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Journal : Journal of Applied Materials and Technology

The Oriented Attachment Crystal Growth Model in Hydrothermal Synthesis of Magnetite (Fe3O4) Nanoparticles Ahmad Fadli; Amun Amri; Esty octiana sari; Sukoco Sukoco; Deden Saprudin
Journal of Applied Materials and Technology Vol. 1 No. 1 (2019): September 2019
Publisher : AMTS and Faculty of Engineering - Universitas Riau

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31258/Jamt.1.1.15-19

Abstract

The magnetite nanoparticles (Fe3O4) are very promising nanomaterials to be applied as drug delivery due to their excellent superparamagnetic, biocompatibility and easily modified surface properties. Those properties are influenced by the structure and size of the material which can be controlled by studying the evolution of crystal growth. The purpose of this research is to study the evolution of crystal growth of magnetite nanoparticles in the hydrothermal system and determine the crystal growth kinetics using the Oriented Attachment Growth model. Magnetite nanoparticles were synthesized using a hydrothermal method from FeCl3, citrate, urea and polyethylene glycol at 210?C for 1 - 12 hours at a various concentration of FeCl3 (0.05 M, 0.10 M, and 0.15 M). The characterizations were conducted by X-ray Diffraction (XRD), Transmission Electron Microscope (TEM), Particle size analyzer (PSA), and Vibrating Sample Magnetometer (VSM). The XRD difractogram indicated that the magnetite was begun to form at 3.5 hours synthesis. The crystallinity and the crystal size of magnetite rose with reaction time. The diameter of magnetite crystals was in the range of 9.4-30 nm. Characterization by TEM showed that the particles were formed from a smaller particles which were then agglomerated. The PSA characterization showed that the distribution of diameter size enlarged with the enhancement of concentrations. VSM result showed that the magnetite nanoparticle has superparamagnetic properties. The magnetite crystal growth can be fitted by the Oriented Attachment Growth model with an error of 29%.
Hydrocarbon-Impacted Soils Supported Mn for Organic Pollutant Oxidation Saputra, Edy; Fadli, Ahmad; Prawiranegara, Barata Aditya; Amri, Amun; Heltina, Desi; Bahri, Syaiful; Sandhyavitri, Ari; Restuhadi, Fajar; Abid, Hussein Rasool; Azhar, Muhammad Rizwan; Utama, Panca Setia
Journal of Applied Materials and Technology Vol. 4 No. 2 (2023): March 2023
Publisher : Faculty of Engineering Universitas Riau and Applied Materials and Technology Society

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31258/Jamt.4.2.90-98

Abstract

Hydrocarbon-impeded soil (HIS) is solid waste from spills or leaks during industrial activities that negatively impact the environment. This study aims to utilize HIS as catalyst support on MnO2 to degrade RhB (RhB) solution using Peroxymonosulfate (PMS) and to determine the optimum conditions for the catalyst to degrade RhB. The catalyst was synthesized by reacting HIS, calcined with KMnO4 with various catalyst supports with high and low Total contain Petroleum Hydrocarbon (TPH). The process degradation of Rhodamine Solution was carried out with various catalysts, PMS, and RhB concentrations. The catalyst was characterized using X-ray diffraction (XRD), Nitrogen gas adsorption-desorption (BET), and Scanning Electron Microscope-Energy Disperse Spectroscope (SEM-EDX). In this study,  the best catalyst performance was MnO2@H-TPH, which could activate PMS to degrade RhB with dye removal of 98% in about 180 min, at conditions 10 g/L RhB, 0.1 g/L catalyst, and 3 g/L PMS with the activation energy of 16.3 kJ/mol.
Metal-Free Activated Carbon Catalytic for Degradation of Organic Contaminants by Peroxydisulfate Activation Prawiranegara, Barata Aditya; Setia Utama, Panca; Amri, Amun; Nurhayati; Muhdarina; Awaluddin, Amir; Saputra, Edy
Journal of Applied Materials and Technology Vol. 5 No. 1 (2023): September 2023
Publisher : Faculty of Engineering Universitas Riau and Applied Materials and Technology Society

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31258/Jamt.5.1.20-26

Abstract

Green chemistry has become trending recently, and the discovery of environmentally friendly catalysts is mandatory. Activated carbons (ACs) are one of the most environmentally friendly yet cheap materials that have the potential for catalyst application. Three commercially available ACs from Pancasari, Norit, and Chemical Supply were used as metal-free catalysts for advanced oxidation process (AOP) phenol removal in water in the presence of oxidants peroxydisulfate (PDS), and hydrogen peroxide (H2O2). It was found that ACs were effective to be used as catalysts for activating those oxidants to oxidize phenol in AOP reactions. In this study, the surface area of the catalyst significantly improved the phenol removal efficiency. ACs Pancasari (ACP) with the highest surface area has the best degradation performance of phenol removal with up to 99% removal efficiency in 60 minutes under the condition of [phenol] = 30 mg L-1, [ACP] = 0.2 g L-1, [PDS] = 3.3 mmol L-1, and T = 25oC. it was also found that the degradation process was significantly influenced by reaction temperature. Nevertheless, in this study, ACs display the potential as catalysts in the AOP process for wastewater treatments.
Co-Authors AA Sudharmawan, AA Abda Abda Abdul Rasyid Amrin Abid, Hussein Rasool Achmad Noerkhaerin Putra Adrianto Ahmad Affandi Affandi Ahmad Fadli Ahmad Fadli Ahmad Fadli Aisyah Dewi Ranti, Aisyah Dewi Akbar, Irfan Sarhadi Alfarizi, Cory Dian Alfatlian, Alfatlian Ali Novia Altarawneh, Mohammednoor Aman Aman Aman, Azka Amila, Khairati Aminati, Ikha Setya Amir Awaluddin Amri, Evelyn Andrizal Andrizal Ani Suryani Anjani, Putri Annisa Rahmat Apriadi Rio Ari Sandhyavitri Arisman Adnan Assylzhan, Mazhibayev Azhar, Muhammad Rizwan Azhari Harahap Azridjal Aziz Bahri, Ahmad Syaiful Bahruddin Bahruddin Bahruddin Bahruddin Bahruddin Benny Ahmadi Bona Tua Chairul Chairul Chairul Damayanti, Elok Deden Saprudin Dedeng Hermoyo Derry Hanriansyah Pratama Desi Heltina Dhini Octavianty Dimas Nofriyan Dumaria, Agustina Dwi Setyo Pambudi, Yoyok Ekawati, Lestari Elmira, Kambarova Erliza Hambali Esty Octiana Sari Esty Octiana Sari Eva Rantika Evelyn Evelyn Evelyn Evelyn Evelyn Evi Nadhifah Fabryza, Dhina Fajar Restuhadi Fajrina Qaishum Fakhri, Fakhri Fauziyah, Hidayatul Febri Riandi Febrizal Ujang Febryza, Dhina Feby Pratama Nugraha Fesya Putri, Andini Firman syah Fitri, Lara Ismano Fri Murdiya, Fri Gilang Fathurrahman Gilda Miranda Gussyafri Hasnul Bustaman Hawa, Karfika Ainil Hawa, Karfika Ainil Hendri, Yola Bertilsya Hendro Ekwarso Heni Sugesti Heri Rahmana Indra Yasri Irwan Irwan Is Sulistyati Isna Rahma Dini Iwantono Iwan Barnawi Jhon Armedi Pinem Jiang, Zhong Tao Jumbri, Khairulazhar Karfika Ainil Hawa Khairat Khairat Khairat Khusnul Ain Komalasari Komalasari Komalasari Komalasari Komalasari Lisa Legawati Lucy Rahmawati M. Fauzan Akbar M. Iwan Fermi M. Yogi Riyantama Isjoni Malindo, Muhammad Eri Maria Peratenta Sembiring Mawaddah Mawaddah, Mawaddah MAYANG SARI Mayangsari Mayangsari Meliagustin, Adilla Michael Hutapea Miran, Hussein A. Mochamad Reizal Ath Thariq Monita Olivia Muhamamad Rizky Zuriadi Muhammad Shalahuddin Muhammad Shalahuddin Muhammad Sugandi Muhammad Zaqi Muhdarina Nabellia Nisa Mulya Novan, Andre Novia Azzahra Nurhayati Nurwijayanti Nurwulandari Saputri Ohi, Hiroshi Oktariandi, Vito Paul Destin Purba Peratenta Sembiring, Maria Perdana, Rendy Putra Peter Peter Prawiranegara, Barata Aditya Puji Rahmawati Dwi Sukma Putra, Rahmat Ade Putri Arini Putri Husni Hidayah, Putri Husni Putri, Diana Eka Rahayu, Ricky Puji Rahmadahana, Suci Rahman, M Mahbubur Rahman, M. Mahbubur Rahmansyah Rahmansyah Rahmat Kurniawan Nasution Rahmi, Sri Wahdini Rani Handayani Reni Yenti, Silvia Reski, M. Rifati Hanifa Rino Rinaldi Rizka Aulia Hardi, Rizka Aulia Rizky, Muhammad Dian Rozanna Sri Irianty Russita Martani Russita Martani Rusydy ' Salma Liska Saputra, Adika Saputra, Fakhri Sari Rahma Yanti Sari, Esty Octiana Sarma, Deki Septian, Handika Setia Utama, Panca Setiani Br Manurung Silvia Reni Yenti Silvia Reni Yenti Suci Afrianti Sukoco Sukoco Sukoco Sukoco Sulistyo Saputro Sunarno SUNARNO Sunarno Sunarno SYAIFUL BAHRI Syamsu Herman Syelvia Putri Utami Syukri Hamdani Tafrikhatul Walidah Tao Jiang, Zhong Utama, Panca Setia Voadi, Salsabilla Diva Wilda Zakiah Windy Odelia Putri Wira Irawan Rossani Wisrayetti Wisrayetti Wisrayetti Wisrayetti Wisrayetti, Wisrayetti Wulandari, Revika Yang, Chun-Chen Yelmida Azis Yolanda, Yogi Yopalim Zanstra Yoselino, Danil Yosi Alwinda Yosi Alwinda, Yosi Yusnimar Sahan Z Zulfansyah Zikri, Ahmed Zuchra Helwani, Zuchra Zultiniar Zultiniar Zultiniar Zultiniar Zultiniar Zultiniar Zultiniar, Zultiniar Zuqni Meldha