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All Journal HAYATI Journal of Biosciences Jurnal Agronomi Indonesia (Indonesian Journal of Agronomy) Jurnal Gizi dan Pangan Jurnal Fitopatologi Indonesia Jurnal Teknologi Dan Industri Pangan Jurnal Akuakultur Indonesia Jurnal Farmasi Udayana CHEMISTRY PROGRESS Jurnal Pendidikan Bahasa dan Sastra Indonesia Undiksha Microbiology Indonesia BIOTROPIA - The Southeast Asian Journal of Tropical Biology Current Biochemistry The Journal of Pure and Applied Chemistry Research Indonesian Journal of Biotechnology BERITA BIOLOGI ANNALES BOGORIENSES FITOFARMAKA: Jurnal Ilmiah Farmasi Menara Perkebunan Jurnal Jamu Indonesia Sainstek : Jurnal Sains dan Teknologi Jurnal Pusat Inovasi Masyarakat Jurnal Ilmu Kehutanan Molekul: Jurnal Ilmiah Kimia Journal of The Indonesian Society of Integrated Chemistry Indonesian Journal of Jamu
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Department Of Biochemistry, Faculty Of Mathematics And Natural Sciences, Darmaga Campus, IPB University, Bogor, 16680, Indonesia
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Pemurnian alfa-selulosa dari baglog bekas jamur tiram putih (Pleurotus ostreatus) menggunakan NaOH dan hidrolisis sulfat (Purification of alpha-cellulose from ex-baglog of white oyster mushroom (Pleurotus ostreatus) using NaOH and sulfate hydrolysis) Hyakansa HANIF; TRI - PANJI; Firda DIMAWARNITA; I Made ARTIKA
Menara Perkebunan Vol. 87 No. 1 (2019): 87 (1), 2019
Publisher : INDONESIAN OIL PALM RESEARCH INSTITUTE

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22302/iribb.jur.mp.v87i1.325

Abstract

Oil Palm Empty Fruit Bunches (OPEFB) are the largest cellulose waste produced by oil palm plantations. Each processing of one ton of Fresh Fruit Bunch (FFB) will produce OPEFB as much as 22-23% or 220-230 kg. OPEFB waste has not been utilized optimally by most palm oil mills and communities. It was reported that OPEFB contains 32.57% cellulose, 27.70% hemicellulose, and 26.49% lignin. The purity of cellulose component in OPEFB can be increased by delignification and hydrolysis of OPEFB. This research aims to produce alpha-cellulose from OPEFB with the highest purity level. The stages of the process include biologically delignification using white oyster mushroom (Pleurotus ostreatus), chemical delignification using 17,5% NaOH solution, and combination of treatment using solution of 17,5% NaOH and hydrolysis using 10% H2SO4solution. The analysis was carried out using the Fourier Transform Infrared Spectroscopy (FTIR). The best result of alpha-cellulose purity was by the treatment of delignified NaOH baglog resulting in 97.43% alpha-cellulose content, 4.47% pentosan hemicellulose level, and undetectable lignin levels.The results of FT-IR spectrum from alpha-cellulose obtained from OPEFB has shown functional groups contained in alpha-cellulose polymers including O-H groups at wave number 3289 cm-1, C-H groups at wave number 2901 cm-1, and functional groups C-O at wave number 1372 cm-1.[Key words: hydrolysis, FT-IR, mushroom, bleaching, waste]  Abstrak Tandan kosong kelapa sawit (TKKS) adalah limbah terbesar yang dihasilkan oleh perkebunan kelapa sawit. Setiap pengolahan satu ton tandan buah segar (TBS) akan dihasilkan TKKS sebanyak 22-23% atau 220-230 kg. Limbah TKKS belum dimanfaatkan secara optimaloleh sebagian besar pabrik kelapa sawit (PKS) dan masyarakat. Dari hasil analisis kimiakomposisi selulosa, hemiselulosa, dan lignin pada TKKSsecara berturut-turut ialah ; 32,57%, 27,70%, 26,49%. Kandungan komponen selulosa dalam TKKSdapat ditingkatkan kemurniannya dengan cara delignifikasi dan hidrolisis. Penelitian ini bertujuan pemurnian alfa–selulosa dari TKKS dengan tingkat kemurnian tertinggi.Tahapan pembuatan alfa-selulosameliputi delignifikasi secara biologis menggunakan jamur tiramputih(Pleurotus ostreatus), delignifikasi secara kimia menggunakan larutan NaOH 17,5%, dan kombinasi perlakuan menggunakan NaOH 17,5% dan larutanH2SO410%. Analisis dilakukan menggunakanFourier Transform Infrared Spektroscopy (FT-IR). Hasil pemurnian alfa-selulosa terbaik ialah melalui sisa baglog terdelignifikasi NaOH menghasilkan kadar alfa-selulosa 97.43%, kadar pentosan hemiselulosa 4.47%, serta kadar lignin tidak terdeteksi. Hasil spektrumFT-IR darialfa–selulosayang diperoleh dari TKKStelahmenunjukkan gugus-gugus fungsi yangterdapat di dalam polimeralfa–selulosadiantaranyagugus O-H pada bilangan gelombang 3289 cm-1,  gugus C-H pada bilangangelombang2901cm-1, dan gugus fungsi C-O pada bilangan gelombang 1372 cm-1. [Kata kunci: hidrolisis, FT-IR, jamur, pemutihan, limbah]
Co-Authors . SURYANI A. E. Zainal Hasan AA Sudharmawan, AA Abdul Choliq ADINDA VIRGINIA DWI SETYO Agung Eru Wibowo AHMAD ENDANG ZAINAL HASAN AHMAD ENDANG ZAINAL HASAN Ahmad Sulaeman Akhmad Endang Zainal Hasan Amanda, Nisa Widya AMIN FATONI Andani, Gita Putri Andita Fitri Mutiara Rizki, Andita Fitri Mutiara Antonius Padua Ratu Apipah Aprianti Apon Zaenal Mustopa APON ZAENAL MUSTOPA Arya Arendra Asri Sulfianti Azmi Azhari Azmi Azhari, Azmi Azmi, Wihda Aisarul BUGI RATNO BUDIARTO DEDI JUSADI Denny Irawati Desi Purwaningsih Dewi Sukma Dhani Luthfi Ramadhani DIMAS ANDRIANTO Djarot Sasongko Hami Seno Dodi Safari Dodi Safari Dodi Safari Dodi Safari Dwi N. Susilowati Dzihan Dinar Rabani Eliza Halim Erismar Amri Erlank Bagjavicenna Erna Puspasari Evi Nur Qolbaini Fatriani, Rizka Fina Febrianti Firda DIMAWARNITA Fri Rahmawati Gusnia Meilin Gholam Gusnia Meilin Gholam Gusnia Meilin Gholam H. A. E. Zainal Hasan Hafizh Zahra Hani 'Athiyya Rafi Hardinsyah Harsana, Ngurah HARTUTIK EKA SUSANTI HARYANTO SUSILO Hasim - HASIM DANURI Hayatul Rahmi Herti Sugiarti Herti Sugiarti, Herti Hyakansa HANIF Ifa Manzila Iman Akhyar Firdausy Iman Rusmana Inawati Inawati Jajang Suhyana K, Popi A Kurnia Agustini Laita Nurjanah Laita Nurjanah, Laita LAKSMI AMBARSARI Lasmiyanti, Metty Lusiana Kresnawati Hartono Luzicoiij, Michael Edison M. Zairin Junior M.Pd Prof. Dr. I Nyoman Sudiana . Mala Nurilmala MARIA BINTANG Meilisza, Nina Melva Louisa Mirza Dikari Kusrini MS, Yulia Atika Muhaimin Muhaimin MUHAMMAD AGUS SUPRAYUDI Muhammad Dailami, Muhammad Muhammad Nafiz Nisa Widya Amanda Noorwati Sutandyo Norman Razief Azwar Norman Razief Azwar Novik Nurhidayat Novik Nurhidayat Nuke Annisa Nasution NUNUK WIDHYASTUTI Nur Bambang Priyo Utomo Nur Hasanah Nurmala Sari Nurul Khumaida Perkasa Arian Puji Lestari Rahadian Pratama Rahmawati, Fri Ramadhani Malik Abdillah Rava Raisha Putra Resti Rahmawati Putri Ridwan Putra Firmansyah Rini Kurniasih, Rini Riyan Alifbi Putera Irsal Rizka Fatriani Roedhy Poerwanto Septiany C. Palilingan Sheryn Sunni Albani Siagian, Putri Junita Siregar, Josephine Elizabeth Siti Nurjanah Siti Nurjanah Soekarno Mismana Putra Soekarno Mismana Putra, Soekarno Mismana Sogandi Sogandi Sogandi Sogandi Sudarsono Suharyanto Suharyanto Sulistiani sulistiani Suryani Suryani Suryani Suryani Suryani Suryo Wiyono Sutoro Sutoro Syaeful Abidin Syamsul Falah Tatik Khusniati Tetty Chaidamsari Tetty Chaidamsari, Tetty Tri Panji Trini Suryani Kadir Vita Rosaline Fahri Waras Nurcholis Wasrin Syafii Wijiastuti Wijiastuti Yadi Suryadi Yahdiana Harahap Yulianto YUNITA ARIAN SANI ANWAR