition, the particle size of HTc is quite small with a scale of 1 μm indicating a particle size of hundreds of nanometers. EDX mapping shows that Ni and V have been dispersed evenly on the HTc surface. Based on the results of N2 adsorption-desorption isotherms, it shows that mesopores are formed which are characterized by hysteresis loops. Ni-V metal impregnation increases the surface area up to 19.915 m2/g and the pore diameter up to 37,642 nm. The results of the Waste Cooking Oil (WCO) hydrocraking reaction show that Ni-V metal impregnation can reduce the carboxylic acid composition up to 67.81% and increase hydrocarbons up to 15% at 10% Ni-V/HTc 1:2. 
Co-Authors Abdul Aziz Abdul Hakim Achmad Ridwan, Achmad agung setiawan Agus Dudung Aip Badrujaman Al Muttaqii, Muhammad Anggraeny, Enny Anggrainy, Rani Arianda, Yoga Dwi Arisudhana, Dicky Awalia, Valent Adnandhiya Awaluddin Tjalla AZ Purwono Budi Santosa, AZ Purwono Budi Aziz, Abdul C. Rudy Prihantoro Deden Kurniawan Dewi Nur Utami Dewi, Aisha Andini Indira Erdawati Erdawati, Erdawati Erik Prasetyo FAISAL MADANI Fauziah, Sarah Ferry Budhi Susetyo H Purnomo, H Hamzah, Rohman Hari Krisyono , Danar Haryani Haryani Hidayah, Nursipah Imam Nursyahied Indah Rahayu Lestari Indrajit, Eko Irrine Budi Sulistiawati Iva Sarifah Kartono , Krisyono, Danar Hari Kusuma, Dani Laksmiwati, Mia Larasati, Amira Larasati, Andini Ayu Lenny Marlinda Lubi, Ahmad Marbun, Maja Pranata Mardiana, Yushi MARIA BINTANG Maryani, Tri MATURBONG, RIRIN KATARINA Merrydian, Siska Muhamad Yusup , Fahmi Muhktar Anshori, Muhktar Muljanto, Widodo Pudji MULYANTO, WIDODO PUDJI N, Ariesta Nugraha, Hari Din Nugrahani, Romdha Nurcahya, Fikri Nurmasari, Anita Nurwijayanti Oktaviani, Maya Peri Oktiarmi Pertiwi, Sri Endah Raden Mohamad Herdian Bhakti Ramdhani, Luthfi Ilham Refni, Evi Reva Edra Nugraha Rini, Indah Mustika Riyadi Riyadi Riza Alviany Rohman, Fakhrony Sholahudin S Setyo Wardoyo, S Setyo Salam, Muhammad Farhan Santiko, Erik Budi Selamet Riyadi Sibuea, Andreas Silalahi Raja, Havier Samuel Huttur Siradjuddin, Hairil Kurniadi Siti Sahara Sudibyo Sudibyo Sukestiyarno Sukestiyarno Suwondo Suwondo Syafaat AM, Fuad Syahrir Syahrir Syaripuddin Togatorop, Elida Triastuti Sulistyaningsih Tyassmadi, Adi Tri Wardani Rahayu Wasinton Simanjuntak Winarno, Pujo yati, indri Yudanto, Sigit Dwi Yustinah Yustinah Yuwono Yuwono Zakiyyah, Salma