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The Effect Of Initiator Composition, Temperature, And Time On Ester Polymerisation Process Of Palm Fatty Acid Distillate Aidil Akbar; Bahruddin Bahruddin; Yelmida Yelmida
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 4, No 1 (2017): Wisuda Februari Tahun 2017
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Palm Fatty Acid Distillate (PFAD) as a byproduct of the processed of palm oil has great potential to be used as raw material for polyester synthesis. The purpose of this research is to study ester polymerisation from PFAD with the composition of initiator, time and temperature as the parameters. First, the esterification process was done by the reaction of PFAD and methanol that used sulfuric acid as catalyst. The reactant composition was 1:8 molar ratio, speed of stirrer at 150 rpm, and H2SO4 composition is 1% (w/w) PFAD with temperature at 70° C for 2 hours. The polymerisation process was done by the reaction of esterification stage product and mixed with benzoyl peroxide as initiator. The variation for this stage were the composition of benzoyl peroxide 1%, 5%,and 9% (w/w) of methyl ester, polymerisation time 4, 5 and 6 hours and polymerisation temperatures of 140, 150 and 160° C. The result showed that the esterification stage product was obtained methyl ester and GC-MS analysis showed that the purity of methyl esters is 90,1%. Polymerisation product that is obtained a polyester but still have vinyl group in the component of the product. Based on the results of polymerisation reaction of the end product, dark and thick and has a viscosity of 180-200 cp. Based on the test results of GC-MS the composition of the methyl ester was reduced from 27.67% to 5.62% as the product of polymerization process which mean that the methyl ester have been converted. The R2 in this study gained 0.9663 which means a significant and lack of fit value of 0.1341 which means insignificant then the variable had a p-value of 0,0002 for the model which it less than α = 0.05 with variables that had a significant impact on model.Key words: benzoyl peroxide, palm fatty acid distillate, polyester, synthesis
Pengaruh Nisbah Dan Suhu Pencampuran Terhadap Karakteristik Campuran Aspal Karet Alam Kompo (Cup Lump) Yanny Sartika; Irdoni Irdoni; Bahruddin Bahruddin
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 6 (2019): Edisi 1 Januari s/d Juni 2019
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Asphalt modified polymer (AMP) is used to increase the resistance of asphalt to changes in temperature by increasing the stiffness of the binder/binder at high temperatures and reducing stiffness at low temperatures at the same time. This study aims to study the effect of ratio and temperature of rubber cup lump on the characteristics of asphalt and determine the ratio and temperature of the best rubber cup lump for the manufacture of asphalt modified polymer. The asphalt used type of bitumen pen 60/70 Pertamina. Asphalt modified polymer is made by mixing cup lump with asphalt at a mixing temperature of 150 oC and 170 oC for 30 minutes. Cup lump ratio varied by 4%, 6%, 8%, 10% and 12%. Testing for modified asphalt includes parameters: penetration, softening point, weight loss and stability of the Marshall. Testing is in accordance with the 2012 Bina Marga General Specifications standard. Based on the research results obtained, the best ratio and temperature is 12% and mixing temperature 170 oC with a penetration value of 52.4 dmm, softening point of 63.55 oC, weight loss of 0.068 and the stability of the Marshall is 1904.4 kg.Keywords: asphalt modified, cup lump, ratio, stability, temperature
Evaluasi Pressure Drop Pada Sumur Injeksi Uap Di Lapangan Duri Dengan Persamaan Beggs-Brill Dan Moody Ahmad Riadi S Hasibuan; Bahruddin Bahruddin; Ahmad Fadli
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 1, No 2 (2014): Wisuda Oktober Tahun 2014
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Steam injection is a heat transfer process to petroleum reservoir through multiphase flow of wet steam. Estimating pressure drop in multiphase flow is more difficult than for single-phase flow. Multiphase flow is a complex phenomenon because of the interdependence of various variables that affecting pressure drop such as flow regime, hold up, flow geometry at horizontal, vertical or deviated, flow rate of each phase and the fluid properties of each phase. The purpose of this study is to find out the most appropriate model to calculate the pressure drop in steam injection wells and understand parameters that most affecting pressure drop. Research methodology for this study is descriptive analysis. Field data from 30 injection wells in Duri field are collected and compared with 2 variations of Beggs-Brill and Moody equation, which are the original model and the model with Palmer correction. Both models are translated into a simple computing program using Excel application. Calculation result from the model is compared with the measurement results to understand the deviation or error. As the result of this study, it is shown that Beggs-Brill and Moody model without Palmer correction is suitable for steam injection application. Average error is only 0,2% with a standard deviation of 3,32%. Further information is obtained from the sensitivity analysis that the accuracy of pressure drop calculation is affected by measurement accuracy of the steam flow rate, steam quality and steam temperature. Keyword: Beggs and Brill correlation, Moody diagram, Palmer correction, pressure drop, steam injection.
Polimerisasi Ester Dari Asam Lemak Sawit Destilat (ALSD) Dengan Menggunakan Inisiator Benzoil Peroksida 0,2 % Liendra Juniarti; Irdoni Irdoni; Bahruddin Bahruddin
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 2, No 2 (2015): Wisuda Oktober Tahun 2015
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Palm Fatty Acid distillate (ALSD) as a byproduct the processing of palm oil has great potential to be used as raw material oil-based polymers. The aims of this research to study the process polymerization of ester from ALSD using initiator (benzoyl peroxide) 0.2%. The stage process consisted of three phases. The esterification stage was done at temperatur 70° C, reaction time of 120 minutes, reactant ratio 1: 8 (ALSD: methanol), concentration of catalyst (H2SO4) 1% (w/w) PFAD; polymerization stage was done at temperature 120, 130, and 140 ° C, concentration of initiator (benzoyl peroxide) 0.2% (w/w) and variation of polymerization reaction time 3, 4, and 5 hours, and polyesterification stage was done at temperature 175-200° C, ratio of reactants 1: 1 (polymerized methyl ester: ethylene glycol), and the reaction time of 4 hours. The results of polymerization was analyzed by using viscosity test, FT-IR and GCMS. The highest viscosity was 25,58 mPa.s at temperature 130° C and 5 hours. The result using FT-IR showed that the polymerization process was unsuccessful, this was indicated by the presence of the vinyl group. The result of GCMS showed there had been molecular weight addition in polymerization process, that was only twice the initial molecular weight.Keywords: benzoyl peroxide, esterification, palm fatty acid distillate, polymerization.
Pengaruh Konsentrasi Completion Fluid Terhadap Laju Swelling Clay Pada Sumur Produksi Minyak Bumi Bramansyah Riswanda; Bahruddin Bahruddin; Irdoni HS
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 3, No 1 (2016): Wisuda Februari Tahun 2016
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In the process of oil production wells maintenance, sometimes it has to face containing mud (clay) formations and this situation can detain the process of well maintenance and damage downhole equipment, especially pumps because of clay swelling. This study intends to determine the concentration effect of completion fluid to clay swelling and determine the optimum completion fluid concentration In this study, KCl and XCD polymer has been chosen as the inhibiting compound of clay swelling. Concentration used is 2%, 4% and 6% for KCl, 2, 3 and 4 ppm for XCD polymer with a ratio between the solution with the clay is 1:8, 1 9 and 1:10. The temperature used is room temperature of 25° C. The results showed that the rate of swelling occurs most rapidly at 2% KCl ratio of 1:8. The phenomenon of swelling clay to a solution of XCD polymer is very small so it can be considered no swelling that occurs, either in 2, 3 or 4 ppm solution of polymer XCDKeywords: clay, swelling, oil producer well, KCl, XCD polymer
Preparasi Pelepah Sawit Untuk Bahan Baku Pembuatan Wood Plastic Composite (WPC) Ditinjau Dari Konsentrasi Asam Oksalat Dan Suhu Pelarutan Angelina Angelina; Bahruddin Bahruddin; Said Zul Amraini
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 5 (2018): Edisi 2 Juli s/d Desember 2018
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Components contained in the palm stem are cellulose, hemicellulose, lignin, and other extractive substances. Cellulose is the largest component of palm fronds. Preparation is used to remove components of hemicellulose and lignin and extractive substances there by increasing the cellulose component which will increase the strength of the interface on the matrix and filler. The purpose of this study was to study the effect of oxalic acid concentration and dissolution temperature on the chemical composition of palm stem in the preparation of palm stem which will be used as raw material of wood plastic composite. Samples of palm stem preparations were prepared using oxalic acid at concentrations of 0,5 M, 1 M, and 1,5 M. Samples were immersed in 15 min with dilution temperature is room temperature, 800C, 1000C, and 1200C. Then the sample size of palm stem dust used is 40 mesh. Tests include water content test and chemical composition test of palm stem using chesson-data method. The test results show that the water content in the palm stem sample is 5% -10%. While for the best composition of the palm stem obtained by preparation using oxalic acid with concentration of 1,5M at dissolving temperature of 1200C that is obtained cellulose level as much as 54%.Keywords : palm stem, cellulose, preparation, wood plastic composite
Sifat Dan Morfologi Wood Plastic Composite Berbasis Pelepah Sawit/Polietilen Dengan Kompatibiliser Maleic Anhydride Dan Inisiator Benzoil Peroksida Wahyu Suci Rahmani; Irdoni Irdoni; Bahruddin Bahruddin
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 5 (2018): Edisi 2 Juli s/d Desember 2018
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The low compatibility between thermoplastic and wood components is a major problem in the manufacture of wood plastic composite. Compatibilities used such as maleic anhydride is useful to increase the value of the mechanical and physical properties of the WPC. The purpose of this study is to determine the effect of the composition palm frond/polyethyleneand maleic anhydride on the properties and morphology of wood plastic composite. The composition of palm frond/polyethylene used is 50/50, 60/40, 70/30 with a mixture of 2% paraffin additive, maleic anhydride (MAH) 3%, 4%, 5%, and benzoyl peroxide 1% of the weight of MAH. The process of mixing fillers, matrices, and additives uses an Internal MixerLabo Plastomill at temperature of 145oC and rotor speed of 80 rpm. The sample was then pressed using a hot press at a temperature of 145oC and a pressure of 100 kgf/cm2. Composites produced were tested including characterization of functional groups, morphological conditions, physical properties and mechanical properties. The results showed that the addition of filler and maleic anhydride composition had a relatively significant effect. The best WPC material is found in the variation palm frond/polyethylene60/40 and MAH 5% with a density value of 1.19 gr/cm3, water content of 0.16%, water absorption capacity of 0.41%, swelling thickness of 0.11%, tensile strength of 18.664 MPa, elastic modulus of 2175.9 MPa, and flexural strength of 35.05 MPa.Keywords: benzoyl peroxide, maleic anhydride, palm stem, wood plastic composite
Pembuatan Komposit Plastik Pati Sagu-Carboxymethyl Cellulose Dengan Penambahan Plasticizer Gliserol Viodita Rizki; Said Zul Amraini; Bahruddin Bahruddin
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 6 (2019): Edisi 1 Januari s/d Juni 2019
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Food packaging aims to protect food products from various physical and mechanical damage. Food packaging that is generally in the form of plastic derived from petroleum is non-renewable, polluting the environment and harmful to human health. One alternative to overcoming this problem is the use of bioplastics that can be decomposed and consumed in the form of edible films. The purpose of this study was to study the effect of levels of carboxymethyl cellulose (CMC) and glycerol plasticizers on mechanical properties and biodegradation of sago starch based bioplastics. Bioplastics were made by mixing sago starch, glycerol (15, 20, 25 % w/w) and CMC (35, 40, 45 % w/w). The resulting bioplastics were carried out by several tests which included tensile strength, elongation, biodegradation and data analysis using Design Expert. The most significant factor affecting all responses was CMC levels followed by glycerol plasticizers. The optimum process conditions were obtained at CMC content 45 % w/w and glycerol plasticizer 15 % w/w with a response value of tensile strength of 8,3 MPa, elongation of 16,8 % and biodegradation 51 %. Keywords: bioplastics, CMC, filler, glycerol, sago starch, RSM
Modifikasi Bioplastik Berbasis Pati-Polivinil Alkohol (PVA) Dengan Cross-Linking Agent Asam Sitrat Dan Pemplastis Sorbitol Yoga Pratama; Bahruddin Bahruddin; Idral Idral
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 7 (2020): Edisi 2 Juli s/d Desember 2020
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Bioplastic characteristics are influenced by various parameters, including levels of cross linking agents (such as citric acid) and plasticizers (such as sorbitol). The research was to study the effect of citric acid and sorbitol levels on mechanical properties, cross linking (characterized by ester groups), and biodegradation of bioplastics based starch-polyvinyl alcohol (PVA). Bioplastic manufacturing is done by mixing sago starch -PVA (1: 3), sorbitol (10, 15, 20% w/w) and citric acid (2.5; 5; 7.5% w/w) at 90ºC for 55°C minutes, optimization of process conditions is determined by response surface methodology (RSM). The parameters tested include tensile strength test, elongation, and biodegradation. The most significant factor affecting all responses was the level of citric acid and sorbitol. The optimum process conditions were obtained at 4.8% w / citric acid content and sorbitol 11.4% w / w with a tensile strength response of 26,34 MPa, elongation 379%, and 49,18% biodegradation. Keywords: bioplastics, citrid acid, sorbitol, polyvinyl alcohol, RSM, sago starch
Epoksidasi Karet Alam Dengan Menggunakan Surfaktan Amonium Lauril Sulfat Sebagai Wetting Agent Donny Kurniawan; Nirwana Nirwana; Bahruddin Bahruddin
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 2, No 2 (2015): Wisuda Oktober Tahun 2015
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Epoxidation of natural rubber were tried to be produced under various conditions within in-situ epoxidation reaction. The use of ammonium lauryl sulphate (ALS) as wetting agent also the effect of hydrogen peroxide (H2O2) amount and the reaction temperature were discussed. The molar ratio values of the isoprene units of natural rubber to formic acid and H2O2 was set at 1:1:1, 1:1:2, and 1:1:3 while the temperature was varied by 40, 50 and 60o C. ALS that been used were 1 phr within 100 ml Latex NR that contained 20,52% DRC. The process reaction were using a reactor with stirrer and water bath for five hours. The results were shown in spectroscopy FT-IR instrument. From the preparation, we know that the natural rubber that been used had the same rubber content compare to the previous researcher. The molar ratio and temperature variation that have been used were not succed to made epoxidation group in natural rubber. The function of ALS as wetting agent at the preparation were not worked enough, so the epoxidized were not produced.Keywords: ALS, formic acid, H2O2, in-situ epoxidation
Co-Authors - Martutik ABD Aziz, ABD Abd. Rahim Ade Putra Adhy Prayitno Adrianto Ahmad Adrianto Ahmad Ady Maulana Afkari, Fahmi Afrila Afrila Ahmad Fadli Ahmad Riadi S Hasibuan Ahmad Zain Sarnoto Aidil Akbar Akhmad Hasan Saleh, Akhmad Hasan Alfian Malik Alfian Mukti Fajar Alumni STIKES Husada Borneo Amir Hamzah Ananda Putri Andi Ibrahim Andreas Sahat Parsaulian Andri Mulia Angelina Angelina Anugerah Rifaldi Aras Mulyadi Aris Aprianto Cahyono Arya Wiranata Arya Wiranata Ayik Pusakaningwati Bramansyah Riswanda David Andrio DESI PURNAMA SARI Dewi Maya Sari Dian Anggraini Purba Dian Eka Indriani, Dian Eka Donny Kurniawan Edi Saputra Efriyeldi, Efriyeldi Eka Mawarni Eko Sumadi Endro Siswoko Eri Malindo Fachry Abda El Rahman Fajar Ladung Farikhatul Akhlis Fahruddin Yulianto Fariq Fahrun Nisa Fatwa, Abdul Halil Firdaus Septiawan Fitra Annisa Fitriani Fitriyani Syukri Gunawan Gunawan Hamsar Hamsar Handayani, K.H Sri Hasan, Haslinda Herlili Peronika Herry Novriansyah Ida Zahrina Idral Amri Idral Amri Idral Idral Imam Agus Basuki Iradhatullah Rahim Irdoni HS Irdoni Irdoni Irdoni Irdoni Irfan Irwiadi Irwan Idrus Isra, Muhammad Ivan Fadhillah Izatun Nufus Jabosar Ronggur Hamonangan Panjaitan Jasman Khairat KRISTINA WIJAYA Liendra Juniarti Lita Darmayanti Lubis, Abdillah Luci Octaria M. Adely Ihsan M. Aldi Muhtadibillah M. Iwan Fermi Mansida, Amrullah Maradona Maradona Mardatillah Mariatul Qiftiah Melda Helena S Melly Anggraeni Mentari Nur Arafah Mery Christina Meysara Meysara Muchlis Ade Putra Mudinillah, Adam Muh. Zulkifli Muhamad Ilham Syabana Muhammad Faiz Fadhlurrohman Muhammad Nasri Katman Muhammad Nur Muhammad Rigan Yusri Muhammad, Muhammad Mutiara Wulandari Nirwana Nirwana Nur Arfiyah Febriyani Nurul Aini Thaibil Fadhly Peji Nopeles Pratiwi MK Puskesmas Guntung Payung Rahma Amariaman Rahmat Rani Yuliantari Razita Hariani Rina Gunarti Rizky Sandy Harahap Robby Kumar Robby Kumar Roy Marthin Panjaitan Rozanna Sri Irianty RS Khusus Bedah Siaga Banjarmasin Septiana Veronika S Siti Sakinah Sofi Nur Meilina Sofyan Sonny Wijaya Sri Helianty Sri Rezeki Muria STIKES Husada Borneo Sudirman Sudirman Suherman, Suherman Sunardjo Surya Baskara Jaya Suwondo Suwondo Syamsia Syaparuddin Syarfi Daud Syelvia Putri Utami Syukri, Fitriyani Thamrin Thamrin Ummy Aisyah Rochaeni Viodita Rizki Wahyu Suci Rahmani Wenny Susanty Winda Ramadhani Wira Bima Stevent Sembiring Yanny Sartika Yelmida Azis Yoga Deswan Suwary Yoga Pratama Yusnila Halawa Zainal Abidin Zuchra Helwani Zuchra Helwani Zuchra Helwani, Zuchra Zulkifli Zultiniar Zultiniar