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Pengaruh Mastikasi Karet Terhadap Karakteristik Campuran Aspal - Karet Spesifikasi Teknis (Crumb Rubber) Arya Wiranata; M. Iwan Fermi; Bahruddin Bahruddin
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 5 (2018): Edisi 2 Juli s/d Desember 2018
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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The use of natural rubber in the form of solids such as crumb rubber (SIR 20) will require a long time when mixing with asphalt, therefore mastication process is used before mixing with asphalt. Mastication is process of grinding natural rubber in open mill to break the chain in natural rubber polymer. The aim of this study to determine the effect of rubber mastication and rubber storage time after mastication on modified asphalt characteristics. In mastication process, asphalt as plasticizer agents with levels of 0%, 1%, 2%, 3%, 4% and 5% w/w and rubber storage time after mastication are 0 days and 30 days. The asphalt used is 60/70 penetration type asphalt. Asphalt modified by mixing SIR 20 and asphalt with a ration of 1:9 at temperature of 165oC and stirring time for 30 minutes. Modified asphalt is tested for penetration test, softening point, marshall stability, and weight loss. The results of the study showed that the addition of plasticizers in rubber and rubber storage time after mastication affected the value of penetration, softening point, marshall stability, and weight loss. The best results were obtained at 0% plasticizer content and 0 days rubber storage time with a Penetration value of 58.5 dmm, Softening Point 59.1ºC, Marshall Stability 1710.9 kg, and Weight Loss 0%. The storage time of 30 days, the best results on a 5% plasticizer content with a Penetration value of 58.4 mm, Softening Point 56.3ºC, Marshall Stability 1463.3 kg, and Weight Loss 0.27%.Keywords : asphalt modification, plasticizer, mastication, SIR 20, penetration, softening point, marshall stability
Studi Polimerisasi Ester Dari Asam Lemak Sawit Distilat (ALSD) Menggunakan Inisiator Benzoil Peroksida 0,4 % Fitra Annisa; Zuchra Helwani; Bahruddin Bahruddin
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 2, No 2 (2015): Wisuda Oktober Tahun 2015
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Palm Fatty Acid Distillate (PFAD) is a byproduct from palm oil processing industry that used as raw material for synthesis polyester based vegetable oil. The purpose of the research is to study polymerization reaction of ester from PFAD using inisiator benzoyl peroxide 0,4%. There are three step reaction in this research that was esterification, polymerization, and polyesterification. The esterification stage was done at temperature 70oC, reaction time 2 hours, reactant ratio 1:8 (ALSD : metanol), and concentration catalyst H2SO4 1% (w/w) ALSD. Polymerization stage was done at variation of temperature 120, 130, and 140oC and variation reaction time 3, 4, and 5 hours using initiator benzoyl peroxide 0,4% (w/w) methyl ester. Polyesterification stage was done at temperature 175-200oC, reaction time 4 hours, and ratio reactant 1:1 (polymerized methyl ester : ethylene glikol). Product was analyzed by using FT-IR, GC-MS, and viscosity. The result of FT-IR showed that vinyl group was presence who indicated double bonding was presence and polymerization was not occur. The result of GC-MS showed there had no change of molecular weight. And product with temperature 130oC and reaction time 5 hours has higher viscosity value.Keyword : benzoyl peroxide, esterification, PFAD, polymerization
Pengaruh Kadar Asam Stearat,Mercaptodibenzothiazyldisulfide (MBTS) Dan Sulfur Terhadap Sifat Dan Morfologi Thermoset Rubber Dengan Filler Carbon Black-Abu Terbang Sawit Mery Christina; Bahruddin Bahruddin; Zuchra Helwani
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 1, No 2 (2014): Wisuda Oktober Tahun 2014
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Abstract

Crude palm oil wastes in the form of fly ash is potentially use as filler for thermoset rubber because it contains silica. This study aims to increase the mechanical and morphological properties of thermoset rubber which filled with mixture of carbon black and fly ash with particles size screened to 700-800nm. Stearic Acid, MBTS and sulfur contents were used 1; 2; 3 phr (per hundred rubber), 0.5; 1; 1.5 phr and 0.5; 1.5; 3 phr respectively. Rubber mastication process performed by a roll mill at room temperature and roll speed of 20 rpm until the texture is smooth and soft, then added minarex as a plasticizer, nanofiller, and other additives, such as ZnO as an activator, stearic acid as a co-activator, as antidegradant TMQ, MBTS as an accelerator and sulfur as a curative agent. Rubber mastication performed by a roll mill at room temperature and roll speed of 20 rpm. The overall duration of the manufacture of compound ±45 minutes. Vulcanization process using a hot press at a pressure of 200 kgf/cm2 and a temperature of 150 oC. Results showed that increased levels of stearic acid, MBTS and sulfur  is directly proportional to the tensile strength,  but yield elongation at break are varied. The best thermoset rubber in this study were obtained on samples having content of  stearic acid 3 phr, MBTS 1.5 phr and sulfur 3 phr with tensile strength values 19,05 MPa, 774.394 % elongation at break, hardness 52±5 shore A, abration 0,074 mm3/kg and 1,28% water absorption percentage. Keywords: carbon black, natural rubber, palm oil mill fly ash, vulcanizate
Pengaruh Nisbah Dan Suhu Pencampuran Terhadap Sifat Campuran Aspal – Crumb Rubber Desi Purnama Sari; Irdoni Irdoni; Bahruddin Bahruddin
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 5 (2018): Edisi 1 Januari s/d Juni 2018
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Modified asphalt is one of the alternative to method the road problems in Indonesia. This experiment aims to determine the effect of mixing ratio and temperature towards the property of asphalt - crumb rubber. This research method conducted by varied ratio 5%, 8% and 10% of melted crumb rubber. Then, mixsed with melt asphalt. The temperature variation of this process were at 150 oC and 170 oC for 60 minutes. The softening point, penetration, marshall stability and loss weight were tested from the modified asphalt. The results of this study indicated that the modified asphalt with crumb rubber has increased the value of softening point, penetration, stability marshall and decrease the loss weight. The best results was at 150 oC with 10% of crumb rubber, which has the softening point at 52 oC, penetration at 74.1 mm, marshal stability 1266.7 kg and loss weight 0.017%.Keywords : asphalt modified, crumb rubber, mixing ratio, penetration, stability marshall
Pengaruh Suhu Dan Tekanan Vulkanisasi Terhadap Morfologi Dan Sifat Karet Alam Vulkanisat (Thermoset Rubber) Dengan Filler Abu Sawit / Carbon Black Muhammad Isra; Irdoni Irdoni; Bahruddin Bahruddin
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 1, No 1 (2014): Wisuda Februari Tahun 2014
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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The production of natural rubber increase sufficient good in indonesia, while the natural rubber to be a product with a high valuable price still less developed than other countries. Therefore,we have to eforts it to employing this natural rubber be a product with a high valuable price from the raw material (natural rubber) to be vulcanized natural rubber using vulcanization process. The purpose of this study is to obtain the best conditions of the vulcanization process in the manufacture of vulcanized natural rubber with fly ash/carbon black filler, which is the variation of temperature 140, 150 and 160 °C and preasure of 50,100,150 and 200 kgf/cm2. The results vulcanized natural rubber of will be tested, it’s mecanical properties and morphology. Based on average yield mecanical properties and morphology tested is obtained that the operating conditions vulcanization process is temperature 150 °C and a pressure of 200 kgf/cm2.     Keyword : Natural rubber, Vulcanization, Vulcanized Natural Rubber.
Pengaruh Jenis Dan Suhu Pelarut Pada Preparasi Pelepah Sawit Sebagai Bahan Baku Wood Plastic Composite Dian Anggraini Purba; Zultiniar Zultiniar; Bahruddin Bahruddin
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 5 (2018): Edisi 1 Januari s/d Juni 2018
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Palm frond biomass is potentially to be used as a filler for plastic-wood composite products known as Wood Plastic Composite (WPC). This study aims to determine the influence of solvent type and temperature on preparation of palm frond as raw material of WPC. The palm frond which has been reduced to powder is dried in open air for ± 24 hours. Further drying uses an oven at 1050C where the final water content of the powder is 5%. Furthermore, the material is scaled down again in size to obtain 60 mesh. Palm oil powder is extracted for 15 minutes using solvent and high temperature. The solvent variations used are NaOH and H2O2 with concentration of 1 N while the variation temperature of extraction step is 100oC, 120oC and 140oC. The results showed that the type of solvent has a relatively significant effect on cellulose content of frond is increasing cellulose level of 13.44% - 22.23%, while the temperature changes did not give significant effect to the increase of fronds cellulose levels. The best preparation results were obtained in the preparation using NaOH solvent at 140 ° C with a cellulose content of 57,47%.Keywords: moisture content, palm frond, preparation, wood plastic composite
Pengaruh Plastisizer Minarex Terhadap Sifat Dan Morfologi Material Wood Plastic Composite Berbasis Batang Sawit Ady Maulana; Bahruddin Bahruddin; Ida Zahrina
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 1, No 1 (2014): Wisuda Februari Tahun 2014
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Oil palm stem is solid waste in oil palm plantation.Oil palm stem content high cellulose which not much in use with optimal. Oil palm stem have potential for filler in wood plastic composite (WPC). The aim of the research is to study the effect of content of oil palm stem particle (SBS) and content of minarex on the morphology and properties of WPC based on a mixture of oil palm stem particle (SBS) and polypropilene (PP). Ratio used of SBS/PP is 70/30, 60/40 and 50/50 with sizes of the SBS is 60-100 mesh. As plastisizer was use minarex-H with values of 0%, 2% and 10% mash. As compatibilizer was use maleated anhydrid polypropilene (MAPP) of 5% mass. WPC samples were prepared using Rheomix 3000 HAAKE mixer at temperature of 170oc. Rotor speed of 60 rpm and time of 20 minutes. Physical testing of WPC focused in water content, bulk density, water absorption and thickness swell and mechanical testing of WPC focused in tensile strength, flexural strength. Beside that morphology testing of WPC using scanning electron microscope (SEM). The result showed ratio of SBS/PP and high content of minarex in WPC will degradate of properties of WPC. The best mechanical properties of WPC are on SBS/PP mass of 50/50 for tensile strength, 61,57 kg/cm2 and SBS/PP mass of 60/40 for flexural strength, 2,68 kg/cm2. key Words : Maleated Anhydrid PolyPropylene, Morphology, plastisizer minarex, Polypropylene, Oil Palm Stem.
Pembuatan Bioplastik Berbasis Pati Sagu Dengan Modifikator Asam Sitrat Dan Filler Carboxymethyl Cellulose (CMC) Dewi Maya Sari; Syelvia Putri Utami; Bahruddin Bahruddin
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 6 (2019): Edisi 1 Januari s/d Juni 2019
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Bioplastic is one of the organic plastic that has been used as an eco-friendly food packagings whether has ability to degraded by nature. Sago starch has a potential to become raw material for bioplastics manufactured, and adding a carboxymethyl cellulose (CMC) aims to increase the tensile strength. The purposes of this research are determine the effect of sago starch, citric acid, CMC and glycerol of the characteristics bioplastics. Bioplastics product was characterized by few tests such as tensile strength (tensile strenght), elongation (elongation at break), and biodegradation. The analysis showed that filler CMC, plasticizer glycerol, and citric acid give an impact to mechanical properties of bioplastic. The best composition is bioplastic with (CMC 25% b/b, 25% b/b glycerol and 3% citric acid b/b) which is tensile strength of 8.23 MPa, elongation of 24,20%, and biodegradation 59,01%. Keyword: Bioplastic, filler, plasticizer, cross-linking agent, tensile strength
Preparasi Pelepah Sawit Dengan Asam Oksalat Dan Pengaruhnya Terhadap Sifat Dan Morfologi Wood Plastic Composite Andreas Sahat Parsaulian; Bahruddin Bahruddin; Zuchra Helwani
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 2, No 1 (2015): Wisuda Februari Tahun 2015
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Reduced forest makes the availability of woods as the construction material on the wane. Oil palm frond has a potential to use to decrease utilization of woods directly. The main objective of this study was to evaluate the effect of oxalic acid and thermal pretreatment to morphology and properties of oil palm frond based wood plastic composite (WPC). The temperature of pretreatment were varied at 100oC, 120oC, and 140oC with submersion time 15 minutes. The mass ratio of oil palm frond sized 100 – 200 mesh as filler and polypropylene as a matrix is 30:70. 2% paraffin as plasticizer and 5% maleic anhydride polypropylene as compatibilizer were use as an additive. WPC samples were prepared using internal mixer Labo Plastomill at temperature 180oC and rotor speed 80 rpm. Testing experiments were prepared to mechanical testing consist of tensile and flexural strength and physical testing consist of density, water absorption, and swelling thickness. Scanning Electron Microscopy was used as a morphology testing. The result showed that oxalic acid pretreatment significantly gives an effect to mechanical and physical properties. The best WPC in this study was treated in the 120oC using oxalic acid based on tensile strength with 23.785 MPa, flexural strength 43.2 MPa, density 0.975 gr/cm3, water absorption 1.44%, and swelling thickness 0.17%.Keywords: pretreatment, oil palm frond, wood plastic composite
Pengaruh Kadar Coupling Agent Maleated Natural Rubber Terhadap Morfologi Dan Sifat Karet Alam Thermoset Dengan Filler Abu Sawit/Carbon Black Andri Mulia; Bahruddin Bahruddin; Irdoni Irdoni
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 2, No 2 (2015): Wisuda Oktober Tahun 2015
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Maleated Natural Rubber (MNR) is a coupling agent which serves to facilitate mixing natural rubber and filler. This research aims to determine the effect of concentration MNR on the morphology and properties of thermoset rubber with fly ash/carbon black as filler. MNR content used were 2 phr 3 phr and 5 phr (per hundred rubber). Mastication process is carried out using a roll mill at room temperature, roll rotational speed of 20 rpm, and the overall time of the manufacture of compound ± 50 minutes. Constant variable is fly ash/carbon black, paraffin as plasticizer, ZnO as activator, stearic acid as co-activator, MBTS as accelerator, TMQ as anti-degradant, and sulfur as curative agent. The ratio of mass hybrid filler fly ash/carbon black used were 0/100; 30/70; 50/50; 70/30 and 100/0. Vulcanization process was carried out at a temperature of 150 °C and pressure of 50 kgf/cm2. Mechanical properties test includes tensile strength, elongation at break and elastic modulus using ISO 527-2 type 5A standard with a universal testing machine. Morphology test was carried out using a scanning electron microscope (SEM) and other parameter test was water absorption resistance. The result showed that coupling agent MNR affect the nature of thermoset and rubber. Best morphology image shows more evenly distributed filler, and interaction of filler and rubber formed quite homogeneous and uniform. The best mechanical properties obtained at 3 phr MNR with filler ratio of fly ash/carbon black 50/50 with a tensile strength of 18,147 MPa, elongation at break 1402.8 % and elastic modulus of 0.7688 MPa.Keywords : fillers hybrid , MNR, natural rubber, thermoset rubber.
Co-Authors ABD Aziz, ABD Abd.Rahim Ade Putra Adhy Prayitno Adrianto Ahmad Adrianto Ahmad Ady Maulana Afkari, Fahmi Afrila Afrila Ahmad Fadli Ahmad Riadi S Hasibuan Ahmad Zain Sarnoto Aidil Akbar Akhmad Hasan Saleh, Akhmad Hasan Alfian Malik Alfian Mukti Fajar Alumni STIKES Husada Borneo Amir Hamzah Ananda Putri Andi Ibrahim Andreas Sahat Parsaulian Andri Mulia Angelina Angelina Anugerah Rifaldi Aras Mulyadi Aris Aprianto Cahyono Arya Wiranata Arya Wiranata Bramansyah Riswanda David Andrio DESI PURNAMA SARI Dewi Maya Sari Dian Anggraini Purba Dian Eka Indriani, Dian Eka Donny Kurniawan Edi Saputra Eka Mawarni Eko Sumadi Endro Siswoko Eri Malindo Fachry Abda El Rahman Fajar Ladung Farikhatul Akhlis Fahruddin Yulianto Fariq Fahrun Nisa Fatwa, Abdul Halil Firdaus Septiawan Fitra Annisa Fitriani Fitriyani Syukri Gunawan Gunawan Hamsar Hamsar Handayani, K.H Sri Hasan, Haslinda Herlili Peronika Herry Novriansyah Ida Zahrina Idral Amri Idral Amri Idral Idral Iradhatullah Rahim Irdoni HS Irdoni Irdoni Irdoni Irdoni Irwan Idrus Isra, Muhammad Ivan Fadhillah Izatun Nufus Jabosar Ronggur Hamonangan Panjaitan Jasman Khairat KRISTINA WIJAYA Liendra Juniarti Lita Darmayanti Luci Octaria M. Adely Ihsan M. Aldi Muhtadibillah M. Iwan Fermi Mansida, Amrullah Maradona Maradona Mardatillah Mariatul Qiftiah Melda Helena S Melly Anggraeni Mentari Nur Arafah Mery Christina Meysara Meysara MK, Pratiwi Muchlis Ade Putra Mudinillah, Adam Muh. Zulkifli Muhamad Ilham Syabana Muhammad Faiz Fadhlurrohman Muhammad Nasri Katman Muhammad Nur Muhammad Rigan Yusri Muhammad, Muhammad Mutiara Wulandari Nirwana Nirwana Nur Arfiyah Febriyani Nurul Aini Thaibil Fadhly Peji Nopeles Pusakaningwati, Ayik Puskesmas Guntung Payung Rahma Amariaman Rahmat Rani Yuliantari Razita Hariani Rina Gunarti Rizky Sandy Harahap Robby Kumar Robby Kumar Roy Marthin Panjaitan Rozanna Sri Irianty RS Khusus Bedah Siaga Banjarmasin Septiana Veronika S Siti Sakinah Sofi Nur Meilina Sofyan Sonny Wijaya Sri Helianty Sri Rezeki Muria STIKES Husada Borneo Sudirman Sudirman Suherman, Suherman Sunardjo Surya Baskara Jaya Syamsia Syaparuddin Syarfi Daud Syelvia Putri Utami Syukri, Fitriyani Thamrin Thamrin Ummy Aisyah Rochaeni Viodita Rizki Wahyu Suci Rahmani Wenny Susanty Winda Ramadhani Wira Bima Stevent Sembiring Yanny Sartika Yelmida Azis Yoga Deswan Suwary Yoga Pratama Yusnila Halawa Zainal Abidin Zuchra Helwani Zuchra Helwani Zuchra Helwani, Zuchra Zulkifli Zultiniar Zultiniar