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Journal : JURNAL REKAYASA KIMIA

Application of Recycle System on a Cocoa Pod Husks Gasification in a Fixed-Bed Downdraft Gasifier to Produce Low Tar Fuel Gas Sunu Herwi Pranolo; Joko Waluyo; Jenni Prasetiyo; Muhammad Ibrahim Hanif
Jurnal Rekayasa Kimia & Lingkungan Vol 14, No 2 (2019): Jurnal Rekayasa Kimia & Lingkungan (December, 2019)
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v14i2.14160

Abstract

Biomass gasification is potentially generating not only producer gas but also tarry components. Practically, the gas may substitute traditional fuel in an internal combustion engine after reducing the tar. This research examined a producer gas recycle system to reduce tar component of producer gas generated with cocoa pod husks gasification using air as gasifying agent in a fixed-bed downdraft gasifier. Cocoa pod husks feed sizes were +1 sieve, -1+ 0.5 sieve, and -0.5 sieve. The gasification process was operated at the temperature range of 491 940oC and at various gasifying agent volumetric rates of 62.84; 125,68; and 188.53 NL/min or at equivalent ratio range of 0.014 0.042. A recycle system of outlet producer gas to gasifier was set at volumetric rates of 0.139; 0.196; and 0.240 L/min. The performance of the system was evaluated with analyzing the tar component using gravimetric method of ASTM D5068-13, and the gas component of CO, H2, CO2 and CH4 compositions in producer gas were analyzed using Gas Chromatography GC-2014 Shimadzu sensor TCD-14. This recycle system succeeded in reducing tar content as much as 97.19% at 0.139 L/min of recycle volumetric rate and at biomass feed size of -1+0.5 sieve. The producer gas contained CO, H2, CO2 and CH4 of 23.29%, 2.66%, 13.30%, and 14.18% respectively. The recycle system cold gas efficiency was observed 65.24% at gasifying agent volumetric rate of 188.53 L/min and at biomass feed size of +1 sieve.
Kinetic of Aerobic Decomposition Process of Linear Alkylbenzene Sulfonate (LAS) in a Well-Shaped Bioreactor Using Commercial Inoculum Margono, Margono; Pranolo, Sunu Herwi; Waluyo, Joko; Sembodo, Bregas Siswahjono Tatag; Susanti, Ari Diana; Setyono, Prabang; Dahlan, Irvan
Jurnal Rekayasa Kimia & Lingkungan Vol 19, No 1 (2024): Jurnal Rekayasa Kimia & Lingkungan (June 2024 )
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v19i1.34317

Abstract

Linear alkylbenzene sulfonate (LAS) belongs to a class of surfactants claimed as an environmentally friendly detergent due to its biodegradability. However, the disposal of LAS waste into the waters without prior treatment causes a risk to the ecosystem. These experiments aimed to study the effects of commercial inoculum size EM-4 on the aerobic decomposition process of LAS in a well-shaped bioreactor. These experiments of LAS decomposition were carried out in a batch system aerated by 2.5 L/min for the low and high initial LAS concentrations. The effects of inoculum acclimation were also investigated for the high LAS concentration. The effects of inoculum size were explored at sizes ranging from 5 to 20% v/v, and samples were taken on a regular basis for residual LAS assessment. The first-order kinetic model gave the best fit to the rate of LAS decomposition, with the highest rate coefficient of 10.44 x 10-2 hour-1. This was achieved by using a 20% v/v inoculum for the initial low concentration of LAS, resulting in the highest decomposition efficiency of 89.4% after 24 hours of incubation. The decomposition rate was slower at the high LAS concentrations than at the low concentrations. The inoculum acclimation increased the decomposition rate for the high LAS concentrations. The results of this study show great potential for the bioremediation of LAS detergent waste using commercial inoculum in a well-shaped batch bioreactor.
Tar Removal of Palm Kernel Shell Syngas using Wet Scrubber Putro, Firman Asto; Pranolo, Sunu Herwi; Waluyo, Joko; Basworo, Agung Tri; Norman, Hafiz; Kristiani, Anis; Hidayati, Luthfiana Nurul
Jurnal Rekayasa Kimia & Lingkungan Vol 19, No 1 (2024): Jurnal Rekayasa Kimia & Lingkungan (June 2024 )
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v19i1.33341

Abstract

In the current situation, biomass gasification has become a major interest in producing clean energy and green chemicals. By gasification, the biomass can be converted to synthetic gas (syngas) for many purposes. However, syngas with high tar content can cause pipeline fouling and disturb the operation of downstream equipment. To reduce tar content, a two-series wet scrubber was installed for syngas cleaning produced by palm kernel shell gasification. Firstly, the gasification is operated at a temperature range of 500 600oC and 700 800oC to determine the conditions where the lowest tar syngas is produced. After that, the wet scrubber is installed with a variety of solvents including isopropyl alcohol, water, used cooking oil, and used lubricating oil. The results show that the lowest tar syngas was produced at a temperature of 800oC with a tar yield of 0.165 g/kg biomass. Meanwhile, in the same condition, isopropyl alcohol delivers the most substantial impact on tar removal efficiency, whereas used lubricating oil results in less impact. The use of isopropyl alcohol resulted in 99.25% tar removal effectiveness while lubricating oil yielded just 50.32%.
Co-Authors Abdul Karim Zulkarnain Abdul Wahid Abil Fida Siskayanti Agus Imam Sonhaji Agustinus Winarno Akhmad F. Alhikami Akif Mahrus Ali Allam K, Muhammad Amalia Febryane Adhani Mazaya Anifah, Eka Masrifatus Anis Kristiani, Anis Ari Ariangga Orranius Putra Patarru Ari Diana Susanti, Ari Diana Arief Budiman Ariyadi, Hifni Mukhtar Bakar, Syafriyudin Abu Bambang Eko Afiatno Bambang Purwono Basuki, Rio Basworo, Agung Tri Bikorin Bikorin Dahlan, Irvan Damayanthy, Ramanda Ayu Damianus Mario Ricky Fernando Damianus Mario Ricky Fernando Daroini, Moch. Fauzun Deny Ratna Yuniartha Dinda Safitri Ramadhani Dodik Prakoso Eko Hery Suwandojo Dodik Prakoso Eko Hery Suwandojo Dwi Siswanta Edi Iskandar, Edi Edy Prayitno Eko Haryanto Eko Haryanto Ely Afridiana Kuncoro Ernawati, Kadek Lusi Fajar Y. Prabowo Ferhadius Endi Ferriawan Yudhanto Ganjar Andaka Gunawan Nugroho Hadi Saputra Hana Himatul ‘Aliyah Haris Puspito Buwono Hartono, Moh Hasan Albana Rhomadhon Hasanah, Rafiatul Hayatullah, Wahyu Herry Purwanti, Noordiana Herry, Noordiana Heru S. B. Rochardjo Hotlan Samosir Hudiyo Firmanto, Hudiyo I Ketut Mahardika Ibnu Singgih Pranoto Ikbar, Royhan Indah Retuwati Ramadhana Izzulhaq, Muhammad Ghozy Jenni Prasetiyo Johan Syafri Mahathir Ahmad Jumina Jumina Jussac Maulana Masjhoer Kamalia Fikri Kholiq Fadillah Amriansyah Kosmar Marojahan Damanik Kurnia, Irwan Kuswati Kuswati Lestari, Nidi Lestary, Septy Luthfiana Nurul Hidayati, Luthfiana Nurul Machida, Masato Mahda Mega Andyka Hieguyta Marausna, Gaguk Mardiana, Alif Margono Margono Michael Seen Mochammad Iqbal Mohammad Imam Farisi Mohammad Wildan Habibi, Mohammad Wildan Muhammad Farhan Abrar Muhammad Ibrahim Hanif Muhammad Kusumawan Herliansyah Muhammad Sholeh MUHAMMAD SHOLEH Muhammad Yusuf Muslim, Ilham Taufik Musyarofah Musyarofah, Musyarofah Nabila, Zahrani Putri Ndaru Pratama, Nico Nidia Lestari Noordiana Herry Purwanti Norman, Hafiz Nugroho Dewayanto Nur Aini Masruroh Nur Mayke Eka Normasari Nur Wahyudi Paryanto Paryanto Pazli, Pazli Prabang Setyono Pramudya Dwi Aristya Putra Pranolo, Sunu Herwi Purba, Ibnu Tryansar Purmanna, Astrino Putra, Ariadi Indra Putri, Rizqi Wulandari Putro, Firman Asto Qadarusman, Muhammad Luqman Rachmawati, Rr Yuliana Rahmat Bayu Raziq, Abdur Reza, Mutia Ridho Bayuaji Ridho Hantoro Rofika Rofika, Rofika Rony Arjuna Rosalinda, Julitha D Rosalinda, Julitha Dwi Saiful Huda Samuel Kristiyana Sapawe, Norzahir Sembodo, Bregas Siswahjono Tatag Septian, Ardie Setyowati Rahayu, Suparni Sidiq, Muhammad Fadel Simarmata, Henni Mariani Slamet Hariyadi Su Dar mono Subchan, Wahju Sudarmono Sudarmono Sugiyanto - Sugiyanto Sugiyanto Sunu Herwi Pranolo Suparni Setyowati Rahayu Sutrisno S Suwanto Raharjo Syafriyudin Syafryudin Tiurlina Siregar Totok R. Biyanto TRI ACHMADI Tri Haryanto Triyanto, Heru Agus Umi Fadilah, Umi Wahyu Wilopo Wahyu Wilopo Wicaksana, Hangga Yayuk Fatmawati, Yayuk Yehezkiel Steven Kurniawan Yonathan Ito Yudha, Venditias Yuli Pratiwi Yuli Pratiwi Yulinar Pramesti Cahyani Zaid Haidar Khairy Zainal Abdi