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PENGARUH KELEMBABAN TERHADAP SIFAT OPTIK FILM GELATIN Maddu, Akhiruddin; Modjahidin, Kun; Sardy, Sar; Zain, Hamdani
Makara Journal of Science Vol. 10, No. 1
Publisher : UI Scholars Hub

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Abstract

Humidity Dependence of Optical Properties of Gelatin Films. Humidity dependence of optical properties of gelatin films prepared by casting technique has been investigated. Gelatin films was investigated its optical properties to varied humidity condition. Optical responses investigated are optical transmission and absorption at visible light spectrum measured utilizing a UV-Vis (Ultraviolet – Visible) spectrophotometer. The results of optical transmittance and absorbance obtained shows an optical response of gelatin films in widely visible light spectrum within range 530 – 680 nm, with most clearly response in a spectrum band in 580 – 650 nm. Different humidity treatment cause a significantly change of optical characteristics, that is the transmittance and absorbance change in to humidity. Transmittance of gelatin films increase with increasing humidity in a range 580 – 650 nm, in contrast with absorbance that is decrease with increasing humidity. Plot of transmission and absorption intensity with varied humidity from 37%RH to 99%RH at 610 nm exhibited a good linearity. Two samples showed same characteristics
The Acoustical Properties of Indonesian Hardwood Species Karlinasari, Lina; Baihaqi, Hans; Maddu, Akhiruddin
Makara Journal of Science Vol. 16, No. 2
Publisher : UI Scholars Hub

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Abstract

SIFAT OPTIK CARBON DOTS (C-DOTS) DARI DAUN BAMBU HASIL SINTESIS HIJAU BERBANTUKAN GELOMBANG MIKRO Permono Adi Putro; Akhiruddin Maddu
Wahana Fisika Vol 4, No 1 (2019): June
Publisher : Universitas Pendidikan Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17509/wafi.v4i1.15569

Abstract

Carbon dots (C-dots)  adalah tipe baru dari nanopartikel berpendar yang dapat mudah disintesis dari sumber alami. Sintesis C-dots dari daun bambu telah berhasil dilakukan menggunakan teknik sintesis hijau berbantukan gelombang mikro. Teknik sintesis hijau dilakukan dengan menggunakan air sebagai pelarut non-kimia dan sumber alami. Sintesis dilakukan menggunakan variasi konsentrasi prekursor untuk dipelajari pengaruhnya terhadap sifat fisik dan sifat optiknya. Sifat fisik C-dots menunjukkan warna transparan di bawah cahaya tampak, dan warna hijau di bawah laser UV 405 nm. Sifat optik C-dots dikarakterisasi menggunakan spektrofotometer UV-Vis, dan spektrofotometer dengan sumber eksitasi 405 nm. Konsentrasi prekursor mempengaruhi intensitas eksitasi dan emisi, namun pergeseran Stokes C-dots memiliki kestabilan yang sangat baik dalam larutan berair. Pergeseran Stokes berasal dari keadaan transisi n–π* dari struktur ikatan aromatik C=O pada permukaan C-dots. Kami peroleh C-dots yang berpotensi untuk diaplikasikan sebagai bioimaging seluler in vivo dan in vitro dan biosensing ion logam dan garam.
Porous Carbon Black Microsphere from Palm Oil Black Liquor Jayadi Jayadi; Akhiruddin Maddu; Yessie Sari; Wahyu Bambang Widayatno; Agus Sukarto Wismogroho; Cherly Firdarini; Marga Asta Jaya Mulya
Jurnal Sains Materi Indonesia Vol. 25 No. 1 (2023): Jurnal Sains dan Materi Indonesia
Publisher : BRIN Publishing (Penerbit BRIN)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55981/jsmi.2023.686

Abstract

The aim of this research is to synthesize porous carbon black microspheres from palm oil black liquor through an in-house spray pyrolysis system. The in-house spray pyrolysis (SP) system was developed using a horizontal furnace. To test the developed SP equipment, the temperature profiles within the developed spray pyrolysis chamber were examined at 3 different setting temperatures (800, 900, and 1000 °C). These temperatures were also applied for synthesizing the carbon black microspheres, with and without nitrogen as carrier gas. The morphology of carbon black produced by using SP equipment was tested by a 3D Optical Microscope and FE-SEM. The optimum temperature obtained in this study is 1000 ºC according to the characterization of carbon black microspheres produced. The FE-SEM analysis indicated the presence of spherical carbon having microstructures. This indicates that the in-house spray pyrolysis machine has been successfully developed for synthesizing carbon black microspheres.
Effect of Precursor Solvent on the Carbon Micro-Structures Derived from Spray Pyrolysis of Pine Resin (Gondorukem): Preliminary Study Jayadi; Wahyu Bambang Widayatno; Agus Sukarto Wismogroho; Cherly Firdharini; Akhiruddin Maddu; Husin Alatas; Yessie Widya Sari
Jurnal Sains Materi Indonesia Vol. 25 No. 2 (2024): Jurnal Sains dan Materi Indonesia
Publisher : BRIN Publishing (Penerbit BRIN)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55981/jsmi.2024.893

Abstract

Carbon materials have been widely used in various fields. This study aimed to produce carbon using spray pyrolysis with pine resin (gondorukem) as the precursor and different solvents, namely gondorukem-acetone (GAC), gondorukem-ethyl acetate (GEA), and gondorukem-dichloromethane (GDC). The precursor was prepared in a 1:8 (m/v) ratio, and the spray pyrolysis method was employed by heating the atomized precursor solution in the heating zone of a tube furnace. The atomization precursor was infused with nitrogen gas at a rate of 1 l/min with furnace temperature set at 1000°C with heating times of 5, 10, and 20 mins. The carbonaceous materials produced from the pyrolysis were collected on the wire mesh 1000 that was put on a stainless pipe. Carbon that has been coated on the wire mesh 1000 was analyzed using the optical microscope (OM). The physical properties and morphology of the synthesized carbonaceous material were analyzed using field emission scanning electron microscopy (FE-SEM), Fourier-transform infrared spectroscopy (FTIR), Raman, and Brunaur-Emmett-Teller (BET). Based on FE-SEM analysis, the particle size of the GAC sample has an average of 283.58 nm and the highest carbon content, which reached an average of 97.312 At%. GAC samples had the lowest disorder properties in the Raman spectroscopy test, with the value of ID/IG reaching 0.795764. The functional groups observed were C–H stretching at 2920.49 cm-1, N–H bending at 1629.07 cm-1, and C–O stretching at 1159.70 cm-1. Based on carbon content, disorder properties, and functional group stabilization, carbon from the GAC precursor provides the ideal characteristics to be used as a filter material in medical masks. Meanwhile, based on BET testing, the carbon materials from GEA have the ideal material morphological properties to be used as a filter in medical masks. Spray pyrolysis is an efficient method for producing carbon materials, and the use of gondorukem as the precursor shows great potential for various applications.
Structure and Morphology of ZnO Nanoparticles Prepared by Sonochemical Method Maddu, Akhiruddin; Zetria Zikri; Irzaman, Irzaman
TIME in Physics Vol. 1 No. 2 (2023): August
Publisher : Universitas Mandiri

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.11594/timeinphys.2023.v1i2p51-58

Abstract

Ultrasonic wave has been utilized to synthesize the ZnO nanoparticle. ZnO is formed from a mixture of zinc acetate (ZnAc) and Natrium Hydroxide (NaOH) with various concentrations of ZnAc 0.5 M (ZnO 1:1) and 1.5 M (ZnO 3:1) and the concentration of NaOH remained at a concentration of 0.5 M. The Structure and crystal size were characterized using X-ray Diffraction (XRD), while its morphology was examined by Scanning Electron Microscopy (SEM). The results show that ZnO 1:1 has a higher (stronger) diffraction intensity than the ZnO 3:1. The crystallite size of ZnO 1:1 averaged 30.57 ± 4.31 nm while the ZnO 3:1 had an average crystallite size of 20.25 ± 7.12 nm. From the size of the crystallites ZnO particles that are formed include nanoparticles. ZnO 1:1 SEM image shows the shape of microrods in the 1:1 ZnO sample while in the 3:1 ZnO sample no microrods are formed. Based on the morphology, the 1:1 ZnO sample has an average size of 230 nm and is larger than the 3:1 ZnO sample which has an average size of 50 nm.
Kajian Fluktuasi Sifat Dielektrik Telur Puyuh yang Bervariasi pada Lama Penyimpanan Irawan, Bagus; Maddu, Akhiruddin; Rustami, Erus; Sulaeman, Ahmad Sofyan; Putro, Permono Adi
TIME in Physics Vol. 2 No. 1 (2024): March
Publisher : Universitas Mandiri

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.11594/timeinphys.2024.v2i1p41-49

Abstract

An increasing of public attention to the quality of food has been increasing, recently. One type of food that consumed is quail eggs (QE). In this study, QE were tested by Electrochemical Impedance Spectroscopy (EIS) method with some parameters such as complex impedance, dielectric constant, and loss tangent analysis. Several interesting results showed that dielectric properties of QE experience a fluctuation phenomenon if the test is influenced by storage duration, qualitatively. Therefore, we approximately prove that QE quality can be tested via EIS to obtain fine results.
Karakterisasi Sifat Listrik Dan Sifat Termal Hidroksiapatit, Fluorhidroksiapatit Dan Fluorapatit Riano, Riza; Sukaryo, Sulistioso Giat; Sugeng, Bambang; Sari, Yessie Widya; Maddu, Akhiruddin
JURNAL Al-AZHAR INDONESIA SERI SAINS DAN TEKNOLOGI Vol 7, No 3 (2022): September 2022
Publisher : Universitas Al Azhar Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.36722/sst.v7i3.1128

Abstract

The apatite compound that is often used in medicine and dentistry is hydroxyapatite with the chemical formula Ca10(PO4)6(OH)2. Fluor ions can substitute hydroxyl ions from hydroxyapatite to form crystals with the formula Ca (PO4)6(OH)2-xF2x, with the value of x indicating the index number of hydroxyl groups (OH-) replaced by fluor ions (F-). This study aims to determine the effect of fluor ion substitution on hydroxyapatite on electrical properties and thermal stability. In this study, the hydrothermal method was characterized by X-Ray diffractometer (XRD), Fourier Transform Infra-Red Spectroscopy (FTIR), LCR meter, Thermogravimetry Analysis (DTA), and Differential Thermal Analysis (TGA). The XRD and FTIR analysis results showed that the samples obtained were in the form of hydroxyapatite, fluorhydroxyapatite, and fluorapatite, which was also indicated by the presence of functional groups PO43-, CO32-, and OH- group libration mode at a wavenumber of 740 cm-1. There was a decrease in the lattice parameter a and an increase in the crystal size as the substitution of fluor ions increased. Based on the results of the electrical and thermal properties characterization, fluorapatite has the highest conductivity and better thermal stability when compared to hydroxyapatite and fluohydroxyapatite.Keywords – Fluor, Hydroxyapatite, Hydrothermal, eggshell, Biomaterial
Sintesis Nano Fertilizer Carbon Dots dari Kulit Pisang Nangka (Musa paradisiaca L.) yang Diperkaya Urea dan Pengujiannya pada Pertumbuhan Vegetatif (Awal) Tanaman Jagung Taqiyyah, Izzatut; Maddu, Akhiruddin; Suhartanto, M Rahmad
POSITRON Vol 15, No 1 (2025): Vol. 15 No. 1 Edition
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam, Univetsitas Tanjungpura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26418/positron.v15i1.86743

Abstract

Carbon dots (CDs) yang berasal dari karbon hijau merupakan salah satu contoh bahan organik yang dapat digunakan untuk membuat pupuk nano yang tidak beracun dan ramah lingkungan. Pada penelitian ini dilakukan proses sintesis nano fertilizer (pupuk nano) carbon dots yang diberi pengayaan nitrogen (N-CDs) dari prekursor kulit pisang nangka dan dilakukan pengujiannya sebagai pupuk nano pada pertumbuhan vegetatif jagung. Penelitian ini juga menguji karakteristik N-CDs dan efektivitasnya terhadap pertumbuhan vegetatif jagung. Metode yang digunakan adalah metode perbandingan langsung. Berdasarkan uji karakteristik CDs dan N-CDs, sejumlah gugus fungsi yang dimiliki bersama oleh CDs dan N-CDs adalah gugus hidroksil C(=O)OH dan sejumlah gugus fungsi lainnya seperti C=C-C, C-O-O, dan C-Cl terdapat dalam N-CDs tetapi tidak dalam CDs. Energi celah pita CDs kulit pisang nangka 40 mg/L urea 0% adalah 2,46 eV, dan CDs kulit pisang nangka 40 mg/L urea 10% adalah 3,99 eV. Cahaya sian dihasilkan oleh CDs dan N-CDs, namun warna sian kurang kuat pada N-CDs. Demikian pula, CDs 40 mg/L dan N-CDs 40 mg/L urea 10%, masing-masing menghasilkan panjang gelombang emisi 505 nm dan 496 nm berdasarkan uji Confocal Laser Scanning Microscope (CLSM). Secara signifikan kinerja N-CDs menunjukkan pengaruh yang lebih baik dibandingkan perlakuan CDs dan urea pada pertumbuhan vegetatif jagung.
Karakteristik fisik carbon dots dan aplikasinya dengan pemupukan untuk meningkatkan produksi dan mutu benih padi: Physical characteristics of carbon dots and its application with fertilizer to increase rice seed production and quality Fitri Viva Yuningsih, Aida; Nafisah, Nafisah; Maddu, Akhiruddin; Rahmad Suhartanto, Mohamad
Jurnal AGRO Vol. 12 No. 1 (2025)
Publisher : Jurusan Agroteknologi

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15575/j.agro.46880

Abstract

Carbon dots (CDs) are nano-sized carbon particles proven to enhance seed germination, plant growth, and yield. This study evaluated CDs in an integrated fertilization system combining macronutrient fertilizers (NPK) and organic matter (OM). The experiment was conducted during the 2023 dry season at the Sukamandi Experimental Station of BBRMP Padi using a Split-split Plot Design. The treatments included NPK combinations (main plot; without NPK, +PK, +NP, +NK, +NPK), OM (sub-plots; manure, straw compost, without OM), and foliar-applied CDs (800 mg L⁻¹) (sub-sub-plots; +CDs, without CDs). The results showed that coffee ground-based CDs from coffee shops were water-soluble, light brown, and had an absorption peak at 300 nm. Nitrogen doping with urea increased the N content from 2,44% to 16,12%. The N and P significantly improved vegetative growth, grain yield, and seed quality, while N and K maintained chlorophyll in the reproductive stage. OM increased NPK efficiency and nutrient availability, with manure more effective than straw compost. CDs enhanced OM in increasing leaf area. The combination of NPK, OM, and CDs shows potential as an efficient and sustainable fertilization strategy to increase rice productivity and seed quality.   ABSTRAK Carbon dots (CDs) adalah partikel karbon berukuran nano yang telah terbukti mampu meningkatkan perkecambahan benih, pertumbuhan, dan hasil tanaman. Penelitian ini bertujuan untuk mengevaluasi CDs dalam sistem pemupukan terintegrasi dengan pupuk hara makro (NPK) dan bahan organik. Penelitian dilaksanakan pada Musim Kemarau 2023 di lahan sawah irigasi Kebun Percobaan Sukamandi BBRMP Padi  dengan Rancangan Petak-petak Terbagi. Kombinasi pupuk NPK (petak utama; tanpa NPK, +PK, +NP, +NK, +NPK), bahan organik (anak petak; pupuk kandang, kompos jerami, tanpa BO), dan aplikasi foliar CDs (800 mg L-1) (anak-anak petak; tanpa CDs, +CDs). Hasil percobaan menunjukkan CDs berbasis ampas kopi dari limbah coffee shop memiliki sifat larut air, berwarna cokelat terang, dan puncak absorbansi pada 300 nm. Pengkayaan nitrogen dengan urea meningkatkan kandungan N dari 2,44% menjadi 16,12%. Kombinasi N dan P sangat mempengaruhi pertumbuhan vegetatif, hasil gabah, dan mutu fisiologis benih. Kombinasi N dan K efektif dalam mempertahankan klorofil pada fase reproduktif. Bahan organik terbukti meningkatkan efisiensi pupuk NPK dan ketersediaan hara, dimana pupuk kandang lebih efektif dibandingkan kompos jerami. Aplikasi CDs meningkatkan efektivitas bahan organik dalam meningkatkan luas daun. Kombinasi pupuk NPK, bahan organik, dan CDs berpotensi menjadi strategi pemupukan efisien dan berkelanjutan untuk meningkatkan produktivitas dan mutu benih padi. Kata kunci: Bahan organik, hasil, luas daun, pupuk NPK, sinergi pupuk
Co-Authors - - Nurrahman . Sugianto Abdulloh Rifai Abdurrahman Bahtiar Agus Ghautsun Niam Agus Sukarto Wismogroho Agus Sukarto Wismogroho, Agus Sukarto Ahmad Aminuddin Ahmad Sulaeman Ahmad, Faozan Akmal, Raihan Muhammad Almiahsari, Ashri Aminuddin Aminuddin Andhika Prima Prasetyo Angga Saputra Anita Firmanti Aribah, Putri Auliya Ilmiawati Bagus Irawan Bagus MARTIANTO Baihaqi, Hans Bambang - Riyanto Bambang Herawan Bambang Herawan, Bambang Bambang Riyanto Bambang Sugeng Berlianingtyas, Dani Indrawati Bonny Poernomo Wahyu Soekarno Budi Arifin Candra A. Basuki Charlena Cherly Firdarini Cherly Firdharini Dede Hermawan Deded Sarip Nawawi Deded Sarip Nawawi Deni Shidqi Khaerudini Dimas Ramadhan Putra Dimas Ramadhan Putra Dimyati , Arbi Djoko Pujiarto Dodyk Pranowo Dyah Iswantini Elbersen, Wolter Erliza Noor Esa Ghanim Fadhallah Esa Ghanim Fadhallah Farly Reynol Tumimomor Fayakun, Kun Firdarini, Cherly Firdharini, Cherly Fitri Viva Yuningsih, Aida Fitriani Indahsari Gareso, Paulus P. Gareso, Paulus P. Gustan Pari Gustan Pari Gustan Pari Gustan Pari Gustan Pari Gustan Pari Gustini Syahbirin Hamdani Zain Hamdani Zain Hamdani Zain Hamdani Zain Hans Baihaqi Hardhienata, Hendradi Harry Ramza Harry Ramza Henny Purwaningsih HERA MAHESHWARI Hera Maheswari, Hera Herry Suhardiyanto Hidayah, Mohamad Ikbal Horasdia Saragih Huda Shalahudin Darusman Husin Alatas Ibrahim Purawiardi, Ibrahim Ida Ayu Putu Sri Widnyani ikhwan wirahadikesuma Ikhwan Wirahadikesuma Imelia Dewi Inda Setyawati, Inda Indah Puspita, Indah Ira Ukhtiningsih Ira Ukhtiningsih, Ira Irmansyah . Irmansyah Irmansyah Irmansyah Irmansyah Irmansyah Irmansyah Irzaman, Irzaman Ismail Budiman Ismail Budiman Isnaeni Isnaeni Isnaeni Isnaeni Isnaeni Isnaeni Isnaeni Jayadi Jayadi Jayadi Jayadi Jayadi Jayadi Jhav Sund Oktoricoento Johan D. Sirait Jufra Jufra Jumardin jumardin jumardin Kadapi, Muhamar Kiagus Dahlan koekoeh santoso Kokoeh Santoso Kudang Boro Seminar Kun Fayakun Kun Modjahidin Kun Modjahidin, Kun La Ode Muliadi LAKSMI AMBARSARI Liesbetini Haditjaroko Lina Karlinasari Luthfan Irfana M. Farouq Iksan Mahfuddin Zuhri Marga Asta Jaya Mulya Melinia Falestin Mersi Kurniati Mia Fitriana, And Moehamad Barmawi Mohamad Rahmad Suhartanto Mohammad Mujirudin Muhammad F Ikhsan Muhammad Ramdani Muhammad Rizki Mujirudin, Mohammad Mulya, Marga Asta Jaya Nafisah Nafisah Novik Nurhidayat Nur Adi Saputra Nur Adi Saputra Nurfina Yudasari Nurul Rostami Dewi Nurul Rostami Dewi Oktarina Heriyani Oktoricoento, Jhav Sund Paulus P Gareso, Paulus P Pepen Arifin Permono Adi Putro Pramudito, Sidikrubadi Purawiardi , Ibrahim Purwantiningsih Sugita Purwantiningsih Sugita Putri, Desi Alifia Rahman, Mohammad Syuhaimi Ab Rahmani, Nabiila Rahmaniah Nalwi Rahmaniah Nalwi Ramdani, Muhammad Ramza, Harry Rasyida Ulfa Ratna Sari Dewi Riano, Riza Rina Mardiana Rini Kurniasih, Rini Rinto Paputungan Rosniyati Suwarda Rustami, Erus Safaruddin A Prasad Sahrudin Sahrudin Sahrudin, Sahrudin Santoso, Zahra Firda Sar Sardy Sar Sardy Sar Sardy Sari, Yessie Setyanto Tri Wahyudi Siti Nikmatin Sofian, Irmansyah Subyakto Subyakto SUBYAKTO SUBYAKTO Sugianto Arjo Sugianto, . Sugianto, . Sugianto, Sugianto Suhartanto, Muhammad Rahmad Sulaeman, Ahmad Sofyan Sulistioso Giat Sukaryo, Sulistioso Giat Sultan, Syamsu Supian, Latifah Sarah Supriyanto . Taqiyyah, Izzatut Tarcisius Rio Mardikanto Tarigan, Putri Andayati Br Tatang Hidayat Wahyu Bambang Widayatno Wahyu Bambang Widayatno, Wahyu Bambang Wasmen Manalu Wasrin Syafii Widaningrum Winarti , Christina wirahadikesuma, ikhwan Wirahadikesuma, Ikhwan Wirahadikesuma Yayan Firmansyah Yessie Sari Yessie Widya Sari Yogi Waldingga Hasnedi Yulia Irdawati Yulia Sani Yulia Sani, Yulia Zetria Zikri zuldian, prima