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Pengaruh Diameter Dan Panjang Serat Pelepah Sawit Terhadap Sifat Dan Morfologi Wood Plastic Composit (WPC) Siti Sakinah; Bahruddin Bahruddin; Zultiniar Zultiniar
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 3, No 2 (2016): Wisuda Oktober Tahun 2016
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Abstract

The length and diameter of the fibers of palm frond is one of the factors that affect the physical and mechanical properties of the material WPC. This study aims to determine the effect of fiber diameter and length of the palm fronds to the properties and morphology of wood plastic composite (WPC). WPC samples prepared by the method of melt blending the fibers of palm fronds, PP, Maleated polypropylene (MAPP), and paraffin for 65 minutes at a temperature of 170 ° C and a rotor speed of 80 rpm using the Internal Mixer. The length and diameter of the fibers of palm fronds used is ± 1 mm, 1 cm and 5 cm in diameter filler: - 40 ~ + 60 mesh, - 60 ~ + 80 mesh and - 80 ~ + 100 mesh. While the ratio of the weight ratio of PP / fiber palm fronds are 50/50 and 70/30. The test results showed that the best mechanical properties resulting in a length of 1 mm and the diameter of the fiber - 80 ~ + 100 mesh at a ratio of polypropylene / palm frond fibers 70/30 with a value of 16.44 MPa tensile strength and flexural strength 31.21 MPa. In testing the physical properties of the best value generated with the water content value of 8,61%, the absorption value of 1.78%, the highest density value of 0.99 g /cm3 and thickness swelling lowest value of 0.33%, while in the SEM testing, interaction between filler and matrix are still lacking thus forming agglomeration as a result of the fiber and the matrix material evenly mixed at WPC.Keywords: fiber diameter, fiber length, physical, mechanical, morphological, wood plastic composite
Modifikasi Pati Sagu Dengan Metode Asetilasi Untuk Peningkatan Sifat Tensile Bioplastik Yoga Deswan Suwary; Yelmida Yelmida; Bahruddin Bahruddin
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 5 (2018): Edisi 2 Juli s/d Desember 2018
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Abstract

Bioplastics are an alternative material to replace conventional plastic packaging so as not to pollute the environment. One method of modifying bioplastics is the acetylation method which is a modified starch method obtained from reacting starch with hydroxyl groups to produce hemiacetal and aldehyde. This study aims to make modified bioplastics with better tensile strength than ordinary bioplastics. The analysis performed was FTIR test, substitution degree test, and mechanical properties of tensile strength. The best results from each test are the value obtained by the value of the substitution degree 0,992, FTIR at the vibration for the wavelength range 1633 - 1645 cm-1, the tensile strength value of 1,893 MPa bioplastically penetrated the decay results of the methylated starch and 12 % filler content b / b and 10 % plasticizers b / b.Keywords : acetylation, bioplastic, acetylated starch, acetylated bioplastic
Pengaruh Pretreatment Batang Sawit Terhadap Sifat Dan Morfologi Wood Plastic Composite (WPC) Muchlis Ade Putra; Ahmad Fadli; Bahruddin Bahruddin
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 2, No 1 (2015): Wisuda Februari Tahun 2015
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Abstract

Palm trunk wood is one of solid waste from palm plantations that have not been utilized optimally. This waste can be developed as materials for Wood Plastic Composite (WPC). Extractive substances and hemicellulose fraction of this material may inhibit mixing process between wood filler and matrix, so it takes a pretreatment to eliminate these fraction. Effect of pretreatment on the properties and morphology of the resulting WPC studied in this research. Pretreatment was performed in an autoclave using water and solution of oxalic acid (OA) with concentration 0,05 M and 0,1 M at soaking temperature 1000C and 1400C then held for 5 and 15 minutes. Mixing the filler and matrix with the ratio 30/70, 2% mass paraffin and 5% mass of Maleic Anhydrate Polypropylene (MAPP) was conducted on Internal Mixer Labo Plastomills with temperature and rotor speed conditions 170 0C and 80 rpm respectively. Results of the lignocellulose analysis showed that highest reduction of extractive substances and hemicellulose fraction was 95,94 % and 25,22 %. The best mechanical and physical properties found in the pretreated sample with conditions 0,05 M OA concentration, 140 0C soaking temperature, and 15 minutes soaking time. The tensile strength, flexural strength, and water absorption values was 273,244 kgf/cm2, 427,551 kgf/cm2 and 1,120 %, respectively.Keywords : filler, lignocelluloce, pretreatment, wood plastic composite
Pengaruh Pencucian Membran Ultrafiltrasi Menggunakan Surfactan Dan NaOH Pada Proses Penyaringan Air Terproduksi Sonny Wijaya; Syarfi Daud; Bahruddin Bahruddin
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 2, No 2 (2015): Wisuda Oktober Tahun 2015
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One of water treatment technology that can be used for treat produced water is membrane technology. The most of challenging in membrane technology is fouling. The objective of this research are to study influence of ultrafiltration membrane washing to flux recovery and removal resistance by using surfactant and NaOH for treat produced water. Membrane that to be used on this research is membrane ultrafiltration with pore size between 0.1500 until 0.0014 micron and using capillary module configuration. The method that to be used is current-cross flow for filtration proses with filtration time 180 minutes with pressure in 0.2 bar, 0.4 bar, 0.6 bar and concentration of cleaning agent surfactant and NaOH in 1.5%, 2.0% and 2.5% by using counter-cross flow with pressure 0.8 bar and time for washing in 30 minutes. The highest washing effectiveness rate of 69.53% obtained by using surfactant 2.5% and filtration pressure 0.6 bar, the highest leaching efficiency based on flux recovery value is 99.32% and 99.65% for removal resistance obtained by using surfactant 2.5% and filtration pressure 0.2 bar.  Key words: flux recovery, fouling, produced water, removal resistance, surfactant, ultrafiltration membrane
Sifat Dan Morfologi Bioplastik Berbasis Pati Sagu Dengan Penambahan Filler Clay Dan Plasticizer Gliserol Anugerah Rifaldi; Irdoni Hs; Bahruddin Bahruddin
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 4, No 1 (2017): Wisuda Februari Tahun 2017
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Bioplastic is one of alternative to relpace comercial plastic that can be harmful to environment. Bioplastic is made to make degradation become easier. One of potential raw material is sago because it has a highest starch component. The aims of this research are the study of impact clay as filler and glycerol as plasticizer to mechanical properties (tensile strenght, elongation, modulus young), hidrophobicity (water uptake), biodegradation and morphology. The synthesis method is solution intercalation of starch, water, filler and plasticizer with variation of filler are 3 (%w/w), 6 (%w/w), 9 (%w/w), 12 (%w/w) and glycerol are 10 (%w/w), 14 (%w/w), 18 (%w/w), 22 (%w/w). The analysis show that filler clay and glycerol give an impact to mechanical properties of bioplastic. the best mechanical properties is on bioplastic with composition 3 % filler and 14 % glycerol with tensile strenght 2.891 Mpa, % elongation 30.99 %, modulus young 9.39 Mpa. The highest hidrophobicity of bioplastic is 85.71% and residual persentation is between 67.39 % to 81.25 % in 8 day. Micrograf analysis shows that filler distribution is not be spread evenly on sago starch matrices.Keywords : bioplastic, clay, filler, glycerol, plasticizer, sago strach
Aplikasi Katalis α-MnO2-400 Yang Dikalsinasi Pada Temperatur 400oc Untuk Degradasi Kandungan Organik Limbah Cair Industri Pulp Dan Kertas Peji Nopeles; Edy Saputra; Bahruddin Bahruddin
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 7 (2020): Edisi 2 Juli s/d Desember 2020
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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The pulp and paper industry is a water-intensive industry, and number third in the world and also a significant contributor to pollutant discharge to the environment. It is know that the low COD/BOD ratio obtained from pulp industry wastewater is an average of 0.3 while the ideal of biodegradability value is in the range above 0.5. Thus, there are alternative treatments that can degrade hazardous compounds in wastewater that are slow to degrade through the oxidation process, known as the Advanced Oxidation Process (AOP). AOP is based on active radicals which are produced as oxidizing agents to mineralize the complex chemical substance in the wastewater. One of the active radicals, known sulfate radicals (SO4*), has a high oxidation potential of 2.5 – 3.1 V. Several studies showed that radical sulfates can be produced by catalytic oxodation process, such as combination of Peroxymonosulfate with homogeneous metal ion catalyst (Fe2+, Mn2+, Ni 2+, Co2+, Cd2+, Cu2+, Ag+1, Cr3+, Zn2+). In this study, AOP method peroxymonosulfate which was activated with the catalyst α-MnO2-400 were used to treat organic content in wastewater of pulp and paper industry. The α-MnO2-400 catalyst was produced from 1:3 molar potassium permanganate (KMnO4) and maleic acid that calcined at 400oC. This catalyst was characterized by XRD, BET and FESEM. From XRD analysis obtained the peak aligned with JCPDS Standard. From the BET analysis obtained surface area is 49.17 m2/g, pore size 6.4 nm and pore total 0,16 cm3/g. From FESEM analysis obtained crystalit structured with average length 21 nm. The best degradation of COD and TOC concentration obtained at temperature 45oC, at retention time 240 minutes, with peroxymonosulfate concentration 2,0 g/L and catalyst concentration 0,4 g/L (73% and 77%). Key word: AOP, Catalyst, COD, Peroxymonosulfate, Waste water
Polimerisasi Ester Dari Asam Lemak Sawit Distilat (ALSD) Menggunakan Inisiator benzoil Peroksida 0,3 % Herry Novriansyah; Ahmad Fadli; Bahruddin Bahruddin
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 2, No 2 (2015): Wisuda Oktober Tahun 2015
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Palm Fatty Acid distillate (PFAD) as a byproduct the processing of palm oil has great potential to be used as raw material oil-based polymers. The aims of this research to study the process polymerization of ester from PFAD using initiator (benzoyl peroxide) 0.3%. Stage of the process consists of three stages. The esterification stage was done at temperatur70° C, reaction time of 120 minutes, reactant ratio 1: 8 (PFAD: methanol), concentration of catalyst (H2SO4) 1% (w/w) PFAD; polymerization stage was done at temperature 120, 130,and 140°C, concentration of initiator (benzoyl peroxide) 0.3% (w/w) and variation of polymerization reaction time 3, 4, and 5 hours, and polyesterification stage was done at temperature 175-200 °C, ratio of reactants 1: 1 (polymerized methyl ester: ethylene glycol), and the reaction time of 4 hours. The results of polymerization was analyzed by using viscosity test, FT-IR (Fourier Transform Infra Red) and GCMS (Gas Chromatography Mass Spectrometry). The highest viscosity was 32,97 mPa.s at temperature 140°C and 4 hours. Theresult using FT-IR showed that the polymerization process was unsuccessful, this was indicated by the presence of the vinyl group. The result of GCMS showed there had been molecular weight addition in polymerization process, that was only three times the initial molecular weight.Keywords: benzoyl peroxide, esterification, palm fatty acid distillate, polymerization
Pengaruh Nisbah Dan Suhu Pencampuran Selulosa Dan Pati Terhadap Sifat Dan Morfologi Bioplastik Berbahan Dasar Pati Umbi Talas Wira Bima Stevent Sembiring; Irdoni HS; Bahruddin Bahruddin
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 4, No 2 (2017): Wisuda Oktober Tahun 2017
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Abstract

The use of plastic in large quantities impact on environment pollution as the effect of the plastic cesspool accumulation which cannot be decomposed naturally (non-biodegradable). Research bioplastics (biodegradable plastic) based starch done to find alternative to reduce the consumption of conventional plastics. But, the starch has a weakness on mechanical properties. The purpose of this study was to knowing the characteristics of taro starch and cellulose from banana stems, knowing the effect of water ratio, temperature and composition of the cellulose filler on mechanical properties and morphology of the bioplastics products. Manufacture of bioplastics made by the casting method, ie mixing taro tuber starch, glycerol, and cellulose. Bioplastics produced do some analysis, which includes the analysis of the chemical composition, tensile strength (tensile strenght), elongation (elongation at break), water uptake, biodegradation, SEM (Scanning Electron Microscopy) and analyzed using Response Surface Methodology (RSM). The most effected factor was significant to all the responds was the composition cellulose filler which followed by the temperature and water ratio. The best composition is bioplastic with filler cellulose 14,999%b/b, temperature 75,775oC and water rasio 20v/b which is tensile strenght was 6,906 MPa, elongation 10,906%, water uptake 28,491% and biodegradable 54,143%.Keyword : cellulose, glycerol, starch, tensile strength, and water uptake
Evaluasi Pressure Drop Pada Sumur Injeksi Uap Di Lapangan Duri Dengan Persamaan Beggs-Brill Dan Moody Ahmad Riadi S Hasibuan; Bahruddin Bahruddin; Ahmad Fadli
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 1, No 2 (2014): Wisuda Oktober Tahun 2014
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Steam injection is a heat transfer process to petroleum reservoir through multiphase flow of wet steam. Estimating pressure drop in multiphase flow is more difficult than for single-phase flow. Multiphase flow is a complex phenomenon because of the interdependence of various variables that affecting pressure drop such as flow regime, hold up, flow geometry at horizontal, vertical or deviated, flow rate of each phase and the fluid properties of each phase. The purpose of this study is to find out the most appropriate model to calculate the pressure drop in steam injection wells and understand parameters that most affecting pressure drop. Research methodology for this study is descriptive analysis. Field data from 30 injection wells in Duri field are collected and compared with 2 variations of Beggs-Brill and Moody equation, which are the original model and the model with Palmer correction. Both models are translated into a simple computing program using Excel application. Calculation result from the model is compared with the measurement results to understand the deviation or error. As the result of this study, it is shown that Beggs-Brill and Moody model without Palmer correction is suitable for steam injection application. Average error is only 0,2% with a standard deviation of 3,32%. Further information is obtained from the sensitivity analysis that the accuracy of pressure drop calculation is affected by measurement accuracy of the steam flow rate, steam quality and steam temperature. Keyword: Beggs and Brill correlation, Moody diagram, Palmer correction, pressure drop, steam injection.
Pengaruh Nisbah Polypropylene / Serat Pelepah Sawit Dan Kadar Maleated Polypropylene (MAPP) Terhadap Sifat Dan Morfologi Wood Plastic Composites (WPC) Nurul Aini Thaibil Fadhly; Irdoni HS; Bahruddin Bahruddin
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 2, No 2 (2015): Wisuda Oktober Tahun 2015
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Abstract

One of the materials that can be used as a component in the manufacture of Wood Plastic Composite (WPC) is a palm frond fibers. Palm frond is one of the solid waste of oil palmplantations and abundant availability has not been utilized optimally. The purpose of this study was to determine the influence of the ratio of polypropylene (PP) / palm frond fibers and Maleated polypropylene compatibilizer levels of the properties and morphology of WPC. WPC samplesprepared by the method of melt blending between palm frond fibers, PP, Maleated polypropylene (MAPP), and paraffin for 15 minutes at a temperature of 170 ° C and a rotor speed of 80 rpm using Internal Mixer. The size of the palm frond fibers used is 1 cm. While the ratio of the weight of PP/palm frond fibers is 50/50, 60/40 and 70/30 and the addition of MAPP of 0%, 4% and 5%. Testing experiments were prepared to mechanical testing consist of tensile and flexural strength and physical testing consist of density, water absorption, and swelling thickness. Scanning Electron Microscopy was used as a morphology testing. The results showed that the best mechanical properties in a ratio of polypropylene / palm frond fibers (60/40), MAPP (5%), with the value of tensile strength 256.05 kgf/cm2 and flexural strength 598 kgf /cm2.The best physical properties of water absorption at a ratio (60/40) with MAPP (0%) is 0,97%, the density at a ratio (60/40) and MAPP (5%) is 1,07% and swelling thickness at a ratio (50/50) with MAPP (0%) is 0,17%.Keywords: maleated polypropylene, morphology, palm frond fibers, mechanical properties , wood plastic composite
Co-Authors ABD Aziz, ABD Abd.Rahim Ade Putra Adhy Prayitno Adrianto Ahmad Adrianto Ahmad Ady Maulana Afkari, Fahmi Afrila Afrila Ahmad Fadli Ahmad Riadi S Hasibuan Ahmad Zain Sarnoto Aidil Akbar Akhmad Hasan Saleh, Akhmad Hasan Alfian Malik Alfian Mukti Fajar Alumni STIKES Husada Borneo Amir Hamzah Ananda Putri Andi Ibrahim Andreas Sahat Parsaulian Andri Mulia Angelina Angelina Anugerah Rifaldi Aras Mulyadi Aris Aprianto Cahyono Arya Wiranata Arya Wiranata Bramansyah Riswanda David Andrio DESI PURNAMA SARI Dewi Maya Sari Dian Anggraini Purba Dian Eka Indriani, Dian Eka Donny Kurniawan Edi Saputra Eka Mawarni Eko Sumadi Endro Siswoko Eri Malindo Fachry Abda El Rahman Fajar Ladung Farikhatul Akhlis Fahruddin Yulianto Fariq Fahrun Nisa Fatwa, Abdul Halil Firdaus Septiawan Fitra Annisa Fitriani Fitriyani Syukri Gunawan Gunawan Hamsar Hamsar Handayani, K.H Sri Hasan, Haslinda Herlili Peronika Herry Novriansyah Ida Zahrina Idral Amri Idral Amri Idral Idral Iradhatullah Rahim Irdoni HS Irdoni Irdoni Irdoni Irdoni Irwan Idrus Isra, Muhammad Ivan Fadhillah Izatun Nufus Jabosar Ronggur Hamonangan Panjaitan Jasman Khairat KRISTINA WIJAYA Liendra Juniarti Lita Darmayanti Luci Octaria M. Adely Ihsan M. Aldi Muhtadibillah M. Iwan Fermi Mansida, Amrullah Maradona Maradona Mardatillah Mariatul Qiftiah Melda Helena S Melly Anggraeni Mentari Nur Arafah Mery Christina Meysara Meysara MK, Pratiwi Muchlis Ade Putra Mudinillah, Adam Muh. Zulkifli Muhamad Ilham Syabana Muhammad Faiz Fadhlurrohman Muhammad Nasri Katman Muhammad Nur Muhammad Rigan Yusri Muhammad, Muhammad Mutiara Wulandari Nirwana Nirwana Nur Arfiyah Febriyani Nurul Aini Thaibil Fadhly Peji Nopeles Pusakaningwati, Ayik Puskesmas Guntung Payung Rahma Amariaman Rahmat Rani Yuliantari Razita Hariani Rina Gunarti Rizky Sandy Harahap Robby Kumar Robby Kumar Roy Marthin Panjaitan Rozanna Sri Irianty RS Khusus Bedah Siaga Banjarmasin Septiana Veronika S Siti Sakinah Sofi Nur Meilina Sofyan Sonny Wijaya Sri Helianty Sri Rezeki Muria STIKES Husada Borneo Sudirman Sudirman Suherman, Suherman Sunardjo Surya Baskara Jaya Syamsia Syaparuddin Syarfi Daud Syelvia Putri Utami Syukri, Fitriyani Thamrin Thamrin Ummy Aisyah Rochaeni Viodita Rizki Wahyu Suci Rahmani Wenny Susanty Winda Ramadhani Wira Bima Stevent Sembiring Yanny Sartika Yelmida Azis Yoga Deswan Suwary Yoga Pratama Yusnila Halawa Zainal Abidin Zuchra Helwani Zuchra Helwani Zuchra Helwani, Zuchra Zulkifli Zultiniar Zultiniar