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Pengaruh penambahan fly ash PLTU Cirebon dan temperatur pengeringan terhadap kuat tekan material konstruksi beton High Volume Fly Ash (HFVA) Anggara, Ferian; Sujoto, Vincent Sutresno Hadi; Tangkas, I Wayan Christ Widhi Herman; Astuti, Widi; Sumardi, Slamet; Putra, Ilham Satria Raditya; Putra, Agik Dwika; Petrus, Himawan Tri Bayu Murti
Jurnal Rekayasa Proses Vol 17, No 2 (2023)
Publisher : Departemen Teknik Kimia Fakultas Teknik Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/jrekpros.77825

Abstract

Penggunaaan batubara sebagai sumber energi di negara berkembang seperti Indonesia masih menjadi pilihan utama. Hasil samping pembakaran batubara di Pembangkit Listrik Tenaga Uap (PLTU) berupa fly ash dan bottom ash (FABA) akan terus meningkat seriring konsumsi bataubara sebagai energi meningkat. Industri semen dapat mengahsilkan 2,9 miliar ton CO2 ke atmosfer hal ini akan berdampak langsung terhadap kenaikan temperatur bumi dan pemansan global. Subtitusi material semen dengan fly ash menjadi sebuah pilihan yang ramah lingkungan dalam meminimalisir gas CO2. Pembuatan beton dimulai dengan mencampurkan fly ash dan semen pada berbagai rasio (1:1; 1:3 ; 1:4) dengan air. Air dituang secara bertahap sedikit demi sedikit sambil diaduk hingga membentuk pasta. Pasta beton yang telah terbentuk dicetak pada cetakan kubus ukuran 5x5x5 cm3. Cetakan pasta HVFA didiamkan selama 1 hari, kemudian dikeringkan (curing) pada temperatur yang divariasikan (30, 40 dan 60°C). Hasil Analisa oksida komponen kimia menunjukan bahwa fly ash dari PLTU Cirebon tergolong kategori fly ash kelas C dengan kadar CaO lebih dari 10% dan SiO2 kurang dari 46% dan Kekuatan beton (compressive strength) HVFA yang  paling besar yang dapat dihasilkan beton HVFA adalah pada rasio komposisi semen dan fly ash 1:3 dengan temperatur pengeringan 40°C. material fly ash mampu menggantikan semen sebesar 75% dari kebutuhan beton HVFA dengan kekuatan beton mencapai 12,557 MPa pada kondisi pengeringan 40°C. Hasil optimasi menunjukan variable yang paling berpengaruh terhadap kuat tekan beton yang dihasilkan adalah temperatur pengeringan.
Jurnal rekayasa proses submission update Petrus, Himawan Tri Bayu Murti
Jurnal Rekayasa Proses Vol 17, No 2 (2023)
Publisher : Departemen Teknik Kimia Fakultas Teknik Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/jrekpros.92642

Abstract

Pembaruan informasi pengumpulan Jurnal Rekayasa Proses Petrus, Himawan Tri Bayu Murti
Jurnal Rekayasa Proses Vol 17, No 2 (2023)
Publisher : Departemen Teknik Kimia Fakultas Teknik Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/jrekpros.92643

Abstract

Optimization of Lithium Separation from NCA Leachate Solution: Investigating the Impact of Feed Concentration, Pressure, and Complexing Agent Concentration Mustika, Pra Cipta Buana Wahyu; Suryanaga, Edward Chandra; Perdana, Indra; Sutijan, Sutijan; Astuti, Widi; Petrus, Himawan Tri Bayu Murti; Prasetya, Agus
ASEAN Journal of Chemical Engineering Vol 23, No 3 (2023)
Publisher : Department of Chemical Engineering, Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ajche.83096

Abstract

Recycling lithium batteries (LIB) has emerged as an attractive solution in the global pursuit of environmentally friendly practices. The aim of achieving zero–waste hydrometallurgical technology is within reach. This research focuses on utilizing the low-pressure nanofiltration process to address this challenge by separating lithium ions from other ions and achieving a desirable permeate flux. The NCA battery leachate concentrate was obtained through a hydrometallurgical process involving sulfuric acid–peroxide. To ensure the prevention of potential nanofiltration membrane (TS80) fouling, the concentrate is initially filtered using an ultrafiltration membrane (UH004) to remove any particles. The research investigates the impact of pressure (4, 6, and 7 bar), solution concentration (concentrate, 10x, and 50x dilution), and the concentration of the complexing agent (EDTA) on the desired separation performance. The investigation reveals that pressure variations exhibit consistent rejection rates, remaining stable above 80%. A similar trend is observed with the addition of EDTA, which consistently yields rejection rates above 80%. However, when examining different feed concentrations, the rejection of lithium falls below 80% for leachate concentrates. In summary, satisfactory results are obtained by employing nanofiltration with a TS80 membrane at a pressure of 7 bar, a dilution factor of 10x, and using a 0.02M EDTA complexing agent. Meanwhile, it was found that the separation factors (Li⁺/Ni²⁺ = ~8.6, Li⁺/ Co²⁺ = ~7.3, Li⁺/Al³⁺ = ~4.9) and permeate flux ±46.58 L m⁻² h⁻¹. The findings demonstrate good selectivity along with relatively high flux.
Sintesis Copper-Nanoparticles dari Limbah Leaching Kalkopirit Sebagai Zat Antibakteri dengan Metode Reduksi Wibowo, Decka Pynka; Kusumastuti, Yuni; Prasetya, Agus; Asih, Yekti; Petrus, Himawan T.B.M; Idrus, Arifudin
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
Publisher : Seminar Nasional Teknik Kimia "Kejuangan"

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Abstract

Nanoparticle technology has been widely used in various industries because of its advantages in particle size control systems. One example of the use of nanoparticle technology is copper nanoparticles as an antibacterial material. This research focuses on the utilization of leaching waste as a material for the synthesis of copper nanoparticles. The synthesis of copper nanoparticles was carried out by chemical reduction method between chalcopyrite stone leaching waste namely CuSO4 as precursor, Cetyl Trimethyl Ammonium Bromide (CTAB) as surfactant and NaBH4 reducing agent. The synthesized material will be analyzed using UV-Vis spectroscopy. Furthermore, the particle size will be estimated using PSA and its antibacterial properties will be analyzed using the well diffusion method by looking at the effectiveness of the inhibitory power against Escherichia coli FNCC 0049 and Staphylococcus bacteria aureus FNCC 0047. The results of the synthesis obtained the smallest size of 235.7 nm from the ratio of precursor concentration, reducing agent concentration and, a surfactant concentration of 1:20:8. The results of the synthesis of copper nanoparticles with concentrations of 10.000 ppm showed the presence of inhibitory power to overcome Escherichia coli FNCC 0049 and Staphylococcus bacteria aureus FNCC 0047.
Studi Recovery Tembaga pada Proses Froth Flotation dari Bijih Tembaga Papua, Indonesia dengan Variasi pH dan Konsentrasi Kolektor Heimbach, Ivano; Petrus, Himawan Tri Bayu Murti; Prasetya, Agus; Idrus, Arifudin; Timotius, Daniel; Kusumastuti, Yuni; Sutijan, Sutijan
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
Publisher : Seminar Nasional Teknik Kimia "Kejuangan"

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Abstract

In the process of flotation of copper-bearing ore, several factors such as the concentration of the collector used and the pH of the fluid used can have an impact. In this study, observations were made on the influence of collector concentration and pH on the recovery of copper ores from Papua, Indonesia. The ore samples were obtained from three different site. Preparation of samples were conducted by crushing and sieving to obtain solid particles with a size of +200 mesh. The fine particles then fed into froth flotation device. Froth flotation operations were carried out at different operating condition namely pH (pH 3, pH 6, and pH 9), xanthate concentration (1300, 2000, and 2600 ppm), and time (3, 5, 7, and 14 minutes). The froth and tailings were collected separately and dried in an oven at 60oC. The feed, froth, and tailings were then subjected to EDX analysis to determine their compositions. The results of the experiment showed that higher collector concentrations did not necessarily lead to increased copper recovery. The appropriate pH conditions, however, could optimize copper recovery. The optimum conditions obtained from this experiment were xanthate concentration of 2000 ppm, pH of 3, and the ore sample 2
Bioremediation of Mercury- Polluted Water in Free Water Surface-Constructed Wetland System by Euglena sp. and Echinodorus palifolius (Nees & Mart.) J.F. Macbr. Siswanti, Dwi Umi; Daryono, Budi Setiadi; Petrus, Himawan Tri Bayu Murti; Suyono, Eko Agus
Journal of Tropical Biodiversity and Biotechnology Vol 8, No 3 (2023): December
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/jtbb.88143

Abstract

Mercury accumulation in the aquatic environment can be highly harmful. The body takes mercury vapor through the lungs, then absorbs mercury metal through the digestive system, and then the blood carries the metal to the brain. Bioremediation is the process of breaking down or converting harmful compounds into non-toxic forms, which can be accomplished through phytoremediation or phycoremediation. The goal of this study was to examine the growth and anatomy of Euglena sp. after being cultured in the mercury-containing FWS-CW waste treatment system. The ability of Euglena sp. and Echinodorus palifolius to bioremediate mercury at different concentration as well as association and non-association treatments. This study was carried out in a bioreactor known as FSW-CW (Free Water Surface-Constructed Wetlands). Plant growth (plant height and number of leaves), chlorophyll content, diameter of root and petiole, metaxylem diameter of root, petiole, and leaves, cortical thickness of root and leaves, and petiole anatomy were all measured. Water temperature, pH, salinity, and light intensity were all measured as environmental parameters. Mercury treatment reduced Euglena density (183.5 cells. mL-1103 in control and 12.6 cells. mL-1103 in 100 ppm mercury treatment) and number of E. palifolius leaves, but not plant height and chlorophyll. Root and petiole diameters were affected by the mercury treatment, petiole diameter decreased unless the concentration was 100 ppm, whereas root diameter actually increased. The diameter of the root metaxylem increased, but the petioles and leaves, as well as the thickness of the root cortex, did not provide a significant response. The growth of E. palifolius was still optimal in the presence of Euglena in mercury-containing medium. 
Bimetallic Ni-Fe Supported by Gadolinium Doped Ceria (GDC) Catalyst for CO2 Methanation Kristiani, Anis; Takeishi, Kaoru; Jenie, Siti Nurul Aisyiyah; Petrus, Himawan Tri Bayu Murti
Bulletin of Chemical Reaction Engineering & Catalysis 2024: BCREC Volume 19 Issue 1 Year 2024 (April 2024)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.20108

Abstract

CO2 conversion into fuels and high value-added chemical feedstocks, such as methane, has gained novel interest as a crucial process for further manufacturing multi-carbon products. Methane, CH4, becomes a promising alternative for environmental and energy supply issues. Nickel-based catalysts were found to be very active and selective for CH4 production. The use of promoter and support material to develop high activity, high selectivity, and durable catalysts for CO2 methanation at low temperature is a challenge. Gadolinium-Doped Ceria (GDC) has been known as material for Solid Oxide Fuel Cell (SOFC) and Solid Oxide Electrolysis Cell (SOEC) due to higher ionic conductivity and lower operating temperatures. However, few researches have been done regarding to CO2 methanation over GDC as catalyst support so far. In this present work, CO2 methanation was investigated over bimetallic Ni-Fe catalyst supported by GDC. The results showed that CH4 production rate by using Ni-Fe/GDC catalyst was higher than that of GDC at all reaction temperatures carried on. Ni-Fe/GDC showed remarkable CH4 production rate as of 17.73 mmol.gcat−1.h−1 at 280 °C. No catalytic activity was produced by GDC catalyst only. The highest CO2 conversion (46.50%) was observed at 280 °C, with almost 100% selectivity to CH4. The turnover frequency (TOF) value of Ni-Fe/GDC (4529.32 h−1) was the highest than that of Ni and common CO2 methanation catalyst, Ni/Al2O3 catalysts at 280 °C, further displaying the outstanding low-temperature catalytic activity. Copyright © 2024 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).
Penentuan kondisi optimum pembuatan silica gel menggunakan silika geothermal dengan metode sol-gel Sujoto, Vincent Sutresno Hadi; Tangkas, I Wayan Christ Widhi Herman; Astuti, Widi; Sumardi, Slamet; Jenie, Siti Nurul Aisyiyah; Tampubolon, Aron Pangihutan Christian; Syamsumin, Syamsumin; Utama, Andhika Putera; Petrus, Himawan Tri Bayu Murti; Kusumastuti, Yuni
Jurnal Rekayasa Proses Vol 17, No 2 (2023)
Publisher : Departemen Teknik Kimia Fakultas Teknik Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/jrekpros.77696

Abstract

Salah satu permasalahan yang muncul di lapangan pembangkit listrik panas bumi (PLTP) adalah terjadinya silica scaling dalam sistem pemipaaan akibat konsentrasi padatan terlarut yang tinggi pada air geotermal (geothermal brine). Silica scalling dapat menyebabkan penurunan efisiensi pembangkitan energi listrik dari panas bumi. Pada penelitian ini lumpur silika yang dihasilkan dari lapangan pembangkit listrik panas bumi akan dimanfaatkan sebagai raw material sintesis silica gel. Silica gel disintesis menggunakan metode sol-gel dengan variasi rasio natrium silikat dan air (1:3 ; 1:4 ; dan 1:5) dan konsentrasi asam klorida ( 0,5 M ; 1 M; dan 2 M). Karakteristik silica gel dilihat menggunakan analisis Forier Transform Infra Red (FTIR). Secara umum, pita serapan yang muncul pada spektra sample silica gel menunjukkan bahwa gugus fungsional yang terdapat pada silica gel adalah gugus silanol (Si-OH) dan gugus siloksan (Si-O-Si). Panjang gelombang 1055,86 cm-1­ menunjukkan gugus Si-O, yang mengindikasikan adanya vibrasi SiO4 dan polimerisasi Si-O-Si saat pembentukan silica gel. Selain itu, kapasitas penjerapan air oleh silika gel menunjukkan bahwa sampel dengan kode A7 memiliki kapasitas penjerapan air terbesar, yaitu mencapai 0,9331 gr air/ gram silica gel. Analisis Response Surface Methodology (RSM) mengindikasikan bahwa konsentrasi asam memberikan pengaruh singnifikan terhadap pembentukan silica gel dibandingkan dengan variasi pengenceran natrium silikat.
Pengaruh penambahan fly ash PLTU Cirebon dan temperatur pengeringan terhadap kuat tekan material konstruksi beton High Volume Fly Ash (HFVA) Anggara, Ferian; Sujoto, Vincent Sutresno Hadi; Tangkas, I Wayan Christ Widhi Herman; Astuti, Widi; Sumardi, Slamet; Putra, Ilham Satria Raditya; Putra, Agik Dwika; Petrus, Himawan Tri Bayu Murti
Jurnal Rekayasa Proses Vol 17, No 2 (2023)
Publisher : Departemen Teknik Kimia Fakultas Teknik Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/jrekpros.77825

Abstract

Penggunaaan batubara sebagai sumber energi di negara berkembang seperti Indonesia masih menjadi pilihan utama. Hasil samping pembakaran batubara di Pembangkit Listrik Tenaga Uap (PLTU) berupa fly ash dan bottom ash (FABA) akan terus meningkat seriring konsumsi bataubara sebagai energi meningkat. Industri semen dapat mengahsilkan 2,9 miliar ton CO2 ke atmosfer hal ini akan berdampak langsung terhadap kenaikan temperatur bumi dan pemansan global. Subtitusi material semen dengan fly ash menjadi sebuah pilihan yang ramah lingkungan dalam meminimalisir gas CO2. Pembuatan beton dimulai dengan mencampurkan fly ash dan semen pada berbagai rasio (1:1; 1:3 ; 1:4) dengan air. Air dituang secara bertahap sedikit demi sedikit sambil diaduk hingga membentuk pasta. Pasta beton yang telah terbentuk dicetak pada cetakan kubus ukuran 5x5x5 cm3. Cetakan pasta HVFA didiamkan selama 1 hari, kemudian dikeringkan (curing) pada temperatur yang divariasikan (30, 40 dan 60°C). Hasil Analisa oksida komponen kimia menunjukan bahwa fly ash dari PLTU Cirebon tergolong kategori fly ash kelas C dengan kadar CaO lebih dari 10% dan SiO2 kurang dari 46% dan Kekuatan beton (compressive strength) HVFA yang  paling besar yang dapat dihasilkan beton HVFA adalah pada rasio komposisi semen dan fly ash 1:3 dengan temperatur pengeringan 40°C. material fly ash mampu menggantikan semen sebesar 75% dari kebutuhan beton HVFA dengan kekuatan beton mencapai 12,557 MPa pada kondisi pengeringan 40°C. Hasil optimasi menunjukan variable yang paling berpengaruh terhadap kuat tekan beton yang dihasilkan adalah temperatur pengeringan.
Co-Authors Achmad Roesyadi Adha Priyawan, Adha Adiatama, Aufa Rai Adythia, Dicky Marsa Agus Haerudin Agus Prasetya Agus Prasetya Ahmad Tawfiequrrahman Yuliansyah Akbar Yulandra Althea Farina Atmaja, Althea Farina Anastasia Prima Kristijarti Andi Nurfaadilah Ulfah Angelia, Annasthasya Milleni Anis Kristiani, Anis Aprilianto, Doni Riski Ardyanto Wijaya Arham, La Ode Arifudin Idrus Arini Nur Utami Asih, Yekti Aulia Pertiwi Tri Yuda Bahri, Elsha Pamida Bangun, Aya Shika Bratakusuma, Danu Bratakusuma, Danu BUDI SETIADI DARYONO Christopher Mario Hananto Chusnul Khotimah Cipta Panghegar Supriadi D Bratakusuma Dagus Resmana Djuanda Danu Bratakusuma Danu Bratakusuma Dea Anisa Ayu Besari Devi, Fatma Putrinta Dewi Purnama Sari Dewi Purnama Sari Dewi, Jilda Sofiana Dwi Umi Siswanti Dwi Wiji Lestari Edward Yonathan Natapraja Eko Agus Suyono Elsha Pamida Bahri Fahrurozi, Mohammad Fajar Nurjaman Fajar Nurjaman Fathan Bahfie Febry Yulindra Abdi Saputra Federick Dwi Putra Federick Dwi Putra Felisha Hapsari Tanujaya Felisha Hapsari Tanujaya Felix Arie Setiawan Ferian Anggara Fika Rofiek Mufakhir Fika Rofiek Mufakhir Fika Rofiek Mufakir Fika Rofiek Mufakir Fika Rofieq Mufakhir Franky Michael Hamonangan Siagian Gelar Panji Gemilar Gelar Panji Gemilar Gemilar, Gelar Panji Gyan Prameswara Hafid Zul Hakim Halomoan Siagian Harta Haryadi, Harta Hazmi, Fariz Al Heimbach, Ivano Hendrik Setiawan Hendrik Setiawan, Hendrik Himmah Sekar Eka Ayu Agustina Hotden Manurung Hotden Manurung I Gde Sukadana I Made Bendiyasa I Wayan Christ Widhi Herman Tangkas I Wayan Warmada Iga Trisnawati Iga Trisnawati Indra Perdana Indra Perdana Indra Perdana Indra Perdana Istihanah Nurul Eskani Ivanna Crecentia Narulita Simanungkalit Jayawarsa, A.A. Ketut Jonas Kristanto Joni Setiawan Kevin Cleary Wanta Kinanti, Divita Hayyu Kristanto, Jonas Kurniawansyah, Firman Laksono Trisnantoro Marizka Aviana Permatasari Mita Kusumaningrum, Mita Mufakhir, Fika Rofiek Mufakhir, Fika Rofieq Muhammad Miftahur Rahman Mustika, Pra Cipta Buana Wahyu Nadya Fardani, Nadya Nasution, Yogi Tri Putra Natalia, Priskila Patria, Aulia Agus Perbawati, Esti Kukuh Poernomo, Venny Pratiwi, Fadiah Putra, Agik Dwika Putra, Ilham Satria Raditya Radinda Bian Zaqina, Radinda Bian Rahman, Muhammad Irfan Rahman, Muhammad Miftahur Ramadhany, Putri Ratna Frida Susanti Rika Ernawati Riyadi, Delfimelinda Nurul RR. Ella Evrita Hestiandari Salafudin Salafudin, Salafudin Shinta Virdhian Shinta Virdhian shinta virdhian, shinta Siagian, Franky Michael Hamonangan Simanungkalit, Ivanna Crecentia Narulita Siti Nurul Aisyiyah Jenie, Siti Nurul Aisyiyah Slamet Sumardi Slamet Sumardi Slamet Sumardi, Slamet Soesaptri Oediyani Stephen Lim Stevanus Adi Darma Sujoto, Vincent Sutresno Hadi Supit, Jance Mudjani Suprabanindya, Caecilia Tridjata Supriadi , Cipta Panghegar Supriyatna, Yayat Iman Surianti Surianti Suryanaga, Chandra Edward Suryanaga, Edward Chandra Sutijan Sutijan Sutijan Sutijan Sutopo, Ulung Syamsumin Syamsumin, Syamsumin Takeishi, Kaoru Tampubolon, Aron Pangihutan Christian Tangkas, I Wayan Christ Widhi Herman Taufik Hery Purwanto Timotius, Daniel Trisnawati, Iga Ulfah , Andi Nurfaadilah Ulin Herlina Ulung Sutopo Utama, Andhika Putera Utomo, Dimas Bagus Galih Vincent Sutresno Hadi Sujoto Wahyu Rachmi pusparini Wahyu Yun Santoso Wibowo, Decka Pynka Widi Astuti Widi Astuti Widi Astuti Widi Astuti Widi Astuti Widi Astuti Widi Astuti Widi Astuti Widi Astuti Widi Astuti Widi Astuti Widi Astuti Widi Astuti Widi Astuti Widya Rosita Wijaya, Ardyanto Wiratni Wiratni Wiratni Wiratni, Wiratni Y Iskandar Yogi Tri Putra Nasution Yuda, Aulia Pertiwi Tri Yuni Kusumastuti, Yuni Yuniati, Mutia Dewi Yusuf Iskandar