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Journal : Reaktor

PENGARUH WAKTU DEALUMINASI DAN JENIS SUMBER ZEOLIT ALAM TERHADAP KINERJA H-ZEOLIT UNTUK PROSES DEHIDRASI ETANOL Widayat Widayat; Achmad Roesyadi; Muhammad Rachimoellah
Reaktor Volume 13, Nomor 1, Juni 2010
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (593.546 KB) | DOI: 10.14710/reaktor.13.1.51-57

Abstract

Katalis H-zeolit telah disintesa dari zeolit alam. Proses pembuatan katalis meliputi tahap proses pelakuan kimia, penyaringan dan pencucian, pengeringan dan proses kalsinasi. Penelitian ini bertujuan mempelajari waktu dan sumber bahan baku terhadap karakteristik katalis yang meliputi perbandingan Si/Al, X ray Diffraction (XRD) dan luas permukaan. Hasil penelitian menunjukkan bahwa perlakuan kimia menyebabkan penurunan kadar CaO, MgO dan Na2O karena melarut dalam asam klorida. Perbandingan Si/Al juga menurun dengan meningkatnya waktu operasi dan nilai Si/Al tertinggi pada waktu perlakuan kimia 7 jam. Hasil analisa XRD dari produk katalis tidak dipengaruhi oleh waktu. Luas permukaan spesifik dan volume total pori bernilai tertinggi pada waktu operasi 10 jam sebesar 184,52 m2/gram dan volume total pori 108,243 x 10-3 cc/gram. Hasil uji katalitik menunjukkan bahwa katalis KZ A dan KZ B dapat digunakan untuk proses dehidrasi etanol, yang ditunjukkan adanya produk DiEtil Eter pada proses dehidrasi. Yield DiEtil Eter terbaik diperoleh untuk katalis zeolit KZ A 10 yaitu sebesar 1,78% dan KZ B 15 sebesar 0,28%.
KINETIKA REAKSI PADA PROSES PRODUKSI DIETIL ETER DARI ETANOL DENGAN KATALIS H-ZEOLIT Widayat Widayat; Achmad Roesyadi; Muhammad Rachimoellah
Reaktor Volume 14, Nomor 2, Oktober 2012
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (151.162 KB) | DOI: 10.14710/reaktor.14.2.101-108

Abstract

DiEtil Eter diproduksi dari etanol dengan proses dehidrasi. Penelitian ini bertujuan untukmempelajari kinetika reaksi proses dehidrasi etanol dengan katalis H-zeolit. Katalis H-zeolitdisintesis dengan proses dealuminasi dan kalsinasi dan impregnasi dengan logam Al dan prosesreduksi dan kalsinasi. Proses produksi DiEtil Eter dilaksanakan dengan proses adsorpsi dan reaksikatalitik sedangkan proses studi kinetika reaksi menggunakan pendekatan Langmuir-Hinshelwood.Proses analisis kinetika reaksi menggunakan perangkat lunak MATLAB. Model kinetika reaksi prosesdehidrasi etanol menjadi DiEtil Eter dan etilen dengan katalis H-zeolit pada konsentrasi umpanetanol 85-95% dan rentang temperatur 140-240oC, dimana reaksi permukaan yang mengontrol reaksiglobal adalahDiEthyl Ether is produced by using ethanol dehydrationprocess. The objective of this research was to study the reaction kinetic of ethanol dehydrationprocess by H-zeolite catalyst from natural zeolite. The H-zeolite catalyst was prepared bydealumination, calcination, impregnation with Al and reduction processes. DiEthyl Ether productionwas produced by using adsorption-catalytic reaction. The kinetic study was did with MATLABsoftware. Kinetic model of ethanol dehydration processes into DiEthyl Ether and ethylene with Hzeolitecatalyst and ethanol feed concentration among 85-95% and temperature between 140-240oCunder surface reaction is shown by
PEMANFAATAN LIMBAH CAIR INDUSTRI TAHU UNTUK PRODUKSI BIOMASSA MIKROALGA Nannochloropsis Sp SEBAGAI BAHAN BAKU BIODIESEL Widayat Widayat; H Hadiyanto
Reaktor Volume 15 No.4 Oktober 2015
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (359.691 KB) | DOI: 10.14710/reaktor.15.4.253-260

Abstract

Indonesia is one of one of productive tofu producer both for industry or home made scale. Tofu industries contribute wastewater up to 20 millions cubic meter (m3) per year. Currently, tofu waste water was treated by anaerobic and aerobic methods which reveal some disadvantages. To overcome the disadvantages of both methods, wastewater of tofu industry was used as a medium for the cultivation of microalgae. Nannochloropsis sp is one of microalgae species which has high content of lipid and thus can be converted to biodiesel. This study examined the growth rate, biomass productivity, reduced organic levels of COD and BOD, and total lipid of microalgae Nannochloropsis sp which cultivated in tofu wastewater medium. The optimum growth of Nannochloropsis sp was found at 20% vol of liquid waste water which produce lipids of 34.25 % and also can reduce COD up to 77.40 %. The optimum nutrients of NaHCO3 was showed at the composition of 70 mg / L which decrease COD up to 78.81 % and produce lipids 16.841 %. The addition of nutrition every 4 days was able to reduce the COD up to 81.835 % and produce 14.195 % yield of lipids.  Keywords: tofu wastewater, Nannochloropsis sp., biodiesel, COD & BODAbstrak Indonesia merupakan salah satu negara penghasil tahu yang cukup produktif baik skala industri maupun rumahan. Industri tahu menyumbang limbah cair mencapai 20 juta meter kubik (m3) per tahun. Pada saat ini pengolahan limbah tahu cair dilakukan dengan metode anaerobik maupun aerobik. Akan tetapi kedua metode tersebut memiliki beberapa kelemahan. Untuk mengatasi kelemahan kedua metode tersebut, limbah tahu cair dapat dimanfaatkan sebagai media kultivasi mikroalga. Nannochloropsis sp merupakan  mikroalga yang mampu menghasilkan lipid  yang besar tersebut dapat dikonversi menjadi salah satu energi alternative biodiesel. Dalam penelitian ini dikaji laju pertumbuhan, produktivitas biomassa, penurunan kadar organik COD dan BOD, dan total lipid mikroalga jenis Nannochloropsis sp yang dikultivasi pada medium limbah tahu cair. Pertumbuhan Nannochloropsis sp. optimum pada medium 20% volume limbah tahu cair yang menghasilkan lipid sebanyak 34,25% dan dapat menurunkan COD hingga 77,40%.  Penambahan nutrisi NaHCO3optimum pada komposisi 70 mg/l yang mampu menurunkan COD sebesar 78,81% dan menghasilkan lipid sebanyak 16,841%. Waktu penambahan nutrisi setiap 4 hari sekali mampu menurunkan COD sebesar 81,835% dan menghasilkan lipid sebesar 14,195%. Keywords: limbah tahu, Nannochloropsis sp., biodiesel, COD & BOD
Kinetic Study of Kapok Seed Oil Esterification using BMIM-PF6 Catalyst Bagus Agang Sudrajat; Widayat Widayat; Ngurah Widiantara; Hantoro Satriadi; Maria Siahaan; Wira Pinem
Reaktor Volume 20 No.3 September 2020
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (0.164 KB) | DOI: 10.14710/reaktor.20.3.138-149

Abstract

Biodiesel offers better combustion efficiency, lower sulfur content and aromatic compounds, higher cetane numbers than diesel fuel, biodegradable and renewable properties that are not possessed by conventional fuels such as diesel fuel. This study aims to study the modeling of esterification process of Kapok seed oil using 3 % liquid ionic catalyst 1-Butyl-3-MethydidazoliumHexafluorophosphate (BMIM-PF6). The validation results of reaction kinetic models for experiments and simulations provide an adjacent correlation value, that is R2 = 0.99526, with the rate constant value (k) based on experimental data are 0.003815 L/mol.s and 0.0038 L/mol.s for the simulation data. Based on the simulation results, the proper reaction order for this esterification reaction is the first order reaction equation with a value of R2 = 0.99526, while the second order reaction gives the value R2 = 0.89453. The reaction kinetics parameters obtained from the experimental results are A = 0.012 L/mol.s and -Ea = -0.437 kJ/mol, while the reaction parameters of the simulation are A = 1.0384 L/mol.s and -Ea = -89.5 kJ/mol.Keywords: Esterification, Ionic Liquid Catalyst, Kinetic
Biofiksasi CO2 Oleh Mikroalga Chlamydomonas sp dalam Photobioreaktor Tubular Hadiyanto Hadiyanto; W Widayat
Reaktor Volume 15, No.1, APRIL 2014
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (75.288 KB) | DOI: 10.14710/reaktor.15.1.37-42

Abstract

Mikroalga memiliki potensi dalam membiofiksasi CO2 dan dapat dimanfaatkan untuk mengurangi kadar CO2 dalam gas pencemar. Pertumbuhan mikroalga sangat dipengaruhi oleh konsentrasi gas CO2 di dalam gas pencemar. Tujuan penelitian ini adalah untuk mengeetahui kemampuan mikroalga Chlamydomonas sp yang dikultivasi dalam photobioreaktor tubular dalam penyerapan gas CO2 serta untuk mengetahui konsentrasi maksimum gas CO2 dalam umpan untuk memproduksi biomasa mikroalga yang optimal. Percobaan dilakukan dnegan memvariasi laju alir dari 0.03 -0.071 L/menit dan konsentrasi CO2 dalam umpan 10-30%. Hasil penelitian menunjukkan bahwa biomasa mikroalga dapat diproduksi dengan maksimal dengan konsentrasi gas CO2 20% dengan laju alir 0.07 L/min. Semakin tinggi laju alir maka produksi biomasa alga semakin besar. Kecepatan pertumbuhan alga maksimum terjadi pada 0.31 /hari. Pada konsentrasi gas CO2 30%, terjadi substrate inhibition yang disebabkan carbon dalam bentuk ion bicarbonate tidak dapat dikonsumsi lagi di dalam kultur alga. Kata kunci : Mikroalga, chlamydomonas sp, biofiksasi CO2, biogas Abstract Microalgae have a potential for CO2 biofixation and therefore can be used to reduce the CO2 concentration in the gas pollutants. Moreover, microalgae growth is strongly affected by the concentration of CO2 in the exhaust gas pollutants. The objective of this research was to investigate the ability of microalgae Chlamydomonas sp which was cultivated in a tubular photobioreactor for CO2 absorption as well as to determine the maximum concentration of CO2 in the feed gas to obtain optimum microalgae biomass. The experiments were performed by varying the gas flow rate of 0.03 -0.071 L / min and the concentration of CO2 in the feed of 10-30%. The results showed that the maximum biomass of microalgae can be produced with CO2 concentration of 20% vol with a flow rate of 0.07 L / min. The result also showed that increasing the gas flow rate, the greater of the production of algal biomass and the maximum algae growth rate occurred at 0.31 / day. At a concentration of 30% CO2 gas, it occurs a substrate inhibition due to inefficient of bicarbonate use by algae culture.
Preparation of Zirconia Catalyst from Zircon Sand and Catalytic Testing for Biodiesel Production Widayat, Widayat; Almaas Salwa, Diah Ayu; Hasanah, Alfi; Nisa, Khoirun; Saudale, Jeanette Mutiara Paula
Reaktor Volume 24 No.2 August 2024
Publisher : Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/reaktor.24.2.36-40

Abstract

Heterogeneous catalyst in biodiesel production was developed to overcome the disadvantages of using homogeneous catalyst in the process. Zircon catalysts were known to have amphoteric properties which were suitable for simultaneous esterification-transesterification process in biodiesel production. This study aims to investigate the effect of NaCl impregnated zirconia catalyst for biodiesel production through esterification-transesterification process. Wet impregnation method with varying NaCl weight (10-30% w/w) was used to synthesize the zircon catalyst. The synthesized catalyst was analyzed for its crystallinity and surface morphology using XRD and SEM respectively. The effect of catalyst weight (0.5-2.5% w/w) and operation temperature (50-70oC) to biodiesel product were also investigated. The biodiesel composition, density and viscosity were analyzed using GCMS analysis, picnometry and viscosimetry. The XRD and SEM results showed the synthesized zircon catalyst with 20% w/w NaCl loading had a tetragonal structure. The density, viscosity and free fatty acid content (FFA) of the biodiesel product decreased along with increasing catalyst weight, while the fatty acid methyl ester content (FAME) increased. The increasing FAME content was attributed to increasing active sites which accelerated the esterification-transesterification reaction process, yielding more biodiesel product.
Co-Authors A Abdullah A Abdurrakhman A. Sadikky DP Abdullah Abdullah Achmad Roesyadi Achmad Roesyadi Achmad Wildan ADE ARTA, MOCHAMAD ZAINUDIN Adi Darmawan Adit Rizky Wicaksono Afriani, Nurfika Agus Suprihanto Ahmad Juanda Ahmad Ni’matullah, Albaari Ahmad Nur Ihsan Aini, Apsari Puspita Aji Baharsyah Aji Prasetyaningrum Aji, Satriyo Akbar Asfar, A.M. Iqbal Al-Baari, Ahmad N Al-Baarri, Ahmad Ni'matullah Al-Baarri, Ahmad Ni’matullah Alfareza, Muhammad Ircham Almaas Salwa, Diah Ayu Andi Friadi Andika Pradifan Andrew Bryano Kermite, Andrew Bryano Andri Cahyo Kumoro Andri Cahyo Kumoro Andrianto, Novian Andry Anggoro Arahim Anggra Widhi Anggra Widhi Anik Sarminingsih, Anik Annisa Metantya Maharani Aprilina Purbasari Ari Eko Prasetyo Ari Eko Prasetyo Ariadi, Ariadi Arianti Nuur Annisa Arief Budiman Aris Triwiyatno Arman, Mhd. Adithia Perdana Arwan, Berriandi Aulia, Haris Nu’man B Budiyono Bacthiar, Hafni Bagus Agang Sudrajat Bakti Jos Bambang Cahyono Bambang Sudarsono Banowati, Tria Nita Berkah Fajar Tamtomo kiono Bernike Vemmialia Jonfita Budi Warsito Budianto, Irawan Arief Catur Pramono D. Ingrid A D. Soetrisnanto Dani Puji Utomo Danny Soetrisnanto DENNY SANJAYA Dessy Ariyanti Devina Ingrid A. Dita Ayu Sofiati Driastuti, Faradilla Dyah Hesti Wardhani Edward, Leonardo Ela, Hulasoh Elysia, Alvina Enda Merizki br Ginting Fauzan, O. K. Muhammad Fauzandy Husna Setyanto Favian Nafiega Ferdy D, Erbert Fistcar, Wawarisa Alnu H Hadiyanto H M Rachimoellah H Satriadi H. Anggraeni H. Hadiyanto H. Satriadi H. Satriadi Hadiyanto Hadiyanto Hadiyanto Hadiyanto Hamzah, Fazlena Hanapi bin Mat Hanapi bin Mat Handung Nuryadi Hanifa Zakiyatul Urbach Hantoro Satriadi Hantoro Satriadi Hantoro Satriado Hapsari, Farida Diyah Haris Nu'man Aulia Haris Nu’man Aulia Hasanah, Alfi Hazim, M. Syafiq Hendra Try Ardianto Hendro, Andika Herlambang, Andy Rahmadi Heru Susanto Hesti Rahayu I Nyoman Widiasa I. Hartati Ika Windrianto K. Handono Indah Hartati Iqbal Mubarak Irawan Arif Budianto Johnner P Sitompul Khoirun Nisa Kurdianto Kurdianto Kurnia, Atik Kusmiyati, K Lestari, Dwi Fitri Lukman Hakim Firdaus Luqman Buchori M. Djaeni M. Hadi M. Hadi M. Hadi Makrufah Hidayah I Manulang, Amanda Nathalia Harti Marusaha Marcelinus Christwardana Maria Siahaan Marta Chandra Anikke Putri Masyhad Masyhad Meiny Suzery Melati, Emilla Mochamad Arief Budihardjo MSK. Tony Suryo Utomo Muchammad Muchammad Muhammad Farizan Praevia Muhammad Hilmazar Hawari Muhammad Rachimoellah Muhammad Rachimoellah Muhammad Syukri Hasan Muhammad Syukri Hasan Nabilla Salma Listyawijayanti Nasir, Yahya Ndaru Okvitarini Ngadiwiyana M.Si. S.Si. Ngurah Widiantara Ni'matuzahroh Ni'matuzahroh Novianti, Khusnul Rofida Noviyanto, Sigit Nur Rokhati Nurjannah, Rifa Nurul Yaqin Pandapotan, Boris Poltak Prakoso, Satrio Budi Prakoso, Satyo Jati Prasetyo, Ahmad Wisnu Pratomo, Shendy Eko Priyosetyoko Priyosetyoko, Priyosetyoko Puja Chrisdianto Manapa Puteri, Safira Rizkya Putri, Sylvia Rahmi Rahmania, Yusi Luluk Ratnawati Ratnawati Ratnawati, Ida Razak, Habibie Rheza Dipo Ridani, Nuraida Riky Yonas Riky Yonas Riva Amrulloh Roz, Kenny S Suherman S Supriyandi salsabila, elvira Samudra, Makitta Widi Santosa, Edward Emannuel Saudale, Jeanette Mutiara Paula Sekarningtyas, Nazifa Seno, Abdi Setia Budi Sasongko Setia Budi Sasongko Setiabudi, Herma Dina Setiadi, Muhammad Irfan Sianturi, Aurelia Genesya Silviana Silviana Silviana, S Simbolon, Natalia Lydia Efrata Siti Nur Khairunisa Aroli Sonya Hakim Raharjo Sri Nastiti Andharini Sri Puji Lestari Sri Widodo Agung Suedi Sri Widodo Agung Suedy Sriatun Sriatun Striadi, H. Sugiyanto - Sulardjaka Sulardjaka Sulardjaka, S Sulastri, Cucu Sumiati Sumiati Suroso Agus Saputro Sussatrio, Hardito Syafrudin Syafrudin Syaiful . Syarief, Elijah Syifa, Viona Sylvia Rahmi Putri Tatang H. Soerawidjaja Taufiq, Akbar Teguh Purnomo, Teguh Tri Winarni Agustini Tri Winarni, Agustini Tutuk Djoko Kusworo Uray Irzandi Uray Irzandi Utama, Bobby Indra Vicky Ramadhani, Vicky widodo, anton sri Winaningsih, Ima Wira Pinem Yanuar Rifianto YS Darmanto Yudhy Dharmawan Yuliani, Kristina Wulan Yulita Arni Priastiwi Yuliyandjaja, John Philia Yusi Luluk, Rahmania