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All Journal Jurnal Bestari Reaktor International Journal of Science and Engineering (IJSE) International Journal of Renewable Energy Development TEKNIK METANA JURNAL KIMIA SAINS DAN APLIKASI Jurnal Ilmu Lingkungan JURNAL TEKNOLOGI KIMIA DAN INDUSTRI Prosiding Seminar Nasional Sains Dan Teknologi Fakultas Teknik Jurnal Bahan Alam Terbarukan Waste Technology Eksergi: Chemical Engineering Journal Techno: Jurnal Penelitian Journal of Engineering and Technological Sciences Majalah Ilmiah MOMENTUM ELKOMIKA: Jurnal Teknik Energi Elektrik, Teknik Telekomunikasi, & Teknik Elektronika International Journal of Artificial Intelligence Research Jurnal Ekonomi dan Bisnis Indonesian Journal of Chemistry Jurnal Aplikasi Teknologi Pangan Indonesia Journal of Halal PRoMEDIA Journal of Innovation in Business and Economics ULIN: Jurnal Hutan Tropis Andalas obstetrics and gynecology journal ASEAN Journal of Chemical Engineering Budimas : Jurnal Pengabdian Masyarakat Jurnal Teknik Kimia Indonesia Jurnal Pengabdian dan Peningkatan Mutu Masyarakat (JANAYU) Jurnal Ilmu Sosial Indonesia (JISI) Jurnal Energi Baru dan Terbarukan Journal of Bioresources and Environmental Sciences Jurnal Riptek Jurnal Profesi Insinyur Indonesia Journal of Bioresources and Environmental Sciences International Journal of Renewable Energy Development Bulletin of Chemical Reaction Engineering & Catalysis JURNAL REKAYASA KIMIA & LINGKUNGAN
. Widayat
Chemical Engineering Department, Faculty Of Engineering, Diponegoro University, Jl. Prof. Soedarto, SH, Tembalang, Semarang 50275
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Silica-rich Sodalite Synthesis: The Effect of Variations in Ultrasound Treatment and Hydrothermal Temperature Sriatun Sriatun; Marta Chandra Anikke Putri; Hanifa Zakiyatul Urbach; Adi Darmawan; Widayat Widayat; Heru Susanto
Jurnal Kimia Sains dan Aplikasi Vol 25, No 4 (2022): Volume 25 Issue 4 Year 2022
Publisher : Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (3852.166 KB) | DOI: 10.14710/jksa.25.4.137-145

Abstract

Silica-rich sodalite zeolite has been synthesized by ultrasound treatment and hydrothermal temperature variation. This study aimed to determine the effect of ultrasound treatment and hydrothermal temperature variations on the crystallinity, hydrophobicity, and structural properties of silica-rich sodalite zeolite. The synthesis was conducted by reacting a sodium aluminate and sodium silicate solution by varying Si/Al ratios of 20, 30, 40, 60, 80, and 90. The next step was to characterize the product. The product with the best crystallinity was used as a reference to determine the effect of ultrasound and hydrothermal temperature. The reaction gel was treated with and without ultrasound and hydrothermal using autoclave at 100, 150, and 200°C for 24 hours. The last step was the product characterization using XRD, FTIR, and GSA. The XRD showed similarity peaks at 2θ = 14.058°; 24.41°; 31.73°; 34.75°; 42.88°. The best crystallinity was silica-rich sodalite zeolite with a Si/Al ratio of 30. Meanwhile, silica-rich sodalite zeolite peaks were obtained at 2θ = 14.16°, 24.66°, 31.99°, 35.13°, and 43.39° by ultrasound treatment and hydrothermal temperature variation (100, 150, and 200°C). Ultrasound treatment revealed the presence of other peaks besides sodalite at 2θ = 19.05° and 27°, where these peaks were referred to as SAPO-56. In conclusion, the degree of crystallinity increased with increasing temperature, decreasing Si-OH/Si-O-Si showed increased hydrophobic properties. Increasing the hydrothermal temperature of 150 and 200°C with and without ultrasound treatment increased the surface area significantly to 114.137 m2/g and 160.717 m2/g, and the pore volume of sodalite with a Si/Al ratio of 30 to 0.318 cc/g and 0.274 cc/g.
Treatment of Natural Rubber Wastewater using Photoactive Nanocomposite Membrane PSf/sulfonated ZnO: Performance Evaluation, HAZOP, and Risk Analysis Tutuk Djoko Kusworo; Widayat Widayat; Hadiyanto Hadiyanto
Waste Technology Vol 10, No 2 (2022)
Publisher : Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/10.2.35-49

Abstract

The application of nanocomposite membranes for high organic wastewater treatment faces several problems such as impurities and low permeate flux. In this study, sulfonated ZnO nanoparticles were incorporated in the PSf membrane. SEM images reveal that sZnO has good compatibility with PSf polymers and the FTIR spectrum also forms sulfonic acid groups on the composite membrane. The addition of sZnO into PSf increased the PWF value but overloading caused a significant decrease. The surface hydrophilicity of the membrane was also enhanced by the incorporation of sZnO into the PSf membrane. The performance evaluation showed a significant increase in flux from 9.0 to 14.5 L.m-2.h-1 and a disappointment rate for ammonium ion (NH4+) up to 87%. Increased hydrophilicity was also revealed by decreasing the air contact angle from 79.33° to 55.67°. PVA-coated membranes can increase COD rejection up to ~88%, which is 8 times higher than uncoated composite membranes. The PVA coating also reduced the tendency of organic fouling on the membrane during rubber wastewater filtration by reducing the total fouling resistance from 14.2 x 10-11 to 9.91 x 10-11 m-1. The HAZOP and risk analysis were also studied in this work regarding on their practical application in industrial scale..
Coconut Waste Pyrolysis Simulation Using Aspen Plus Software Muhammad Syukri Hasan; Widayat Widayat; Sri Widodo Agung Suedi
TECHNO: JURNAL PENELITIAN Vol 12, No 1 (2023): TECHNO JURNAL PENELITIAN
Publisher : Universitas Khairun

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33387/tjp.v12i1.5263

Abstract

Currently, in the world are trying to substitute fossil energy for renewable energy. One of the renewable energy is biomass energy. Biomass is a renewable natural resource derived from biological nature. Biomass from palm shells has been successfully used by the Tembilahan PLTU as an effort to substitute coal. The results of technical evaluation and monitoring show operating parameters within normal limits. Palm shells are known to have a lower sulfur content than coal so that the emissions produced are less than coal. When viewed from the characteristics based on the analysis of proximate, ultimate and calorific value, it shows that the characteristics of biomass from coconut waste, especially coconut shells, are not significantly different from biomass from palm shells. This means that coconut shells can be considered as a renewable energy source. To improve the quality of the calorific value of biomass, a pyrolysis process is carried out to produce bio-charcoal. Modeling using Aspen Plus software has a difference average of less than 6%. Simulation results of coconut shell pyrolysis with maximum yield of bio-charcoal occurring at an operating temperature of 600°C which produces a total of 30.35% bio-charcoal, a calorific value (LHV) of 33.03 MJ/kg, and an ash content of 18.99%. While the simulation results of coconut shell pyrolysis with maximum syngas yield occurred at an operating temperature of 800°C which produced 82.43% syngas, high H2 49.67% and low CO2 2.90%.
The Effect of NaHCO3 and Mg2+ Addition in Haematococcus pluvialis Cultivation by Carbon Injection Method W. Widayat; Annisa Metantya Maharani; Siti Nur Khairunisa Aroli; Muhammad Hilmazar Hawari
Journal of Bioresources and Environmental Sciences Vol 1, No 3 (2022): December 2022
Publisher : BIORE Scientia Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/jbes.2022.15220

Abstract

The emission of carbon dioxide has been continuously rising year by year. Many efforts that have been used with aim of climate recovery, such as capturing CO2 with the Carbon Capture Storage (CCS) method, which is the CCS technology is one of the effective tactics for reducing carbon emissions by utilizing energy from biomass of microalgae. This research will discuss about carbon capture using microalgae Haematococcus pluvialis in a lab scale photobioreactor (PBR), and resulting the optimum biomass productivity for Haematococcus pluvialis has occurred in the H2 variable (50 ppm Mg2+). This happens because of addition of Mg ions above 50 ppm can decrease the yield of biomass productivity, since Haematococcus pluvialis cannot live in high salinity concentrations. Further research should make a calculation of optimal cost incurred at the optimal carbon concentration that can be captured by microalgae, also the results of increasing value of the microalgae biomass produced for the comprehensive use of the microalgae.
Palm Oil Milling Effluent (POME) Waste Processing by Using Microalgae Chlamydomonas sp. Riky Yonas; Uray Irzandi; Hantoro Satriadi; W. Widayat; Marcelinus Christwardana; H. Hadiyanto
Journal of Bioresources and Environmental Sciences Vol 1, No 2 (2022): August 2022
Publisher : BIORE Scientia Publisher

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/jbes.2022.15152

Abstract

Along with the growth in oil palm output, the amount of trash produced will also increase. Every palm oil mill is responsible for the disposal of liquid waste known as palm oil mill effluent (POME). POME includes very high levels of BOD and COD, which may hinder the development of microalgae. Before POME may be utilized as a medium for the growth and development of microalgae, a detailed investigation is required to establish the pretreatment measures necessary to reduce the BOD and COD levels. The purpose of this investigation of POME waste as a substrate for the growth and development of microalgae is to examine the POME processing procedure utilizing wild microalgae. The experimental technique consisted of adding POME and microalgae to the Erlemeyer in accordance with the required proportion. Research demonstrates that POME pond IV waste may be utilized as a substrate for the development of wild microalgae to lower POME waste BOD and COD levels. The variables used were the ratio of POME to microalgae volume and the quantity of nutrients supplied. Microalgae growth at a ratio of 1:4 produced the greatest decreases in BOD and COD, namely 61.66 ppm and 173.33 ppm from 110.6 ppm and 496.67 ppm, respectively. The impact of adding nutrient C at a concentration of 120 ppm led to the greatest decrease of BOD and COD, namely 65.33 ppm and 186.67 ppm, whereas adding nutrient N at a concentration of 40 ppm led to the greatest reduction of BOD and COD, namely 55.41 ppm and 158.33 ppm.
Potency of Microalgae as Biodiesel Source in Indonesia Hadiyanto Hadiyanto; Widayat Widayat; Andri Cahyo Kumoro
International Journal of Renewable Energy Development Vol 1, No 1 (2012): February 2012
Publisher : Center of Biomass & Renewable Energy, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/ijred.1.1.23-27

Abstract

Within 20 years, Indonesia should find another energy alternative to substitutecurrent fossil oil. Current use of renewable energy is only 5% and need to be improved up to 17%of our energy mix program. Even though, most of the area in Indonesia is covered by sea, howeverthe utilization of microalgae as biofuel production is still limited. The biodiesel from currentsources (Jatropha, palm oil, and sorghum) is still not able to cover all the needs if the fossil oilcannot be explored anymore. In this paper, the potency of microalgae in Indonesia was analysed asthe new potential of energy (biodiesel) sources.
UV Irradiation and Ozone Treatment of κ-Carrageenan: Kinetics and Products Characteristics Aji Prasetyaningrum; Widayat Widayat; Bakti Jos; Yudhy Dharmawan; Ratnawati Ratnawati
Bulletin of Chemical Reaction Engineering & Catalysis 2020: BCREC Volume 15 Issue 2 Year 2020 (August 2020)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.15.2.7047.319-330

Abstract

The low molecular weight (LMW) of sulfated polysaccharides including k-carrageenan, is shows a wide spectrum of biological activities. This research investigates the influence of UV irradiation, ozone (O3), and the combination of O3/UV methods on the depolymerization of k-carrageenan. The depolymerization kinetics of k-carrageenan using the Advanced Oxidation Process (UV/O3) was also studied. Furthermore, the intrinsic viscosity method was used to determine the average molecular weight of the research sample, and a mathematical model was developed to predict the kinetic rate constant, as a function of ozone dosage and UV irradiation intensity. Therefore, the physicochemical and morphological properties of the degraded k-carrageenan were analyzed by FT-IR, SEM, and XRD. The intrinsic viscosity k-carrageenan decreases with increasing UV light intensity and ozone concentration. The combination of UV/O3 treatment appeared to be more effective than the individual approaches, as the highest kinetic rate constant for depolymerization was 1.924×10-4 min-1, using 125 mg/L ozone concentration and 40 mW/cm2 of UV lamp intensity. This research also evaluated the relationship between various experimental conditions, including UV lamp power dissipation and ozone concentration on the reaction kinetics model, and the results suggest that lower effect is contributed by UV irradiation intensity. In addition, FT-IR spectra showed the absence of any significant change in the functional properties of k-carrageenan treated with UV and O3 processes, although the morphological properties of the LMW k-carrageenan were rougher and more porous than the native k-carrageenan. Copyright © 2020 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
Preparation and Characterization of Anadara Granosa Shells and CaCO3 as Heterogeneous Catalyst for Biodiesel Production Hadiyanto Hadiyanto; Sri Puji Lestari; Widayat Widayat
Bulletin of Chemical Reaction Engineering & Catalysis 2016: BCREC Volume 11 Issue 1 Year 2016 (April 2016)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.11.1.402.21-26

Abstract

Nowadays, the use of homogenous catalyst has been gradually reduced for its operational reason. The homogenous catalyst leads in difficulty of separation after the process completed and the life cycle is shorter. Therefore, most of researches are introducing heterogenous catalyst for its substitution. This research was aimed to evaluate the use of shell of Anadara granosa and CaCO3 as source of CaO based catalyst through impregnation method. The preparation of the catalyst was started by decomposition of shells and CaCO3 at temperature of 800 oC for 3 hours, followed by impregnation at 70 oC for 4 hours and then calcined at 800 oC for 2 hours. The CaCO3 based catalyst gained high yield of biodiesel (94%) as compared to Anadara granoasa based catalyst (92%). The reusability study showed that these catalysts could be used until three times recycle with 40-60% yield of biodiesel. The CaO contents of catalyst decreased up to 90% after three times recycles. 
Penggunaan Ekstrak Kulit Pisang Ambon Sebagai Baku Pembuatan Moutwash Herbal Banowati, Tria Nita; Silviana, S; Widayat, Widayat
Indonesia Journal of Halal Vol 6, No 1 (2023): IJH
Publisher : Pusat Kajian Halal Undip

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/halal.v6i1.19156

Abstract

Abstract Utilization of Ambon Banana Peel Extract as a Raw Material for Making Herbal Mouthwash, Ambon banana peel extract was prepared in the form of hand rinse or mouthwash. The treatment in making banana peel extract extract into Mouthwash was made into 2 variables, namely variable 1 Ambon banana peel which had been incubated and extracted for 7 days, and variable 2 Ambon banana peel with an incubation period and extraction for 10 days. The Mouthwash formulation is made in a formulation with the main ingredient being Ambon banana peel extract. Mouthwash evaluation carried out was organoleptic test (shape, smell, color, and taste), pH test, antibacterial activity test. The conclusion of this study is that Ambon banana peel extract can be made in the form of mouthwash which is safe for kids. Keywords:  author guidelines; Ambon banana peel, maceration extraction, Herbal Mouthwash  Abstrak Kulit pisang ambon (Musa Acuminata) merupakan limbah tanaman buah pisang yang mana masih mengandung berbagai macam nutrien. Salah satu komponen terbesarnya yaitu tanin dan flavonoid yang dapat digunakan sebagai bahan baku pembuatan antiseptik. Dalam penelitian ini dibuat ekstrak kulit pisang ambon dalam bentuk sediaan pembilas tangan atau Mouthwash. Perlakuan dalam pembuatan ekstrak kulit pisang menjadi Mouthwash dibuat menjadi 2 variabel yaitu variabel 1 kulit pisang ambon yang telah di inkubasi dan di ekstraksi selama 7 hari, dan variabel 2 kulit pisang ambon dengan masa inkubasi dan ekstraksi selama 10 hari. Formulasi Mouthwash dibuat dalam formulasi dengan bahan utamanya adalah ekstrak kulit pisang ambon. Evaluasi Mouthwash yang dilakukan adalah uji organoleptis (bentuk, bau, warna, dan rasa), uji pH, uji daya antibakteri. Kesimpulan dari penelitian ini adalah ekstrak kulit pisang ambon dapat dibuat dalam bentuk sediaan Mouthwash yang aman. Kata Kunci: kulit pisang ambon, ekstraksi maserasi, Handsanitizer herbal 
Effect Of Liquid Smoke And Carrageenan To Beef Meatball Texture And Lightness Widayat, Widayat; Afriani, Nurfika
Indonesia Journal of Halal Vol. 4 (1) 2021
Publisher : Pusat Kajian Halal Undip

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/halal.v4i1.13674

Abstract

AbstractBeef meatballs lots sold in the market with additional preservatives that are not recommended for food. This study will discuss the use of liquid smoke to preserve beef meatballs with the addition of carrageenan as firmness agent. The purpose of this study was to determine the optimum composition of addition of liquid smoke and carrageenan. Beef meatballs prepared by adding liquid smoke and carrageenan on a particular variation into meatballs dough. Liquid smoke variation used was 0.5%-1%, and carrageenan variation used was 0.5%-1.5%. The meatballs that has been created and then stored for 0, 12, 24, and 36 hours. The results of optimization using RSM shows the maximum value of hardness and springness of beef meatballs obtained in 24 hours of storage. The optimum composition of liquid smoke and carrageenan on the hardness and springness obtained on the liquid smoke concentration 0.755% and 1.04% carrageenan. The addition of carrageenan in beef meatballs provide a dominant influence on the texture. Lightness test is not a significant effect on the addition of liquid smoke and carrageenan, but give significant effect on the storage time, the longer the storage time, the lightness of the color of beef meatballs was decrease
Co-Authors A Abdullah A Abdurrakhman Abdullah Abdullah Achmad Roesyadi Achmad Roesyadi Achmad Wildan ADE ARTA, MOCHAMAD ZAINUDIN Adi Darmawan Adit Rizky Wicaksono Afriani, Nurfika Agus Suprihanto Ahmad Juanda Ahmad Ni’matullah, Albaari Aini, Apsari Puspita Aji Baharsyah Aji Prasetyaningrum Aji, Satriyo Akbar Asfar, A.M. Iqbal Al-Baari, Ahmad N Al-Baarri, Ahmad Ni'matullah Al-Baarri, Ahmad Ni’matullah Alfareza, Muhammad Ircham Almaas Salwa, Diah Ayu Andi Friadi Andika Pradifan Andrew Bryano Kermite, Andrew Bryano Andri Cahyo Kumoro Andri Cahyo Kumoro Andrianto, Novian Andry Anggoro Arahim Anggra Widhi Anggra Widhi Anik Sarminingsih, Anik Annisa Metantya Maharani Ari Eko Prasetyo Ari Eko Prasetyo Ariadi, Ariadi Arianti Nuur Annisa Arief Budiman Aris Triwiyatno Arwan, Berriandi Aulia, Haris Nu’man B Budiyono Bacthiar, Hafni Bagus Agang Sudrajat Bakti Jos Bambang Cahyono Banowati, Tria Nita Berkah Fajar Tamtomo kiono Bernike Vemmialia Jonfita Budi Warsito Budianto, Irawan Arief Catur Pramono D. Ingrid A D. Soetrisnanto Dani Puji Utomo Danny Soetrisnanto DENNY SANJAYA Devina Ingrid A. Dita Ayu Sofiati Driastuti, Faradilla Dyah Hesti Wardhani Edward, Leonardo Ela, Hulasoh Elijah Syarief Elysia, Alvina Enda Merizki br Ginting Fauzandy Husna Setyanto Ferdy D, Erbert H Hadiyanto H M Rachimoellah H Satriadi H. Satriadi H. Satriadi Hadiyanto Hadiyanto Hanapi bin Mat Hanapi bin Mat Handung Nuryadi Hanifa Zakiyatul Urbach Hantoro Satriadi Hantoro Satriadi Hantoro Satriado Haris Nu'man Aulia Haris Nu’man Aulia Hasanah, Alfi Hendra Try Ardianto Hendro, Andika Heru Susanto Hesti Rahayu I. Hartati Ika Windrianto K. Handono Indah Hartati Iqbal Mubarak Irawan Arif Budianto Irayani, Indah Jafron Wasiq Hidayat Johnner P Sitompul Khoirun Nisa Kurdianto Kurdianto Kurnia, Atik Kusdiantini, Endang Kusmiyati, K Lukman Hakim Firdaus Luqman Buchori Luqman Buchori M. Djaeni M. Hadi M. Hadi M. Hadi Makrufah Hidayah I Marcelinus Christwardana Maria Siahaan Marta Chandra Anikke Putri Masyhad Masyhad Meiny Suzery Melati, Emilla Mhd. Adithia Perdana Arman Mochamad Arief Budihardjo MSK. Tony Suryo Utomo Muchammad Muchammad Muhammad Farizan Praevia Muhammad Hilmazar Hawari Muhammad Rachimoellah Muhammad Rachimoellah Muhammad Syukri Hasan Muhammad Syukri Hasan Nabilla Salma Listyawijayanti Nasir, Yahya Ndaru Okvitarini Ngadiwiyana M.Si. S.Si. Ngurah Widiantara Ni'matuzahroh Ni'matuzahroh Novianti, Khusnul Rofida Noviyanto, Sigit Nur Rokhati Nurjannah, Rifa Nurul Yaqin Pandapotan, Boris Poltak Prakoso, Satrio Budi Prasetyo, Ahmad Wisnu Pratomo, Shendy Eko Priyosetyoko Priyosetyoko, Priyosetyoko Puja Chrisdianto Manapa Putri, Sylvia Rahmi Rahmania, Yusi Luluk Ratnawati Ratnawati Razak, Habibie Riky Yonas Riky Yonas Riva Amrulloh Roz, Kenny S Suherman S Supriyandi Samudra, Makitta Widi Saudale, Jeanette Mutiara Paula Sekarningtyas, Nazifa Seno, Abdi Setia Budi Sasongko Setia Budi Sasongko Setiadi, Muhammad Irfan Sianturi, Aurelia Genesya Silviana Silviana Silviana, S Siti Nur Khairunisa Aroli Sri Nastiti Andharini Sri Puji Lestari Sri Widodo Agung Suedi Sriatun Sriatun Striadi, H. Sugiyanto - Sulardjaka Sulardjaka Sulardjaka Sulardjaka Sulardjaka, S Sulastri, Cucu Sumiati Sumiati Suroso Agus Saputro Sussatrio, Hardito Syafrudin Syafrudin Syaiful . Sylvia Rahmi Putri Tatang H. Soerawidjaja Taufiq, Akbar Teguh Purnomo, Teguh Tri Winarni Agustini Tri Winarni, Agustini Tutuk Djoko Kusworo Uray Irzandi Uray Irzandi Utama, Bobby Indra Vicky Ramadhani, Vicky widodo, anton sri Wira Pinem Yanuar Rifianto YS Darmanto Yudhy Dharmawan Yuliani, Kristina Wulan Yulita Arni Priastiwi Yuliyandjaja, John Philia Yusi Luluk, Rahmania