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Journal : Science and Technology Indonesia

Nickel Salt Dependency as Catalyst in the Plating Bath on the Film Properties of Cu/Cu-Ni Rosyidan, Cahaya; Kurniawan, Budhy; Soegijono, Bambang; Maulani, Mustamina; Samura, Lisa; Nababan, Frederik Gresia; Putra, Valentinus Galih Vidia; Susetyo, Ferry Budhi
Science and Technology Indonesia Vol. 9 No. 3 (2024): July
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/sti.2024.9.3.529-538

Abstract

Metal plating frequently employs nickel (Ni) and copper (Cu) as anodes. Cu/ Cu-Ni film formed has many advantages, such as better corrosion resistance and high hardness characteristics. This study aims to assess the properties of Cu/Cu-Ni film, such as phase, surface morphology, crystallographic orientation, hardness, corrosion analysis, and contact angle, which were fabricated using electrodeposition with various Ni salt additions (0.3, 0.5 and 0.7 M). In addition, the cathode current efficiency (CCE) and deposition rate of the Cu/Cu-Ni electrodeposition were also investigated. An increase in Ni salt in the plating bath could enhance the pH, promoting higher CCE and depleting hydrogen evolution at the cathode, leading to the presenting Ni phase in the alloy. The higher concentration of Ni salt in the solution could also enhance the deposition rate due to a shift to a pH value, which affects the roughening of the surface morphology, promoting a higher contact angle. All crystal structures generated by Cu/Cu-Ni electrodeposition were FCC, with the preferred orientation of the (111) plane. Crystallite size and lattice strain depend on the deposition rate. Less crystallite size and lattice strain affect the film’s hardness and corrosion resistance. Moreover, the third bath had the resulting Cu-Ni layer with the best hardness and corrosion rate of around 136 HV and 0.081 mmpy.
Co-Authors Andry Prima Arkaan, Muhammad Dzaki Aryandi, Firman Aryanto, Reza Asih Retno Dewanti Asri Nugrahanti, Asri Astri Rinanti Azica, Muhammad Raihan Azizi, Masagus Ahmad Bambang Soegijono Bayu Satiyawira Bayu Satyawira, Bayu Binartha, Ciptadhi Tri Oka Buana, Firdha Meidya Budhy Kurniawan Burhanudinnur, Muhammad Cahaya Rosyidan Damayanti, Sisca Dida Nurhaida Djunaedi Agus Wibowo Dwi Nuryana, Suherman Fadliah, Fadliah Fajarwati, Kartika Ferry Budhi Susetyo Gihon Nugrahadi, Gihon Giraldi Fardiaz Kuswanda Harin Widiyatni Harris Effendi Havidh Pramadika Hidayat, Hifdzan Rizki Hidayat, Hifzhan Rizki Ida Busnetty Indralaksmi, Indralaksmi Irvan, Rayhan Ischak, Mohammad Jasmine, Gabriella Julia Damayanti Kashah, Muhammad Refli Kurniawati, Riskaviana Lukas Pearlo, Kevin Mahanggi, Muhammad F.Z. Maman Djumantara, Maman Menul Teguh Riyanti, Menul Teguh Michael, David Mohammad Apriniyadi Muhammad Burhannudinnur Muhammad Fathurrahman Muhammad Taufiq Fathaddin, Muhammad Taufiq Mulia Ginting, Mulia Nababan, Frederik Gresia Nelfia, L. Oksri Nugraheni, Rosmalia Dita Nurfajrin, Zakiah Darajat Nurhayati Nurhayati Okvianti Irlan, Ade Patricia, Cicilia Benita Putri Pauhesti Pauhesti, Pauhesti Pearlo, Kevin Lukas Permanasari, Arlina Pramadika, Havid Prapansya, Onnie Ridaliani Putra, Rakha Handika Putra, Valentinus Galih Vidia Rachmaputra, Try RakhmantoPri Agung Rakhmanto, Pri Agung Ristawati , Arinda Riswati, Arinda Samura, Lisa Sangayu Ketut Laksemi Nilotama Sari, Emilia Setiadi, Virginia Suryani Soekardy, Mentari Gracia Suherman Dwi Nuryana Suryo Prakoso, Suryo Syamsul Irham, Syamsul Wawan Kurniawan Wegig Murwonugroho Widia Yanti, Widia Wilastrina, Atridia wiwik dahani, wiwik Young, Henry David