Claim Missing Document
Check
Articles

Preparation of CaTiO3 Asymmetric Membranes Using Polyetherimide as Binder Polymer Endang Purwanti Setyaningsih; Maya Machfudzoh; Wahyu Prasetyo Utomo; Hamzah Fansuri
Indonesian Journal of Chemistry Vol 16, No 1 (2016)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (288.743 KB) | DOI: 10.22146/ijc.21172

Abstract

Asymmetric dense and thin membranes have been prepared from powders of perovskite oxide-type CaTiO3 without cracking by phase inversion method. Polyetherimide was used as a polymeric binder in the method. The resulting green membranes, composed of CaTiO3 powder and polyetherimide binder, were sintered at 890, 1100 or 1200 °C. The crystal phase of CaTiO3 was analyzed using X-Ray Diffraction (XRD). The XRD pattern of the synthesized CaTiO3 powder was matched with the reference indicating the formation of CaTiO3 structure. Sintering at 890 °C fails to form a strong membrane. Scanning Electron Microscope (SEM) images of the membranes showed that the membrane had the asymmetric structure with dense layer on one side and porous layer on the other side. The pores in the porous layer were both finger-like and sponge-like structure. The mechanical strength of the membranes, which were determined by Vickers micro hardness method, varied from 3.5 to 25.8 Hv. The strongest membrane without any crack was resulted from sintering at 1200°C with hardness values between 19.4 and 25.8 Hv. Thermal expansion coefficients of the asymmetric membranes sintered at 1100 and 1200 °C, measured with Thermomechanical Analyzer (TMA), were 10.82 × 10-6 and 12.78 × 10-6.C-1 respectively.
SYNTHESIS AND MAGNETIC PROPERTIES OF BINUCLEAR COMPLEX [N(n-C4H9)4][MnIIFeIII(ox)3] Fahimah Martak; Hamzah Fansuri; Sekarayu Dianing Putri
Indonesian Journal of Chemistry Vol 12, No 1 (2012)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (423.294 KB) | DOI: 10.22146/ijc.21377

Abstract

Binuclear complex, [N(n-C4H9)4][MnIIFeIII(ox)3] (ox=oxalate), has been synthesized and characterized. Binuclear complex with formula of [N(n-C4H9)4][MnIIFeIII(ox)3] was synthesized by forming precursor K3[Fe(ox)3] which was followed by adding manganese chloride and tetrabutyl ammonium chloride. Characterization of the complex was made by microanalysis, FT-IR spectroscopy, x-ray diffraction and Magnetic Susceptibility Balance. Magnetic moment of binuclear complex [N(n-C4H9)4][MnIIFeIII(ox)3] is 7.81 BM. The compound has higher magnetic moment than the previously reported compound with different organic cation, [N(n-C5H11)4][MnIIFeIII(ox)3]. This behavior might be associated with the decreasing range among layers on polymeric network.
CRYSTALLINE PHASE REACTIVITY IN THE SYNTHESIS OF FLY ASH-BASED GEOPOLYMER Lukman Atmaja; Hamzah Fansuri; Anggaria Maharani
Indonesian Journal of Chemistry Vol 11, No 1 (2011)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (710.099 KB) | DOI: 10.22146/ijc.21426

Abstract

Aluminosilicate, alkaline solution and fly ash from a power plant have been used to synthesize geopolymer at ambient temperature. SiO2/Al2O3 mole ratio of the starting materials was varied by the addition of pure, insoluble corundum and quartz. The geopolymer exhibited some differences in the ratio of initial reaction mixtures and that of final products. The corundum gave no influence to the compressive strength while the quartz at SiO2/Al2O3=4.0-6.0 produced significant change in the strength. The highest compressive strength achieved was 65 MPa. XRD using analysis Rietveld method proved that quartz has been found both in starting materials as well as in the geopolymer indicating the involvement of crystalline phases, to some extent, in geopolymerization process.
THE EFFECT OF PHOSPHORUS ADDITION ON THE ACTIVITY OF BISMUTH MOLYBDATE CATALYST FOR PARTIAL OXIDATION OF PROPYLENE TO ACROLEIN Hamzah Fansuri; Gia Hung Pham; Sandra Wibawanta; Dong-ke Zhang
Indonesian Journal of Chemistry Vol 10, No 3 (2010)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (187.41 KB) | DOI: 10.22146/ijc.21445

Abstract

In order to examine the effect of phosphorus addition on the activity and selectivity of bismuth molybdate catalysts for partial oxidation of propylene to acrolein, three modes of phosphorus addition were performed. The three modes of Preparation were performed by (1) adding phosphorus into a-Bi2Mo3O12 to obtain Bi2PxMo3Oy, (2) inserting phosphorus on bismuth sites to obtain Bi2-xPxMo3Oy, and (3) inserting phosphorus on molybdenum sites to obtain Bi2PxMo3-xOy. Four major phases of bismuth phosphomolybdate were detected as the result of the phosphorus addition, namely a-Bi2Mo3O12, Bi9PMo12O52, MoO3, and BiPO4. Experimental results showed that the catalysts solely containing BiPO4 and/or MoO3 have very low activities for partial oxidation of propylene to acrolein. Meanwhile, catalysts containing a-Bi2Mo3O12 and Bi9PMo12O52, together with either MoO3 or BiPO4 showed on average the same activities as a-Bi2Mo3O12 and one of them (combination of a-Bi2Mo3O12, Bi9PMo12O52 and MoO3) has better performance than a-Bi2Mo3O12 at lower temperatures. The presence of the oxygen donor phase, i.e. BiPO4 and MoO3, are believed to play a key role for the high activities of bismuth-phosphomolybdate catalysts. However, at higher temperatures, the presence of oxygen donor reduces the catalyst selectivity to acrolein.
CATALYTIC PERFORMANCES OF Fe2O3/TS-1 CATALYST IN PHENOL HYDROXYLATION REACTION Didik Prasetyoko; Cholifah Endah Royani; Hamzah Fansuri; Zainab Ramli; Hadi Nur
Indonesian Journal of Chemistry Vol 10, No 2 (2010)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (392.369 KB) | DOI: 10.22146/ijc.21452

Abstract

Hydroxylation reaction of phenol into diphenol, such as hydroquinone and catechol, has a great role in many industrial applications. Phenol hydroxylation reaction can be carried out using Titanium Silicalite-1 (TS-1) as catalyst and H2O2 as an oxidant. TS-1 catalyst shows high activity and selectivity for phenol hydroxylation reaction. However, its hydrophobic sites lead to slow H2O2 adsorption toward the active site of TS-1. Consequently, the reaction rate of phenol hydroxylation reaction is tends to be low. Addition of metal oxide Fe2O3 enhanced hydrophilicity of TS-1 catalyst. Liquid phase catalytic phenol hydroxylation using hydrogen peroxide as oxidant was carried out over iron (III) oxide-modified TS-1 catalyst (Fe2O3/TS-1), that were prepared by impregnation method using iron (III) nitrate as precursor and characterized by X-ray diffraction, infrared spectroscopy, nitrogen adsorption, pyridine adsorption, and hydrophilicity techniques. Catalysts 1Fe2O3/TS-1 showed maximum catalytic activity of hydroquinone product. In this research, the increase of hydroquinone formation rate is due to the higher hydrophilicity of Fe2O3/TS-1 catalysts compare to the parent catalyst, TS-1.
PENERAPAN MEMBRAN REVERSE-OSMOSIS DI LINGKUNGAN PANTI ASUHAN YATIM AISYIYAH BALONGBENDO UNTUK MEMENUHI KEBUTUHAN AIR MINUM Nurul Widiastuti; Triyanda Gunawan; Hamzah Fansuri; Syafsir Akhlus; Yuly Kusumawati; Harmami
Jurnal Pengabdian Kepada Masyarakat ITK (PIKAT) Vol. 2 No. 2 (2021): PIKAT : Jurnal Pengabdian Kepada Masyarakat
Publisher : LPPM Institut Teknologi Kalimantan

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (665.456 KB) | DOI: 10.35718/pikat.v2i2.616

Abstract

Pada program pengabdian masyarakat berbasis produk yang dilakukan Tim Abdimas Institut Teknologi Sepuluh Nopember (ITS) dihasilkan alat produksi air minum menggunakan perpaduan teknologi membran Reverse-Osmosis (RO), adsorben dan sinar UV yang sesuai dengan baku mutu air dari air sumur di Panti Asuhan Yatim Aisyiyah (PAY Aisyiyah). Kegiatan ini meliputi desain penyaring air yang menghasilkan standar air minum, rancangan bisnis air minum, kemasan produk air minum dan perawatan alat penyaring air. Uji mutu air minum yang dihasilkan dari sumber air sumur di PAY Aisyiyah dilakukan di labaratorium sesuai dengan standar baku mutu air. Berdasarkan hasil analisa dari air sesudah diolah telah memenuhi beberapa parameter sesuai Permenkes No. 492/MENKES/PER/IV/2010. Selain itu, air minum yang dihasilkan masih terdapat kandungan mineral yang dibutuhkan tubuh meliputi Fe, Mn, Zn, Cl, dan F. Sosialisasi telah dilakukan untuk memberikan pengetahuan mengenai pengolahan air minum dan perawatan alat yang benar, serta akan dilakukan pengawasan dan evaluasi secara berkala agar alat penjernih air dapat digunakan secara berkelanjutan guna memenuhi kebutuhan air bersih dan air minum lingkungan PAY Aisyiyah dan prospek kedepan untuk bisnis air minum di PAY Aisyiyah.
Pelatihan ISO 9001 Sebagai Upaya Peningkatan Mutu di SD Mambadiul Ulum, Gebang Putih, Surabaya Hamdan Dwi Rizqi; Adi Setyo Purnomo; Herdayanto Sulistyo Putro; Refdinal Nawfa; Hamzah Fansuri; Nurul Widiastuti
Sewagati Vol 4 No 2 (2020)
Publisher : Pusat Publikasi ITS

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (660.026 KB)

Abstract

Pendidikan merupakan salah satu sektor yang berperan besar dalam peningkatan Sumber Daya Manusia (SDM) dan pembanguanan susatu bangsa. Permasalahan yang dihadapi Indonesia dalam hal pendidikan yaitu masih rendahnya mutu pendidikan di setiap jenjang serta tidak meratanya sumber daya pendidikan sehingga perkembangan mutu pendidikannya tidak merata. Gebang Putih merupakan salah satu kelurahan di wilayah Kecamatan Sukolilo, Kota Surabaya, Provinsi Jawa Timur. Secara letak, Kelurahan Gebang Putih terbilang cukup strategis, hal tersebut dikarenakan lokasinya yang dekat dengan salah satu perumahan elite di Surabaya. Selain itu, Kelurahan Gebang Putih juga berada di kawasan Perguruan Tinggi Negeri dan Swasta. Namun, berdasarkan Data Pokok Pendidikan Dasar dan Menengah Direktorat Jendral Pendidikan Dasar dan Mengah Kementerian Pendidikan dan Kebudayaan, di wilayah Kelurahan Gebang Putih ternyata masih terdapat sekolah yang akreditasinya belum maksimal dan masih belum menerapkan sistem manajemen mutu, salah satunya adalah SD Mabadiul Ulum, Gebang Putih Surabaya. SD yang berdiri sejak tanggal 1 Mei 1954 tersebut hingga saat ini masih terakreditasi B. Tim Pengabdi ITS berupaya untuk turut berpartisipasi dalam mengembangkan pendidikan di wilayah Kelurahan Gebang Putih dengan meningkatkan kesadaran pengelola sekolah terhadap pentingnya sistem manajemen mutu di sekolah serta memberikan pelatihan dan pendampingan terkait penerapan ISO 9001 guna meningkatkan kualitas pendidikan di wilayah kelurahan Gebang Putih, Sukolilo, Surabaya. Kegaiatan pengabdian ini dilekukan dalam empat tahapan utama yaitu pendekatan awal, pelatihan dan workshop implementasi ISO 9001, pembimbingan dan pendampingsan serta tahap yang terakhir adalah evaluasi. Melalui kegiatan pengabdian masyarakat ini diharapkan dapat membantu peningkatan mutu sekolah melalui implementasi ISO 9001.
CHARACTERISTICS OF STYROFOAM WASTE-BASED MEMBRANE THROUGH VAPOR AND LIQUID-INDUCED PHASE INVERSION PROCESS Silvana Dwi Nurherdiana; Bambang Wahyudi; Merry Jhoe Stefanny; Anita Karlina; Rachmad Ramadhan Yogaswara; Mohd Jumain Jalil; Hamzah Fansuri
Jurnal Kimia Riset Vol. 8 No. 1 (2023): June
Publisher : Universitas Airlangga, Campus C Mulyorejo, Surabaya, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20473/jkr.v8i1.42957

Abstract

Polymeric membrane-based-Styrofoam waste in the form of a thin sheet was successfully prepared by a phase-inversion technique in different final solidification treatments, namely, immersion and evaporation. This study aims to identify the effects of different solidification processes on membrane properties such as hydrophobicity, pore configuration, porosity, and membrane temperature stability. Characterization was carried out using contact angle, SEM, FTIR, TGA, and porosity tests. The results showed that an increase in Styrofoam 18-30 wt.% in dimethylformamide (DMF) as solvent decreases the hydrophobicity by 9.5%. The average contact angle of 62–80° indicated that the obtained membrane was prepared by immersion treatment. The membrane subjected to evaporation treatment was hydrophobic. Moreover, the microscopy image shows that the immersed membrane was denser than the evaporated membrane. This showed that a higher exchange rate between the solvent and non-solvent (water) produced a tight membrane than free evaporation in air. The polystyrene membrane from Styrofoam exhibited excellent temperature stability up to 350 °C. In addition, the mechanical strength was affected by employing different solidification processes. The obtained results were also successfully tabulated from a statistical point of view to validate the conclusions. The following information can provide basic knowledge for modifying membrane-based-Styrofoam to optimize zero-waste goals.
PREPARATION, CHARACTERIZATION AND CATALYTIC ACTIVITY OF CuO/TS-1 ON BENZENE HYDROXYLATION REACTION Ediati, Ratna; Fansuri, Hamzah; Prasetyoko, Didik
Makara Journal of Science Vol. 15, No. 2
Publisher : UI Scholars Hub

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

CuO/TS-1 catalysts have been prepared and tested in the benzene hydroxylation. TS-1 was synthesized by hydrothermal method, while CuO/TS-1 was prepared by impregnation method using Cu(NO)2.3H2O as precursor. Catalysts were characterized by using X-ray diffraction (XRD), infrared spectroscopy (IR), and N2 adsorption-desorption techniques. The catalytic activity was tested in the hydroxylation reaction of benzene. The products were analyzed using gas chromatography. Catalyst characterization by XRD and IR techniques have showed that the catalyst structure was a MFI type of zeolite. XRD pattern have showed the orthorombic structure and indicated the presence of CuO aggregation. The results of the pyridine adsorption have found that the acidity of TS-1 and CuO/TS-1 were a Lewis acid and it’s increased with an increasing amount of CuO loading. The results of nitrogen adsorption analysis have showed decreasing of surface areas of catalyst with increasing amount of CuO loading. The optimum conditions of benzene hydroxylation was observed by 1%CuO/TS-1 catalyst at 70 °C, reaction time 2 h and acetic acid as the solvent yielded 27.6% of phenol with phenol selectivity was 75.5%
Sintesis Nanoemulsi Ekstrak Cabe Jawa (Piper retrofractum Vahl): Kajian Rasio VCO:Tween 80 dan Lama Homogenisasi Rahman, Askur; Mojiono, Mojiono; Fansuri, Hamzah; Puspita, Diah Ayu
Jurnal Ilmiah Rekayasa Pertanian dan Biosistem Vol 12 No 2 (2024): Jurnal Ilmiah Rekayasa Pertanian dan Biosistem
Publisher : Fakultas Teknologi Pangan & Agroindustri (Fatepa) Universitas Mataram dan Perhimpunan Teknik Pertanian (PERTETA)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29303/jrpb.v12i2.673

Abstract

Piperine obtained from Javanese long pepper extract is an essential compound, but it has the disadvantage of being insoluble in water, so its bioavailability is low. One of the efforts that can be made to overcome this is by changing the size to nano, such as making nanoemulsion preparations. The study aims to determine the effect of VCO:Tween 80 ratio and homogenization time on nanoemulsion characteristics of Javanese long pepper extract. The research method utilized a completely randomized design by treating VCO:Tween 80 ratio and homogenization time. The research parameters included an organoleptic, percent transmittance, pH, viscosity, piperine content, particle size, polydispersity index, and zeta potential. This research resulted in a percent transmittance value of 97.05-99.55%, pH 4.89-5.56, viscosity 0.35-0.76 cP, piperine content 6.29-12.25%, particle size 41.482 nm and 266.62 nm, polydispersity index 0.7446 and 0.4358, zeta potential -4.443 mV, and -2.166 mV. The study is expected to be a reference in utilizing piperine content to benefit spices and medicines.
Co-Authors Abdul Munip Abdullah, Romario Achmad Otong Busthomi Adi Setyo Purnomo Afif Muamar Agung Muliawan Ahmad Rofii Ahyudia Malisa Ilham Aisah Aisah Al Mustaqim, Dede Amirul Mukminin Andriyani, Yani Anggaria Maharani Anita Karlina Arief Adhiksana Arief Firmansyah Arif Rahman Saleh Arvan Rahmanda Askur Rahman Astira, Dinia Aulia Indri Cahya Azaki Khoirudin Bahomaid, Saleh Abdoalgaader Ali Bambang Sudarmanta Bambang Sudarmanta, Bambang Bambang Wahyudi Cholifah Endah Royani Dahlan, Rahman Dani Hanif Rianto Dety Oktavia Sulistiono Devi, Serlina Oktavia Diah Kartika Sari Dian Farida Asfan Didik Prasetyoko Dinansyah Aditya Djoko Hartanto Djoko Hartanto Dong-ke Zhang Edy Setyawan Endang Purwanti Endang Purwanti Setyaningsih Enung Siti Nurhidayah Erliyanti, Nove Kartika Fadlan, Arif Fahimah Martak Faisal Farhanah Thalib Faridz Ravsamjani Fauziah, Difari Afreyna Gia Hung Pham Gunawan, Triyanda Gunawan, Triyanda Hadi Nur Hadi Nur Hafiz Dzarfan Othman, Mohd Hamdan Dwi Rizqi Harmami Harmami Hendiyani, Mesy Faridah Herdayanto Sulistyo Putro Hidayati, Ririn Eva Icha Sugiasari Imam Machali Iqbal, Rendy Muhamad Karim Budiono Kemala, Yusnadia Khalid, Khalisah Khoirul Hidayat Kusumawati, Yuly Lestari, Witri Wahyu Lia Harmelia Lia Rachmawati Lisdayana, Nurmalisa Lukman Atmaja Maria Ulfa Mariaty Ibrahim Maya Machfudzoh Merry Jhoe Stefanny Mohd Hafiz Dzarfan Othman Mohd Jumain Jalil Mojiono, M. Mojiono, Mojiono Muhamat Abdul Rohim Muhammad Amir Rudin Yusup Muhammad Arif Ramadhan Muhammad Rickyu Yudhistira Mukti, Rino Rakhmata Mutasim Billah Mu’tamar, M Fuad Fauzul Naimatul Khoiroh Naimatul Khoiroh Nandini , Atika Nandini, Atika Nasruddin Nasruddin Neneng Ayunanda Novia Dwi Permata Nugraha, Reva Edra Nugraheni, Zjahra Vianita Nugroho, Roshid Adi Nuni Widiarti Nur Ali Nurul - Widiastuti Nurul Widiastuti Oktavina Kartika Putri Perry Burhan, Perry Pratama, Jeesica Hermayanti Probowati, Banun Diyah Puspita, Diah Ayu Puspitasari, Melani Puji R. A. Syukuri Nikmah R. A. Syukuri Nikmah, R. A. R.Y. Perry Burhan, R.Y. Perry Rachmad Ramadhan Yogaswara Rachmad Ramadhan Yogaswara Rafli Azhari Ahmad Faisal Rahmad Widyanto, Alvin Rahmawati, Zeni Rakhmawati Rakhmawati Ratna Ediati Ratna Ediati Refdinal Nawfa Ridho Bayuaji Rieswana, Yuried Diilan S. Sugiharto S. Supriyanto Safira Habiba Nuhaa Sandra Wibawanta Sekarayu Dianing Putri Sigit Mujiarto Silvana Dwi Nurherdiana Silvana Dwi Nurherdiana Sintha Soraya Santi Stephen Maruli Tua Gultom Subaer - Suharbiansah, Rujito S. R. Supriadi, Warih Suri, Nabilah Atika Syafsir Akhlus Teguh Endah Saraswati Totok Trengginas Tri Ana Mulyati Tri Eddy Susanto Tri Esti Purbaningtias Vivi Zulaicha Wahyu Prasetyo Utomo Wasman Wasman, Wasman Wiwik Fitria Ningsih Yani Dahliani Yogaswara, Rachmad Ramadhan Zainab Ramli Zainab Ramli Zainab Ramli Zetra, Yulfi Zulfiani, Utari