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Journal : Science and Technology Indonesia

Nickel Salt Dependency as Catalyst in the Plating Bath on the Film Properties of Cu/Cu-Ni Rosyidan, Cahaya; Kurniawan, Budhy; Soegijono, Bambang; Maulani, Mustamina; Samura, Lisa; Nababan, Frederik Gresia; Putra, Valentinus Galih Vidia; Susetyo, Ferry Budhi
Science and Technology Indonesia Vol. 9 No. 3 (2024): July
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/sti.2024.9.3.529-538

Abstract

Metal plating frequently employs nickel (Ni) and copper (Cu) as anodes. Cu/ Cu-Ni film formed has many advantages, such as better corrosion resistance and high hardness characteristics. This study aims to assess the properties of Cu/Cu-Ni film, such as phase, surface morphology, crystallographic orientation, hardness, corrosion analysis, and contact angle, which were fabricated using electrodeposition with various Ni salt additions (0.3, 0.5 and 0.7 M). In addition, the cathode current efficiency (CCE) and deposition rate of the Cu/Cu-Ni electrodeposition were also investigated. An increase in Ni salt in the plating bath could enhance the pH, promoting higher CCE and depleting hydrogen evolution at the cathode, leading to the presenting Ni phase in the alloy. The higher concentration of Ni salt in the solution could also enhance the deposition rate due to a shift to a pH value, which affects the roughening of the surface morphology, promoting a higher contact angle. All crystal structures generated by Cu/Cu-Ni electrodeposition were FCC, with the preferred orientation of the (111) plane. Crystallite size and lattice strain depend on the deposition rate. Less crystallite size and lattice strain affect the film’s hardness and corrosion resistance. Moreover, the third bath had the resulting Cu-Ni layer with the best hardness and corrosion rate of around 136 HV and 0.081 mmpy.
Carbon Micron-size Content Dependency in Epoxy/Carbon Composite Coated onto SPCC Plate for Automotive Bodies Protection Anggrainy, Rani; Susetyo, Ferry Budhi; Lubi, Ahmad; Yudanto, Sigit Dwi; Rosyidan, Cahaya; Soegijono, Bambang; Ajiriyanto, Maman Kartaman; Kurniawan, Ova; Nanto, Dwi
Science and Technology Indonesia Vol. 9 No. 4 (2024): October
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/sti.2024.9.4.989-998

Abstract

Conventional epoxy coating for surface metal corrosion protection reported many unsolved technical problems. Adding filler in the epoxy could enhance the promising properties of the composite coating. Our work describes in detail the synthesizing and characterizing epoxy/carbon composite coating. Epoxy was mixed with thinner high gloss (HG) and hardener and stirred using a stirrer apparatus. After blending, various carbons were added (1 wt. %, 3 wt. %, and 5 wt. %) and then appropriately stirred. The different mixture composite was coated onto the steel plate cold rolled coiled (SPCC) plate using high-volume low-pressure (HVLP) in two passes. Various characterizations were performed, including crystallographic orientation, Infra-Red (IR)-spectra, surface morphology, thickness, hydrophobicity, hardness, and corrosion using X-ray diffraction (XRD), Fourier transform infrared (FTIR), Scanning electron microscopy (SEM), portable dry film coating thickness (DFT), digital camera, Vickers microhardness tester, and Potentiostat, respectively. More carbon micron-sized content led to elevate the peak intensity, surface bumpiness, and hydrophobicity. The uppermost external bumpiness and hydrophobicity values are 23.51 µm and 101◦. Hardness depends on carbon content and more carbon leads to an increase in the hardness of the composited coating. The highest average Vickers hardness value is 28.24 HV. The coating thickness influenced the corrosion rate, more coating thickness promoted lesser corrosion rate. The highest coating thickness (60.8 µm) promoted a corrosion rate of around 5.65×10−4 mmpy.
Cu Film Characteristics Synthesized Using Electrodeposition Technique at Various Currents and Under a Rotating Neodymium Magnet Susetyo, Ferry Budhi; Basori; Mansor, Muhd Ridzuan; Ruliyanta; Yudanto, Sigit Dwi; Rosyidan, Cahaya; Situmorang, Evi Ulina Margareta; Edbert, Daniel; Mutiara, Etty; Yulianto, Tri; Agus Jamaludin; Nanto, Dwi
Science and Technology Indonesia Vol. 10 No. 4 (2025): October
Publisher : Research Center of Inorganic Materials and Coordination Complexes, FMIPA Universitas Sriwijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/sti.2025.10.4.1156-1168

Abstract

In the present study, Cu films were made over Al alloy using the electrodeposition technique. Electrodeposition conducted at various currents (80, 100, and 120 mA), with and without influence by a rotating magnetic field (100 rpm of rotation). 0.5 M CuSO4 + 20 mL of H2SO4 was used for electrolyte solutions. The sample before and after electrodeposition was weighed using digital scale to calculate deposition rate and current efficiency. All formed Cu films were characterized using X-ray diffraction (XRD), attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), Scanning electron microscopy equipped with Energy dispersive spectroscopy (SEM-EDS), and Potentiostat apparatus. Furthermore, antibacterial activity using Staphylococcus aureus was also investigated. Increasing the current of electrodeposition leads to an increase in deposition rate and current efficiency for both conditions (with and without rotating magnetic field influence). Based on the XRD and ATR-FTIR investigation, Cu was successfully deposited onto Al surface. Currents used for the electrodeposition process between 80-100 mA would result in a faceted structure, while using 120 mA results near to spheroidal. Shifting to higher currents leads to decreases in grain sizes and presenting a rotating magnetic field also enhances the grain size. Current and rotating magnetic influences are not linearly influencing corrosion potential, corrosion rate and antibacterial activity. The sample made using higher current plus influencing with a rotating magnetic field has less corrosion rate and higher area of inhibition at around 0.808 mmpy and 4.01 cm2.
Co-Authors - Sunardi - Sunardi Abdul Hamid Agus Jamaludin Alfiandi Sembiring Aliya Mayendra Ammar Ammar Andreas Junianto Andreas Junianto Andry Prima Anggrainy, Rani Arinda Riswati Arkaan, Muhammad Dzaki Aryanto, Reza Asri Nugrahanti Asri Nugrahanti, Asri Aulia Alfath Auliya, Hilyah Bambang Soegijono Bambang Soegijono Basori Basori Basori Bayu Satiyawira Bayu Satyawira Bayu Satyawira Bayu Satyawira, Bayu Budhy Kurniawan Bujasuandi Maulana Cahyaningratri Prima Riyandhani Dalimunthe, Yusraida Khairani Daniel Edbert Daniel Edbert, Daniel Dio Rekayandra Djunaedi Agus Wibowo Dwi Nanto, Dwi Dwi Nuryana, Suherman DWI YULIANTI Etty Mutiara Evi Ulina Margareta Situmorang Evi Ulina Margaretha Situmorang Ezenwune, Jose Andreas Ferry Budhi Susetyo Ferry Budhi Susetyo Gabriella Jasmine Galih Vidia Putra, Valentinus Gemintang Atlantika Urbiyanto hanz seca rifansyah cipta maheza Harin Widiyatni Havid Pramadika Havidh Pramadika Heri Hardiyanti Hidayat, Hifdzan Rizki Hidayat, Hifzhan Rizki Hilyah Auliya Imam Setiaji Ronoatmojo Irwan . Irwan . Irwan Irwan Jasmine, Gabriella kartika fajarwati hartono Kashah, Muhammad Refli Koesmawardani, Wildan Tri Kurniawan, Ova Livia Ailen Dharma Lubi, Ahmad Lukas Pearlo, Kevin M.T Fathaddin Maman Djumantara Maman Djumantara, Maman Maman Kartaman Ajiriyanto Mansor, Muhd Ridzuan Maulani, Mustamina Michael, David Mixsindo Korra Herdyanti Mohamad, Juliany Ningsih Mohammad Apriniyadi Muh Taufiq Fathaddin Muhammad Burhannudinnur Muhammad Burhannudinnur Muhammad Burhannudinnur Muhammad Yunan Hasbi Mulia Ginting, Mulia Mustamina Maulani Mustamina Maulani Nababan, Frederik Gresia Nadhira Andini Nugraheni, Rosmalia Dita Onnie Ridaliani Onnie Ridaliani, Onnie Pantjanita Novi Hartami Pauhesti Pauhesti Pauhesti Pauhesti Pauhesti Pauhesti, Pauhesti Pearlo, Kevin Lukas Pramadika, Havid Prapansya, Onnie Ridaliani Puri Wijanti Putra, Raka Handika Putra, Valentinus Galih Vidia Raihan Ramadhan Raisha Marsha Raka Handika Putra Ratnayu Sitaresmi Renanda, Raka Ilham Ririn Yulianti Riswati, Arinda Risyad Baihaqi Rizki Ananda Parulian Rosika Kriswarini Rosmalia Dita Nugraheni Rosmalia Dita Nugraheni Ruliyanta Samsol Samura, Lisa Shabrina Sri Riswati Sigit Rahmawan Soekardy, Mentari Gracia Suherman Dwi Nuryana Suryo Prakoso, Suryo Syamsuir, Syamsuir Tina Martina Tina Martina, Tina Totong Irwan Tri Yulianto Urbiyanto, Gemintang Atlantika Valentinus Galih Vidia Putra Valentinus Galih Vidia Putra Widia Yanti, Widia Wijayono, Andrian wiwik dahani, wiwik Yarra Sutadiwiria Yudanto, Sigit Dwi zakiah darajat