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Journal : Journal of Mechanical Engineering Science and Technology

The Effect of Adding Aluminium on the Performance of ZnO NRs/PANi in Their Application as Photoelectrochemical Water Splitting Sari, Eprilia Trikusuma; Mufti, Nandang; Nadhira, Anissa Chairani Alfin; Wisodo, Hari; Diantoro, Markus
Journal of Mechanical Engineering Science and Technology (JMEST) Vol 7, No 2 (2023)
Publisher : Universitas Negeri Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17977/um016v7i22023p202

Abstract

Photoelectrochemical (PEC) is a new renewable energy technology that converts H2O into hydrogen and oxygen gas with the help of sunlight. A photoelectrochemical cell device consists of three main components, one of which is the photoanode. One of the materials that can be used as a photoanode is ZnO which has good electrical properties and is non-toxic. Nanorods-structured ZnO has the advantage of being able to increase light absorption due to its high surface area. However, the resulting performance is still quite low. So it is necessary to make modifications to the photoanode, one of which is by adding aluminium material to ZnO NRs, which has the potential to increase the conductivity of PEC in the production of H2 and O2 in H2O. To overcome the loss of samples during testing, the thin film will be coated with conductive polymers such as polyaniline (PANi), which has high conductivity, can increase photoactive ability, and has good corrosion resistance. In this study, the performance of ZnO NRs/PANi against AZO NRs/PANi will be studied by adding aluminium. The ZnO nanorods were synthesized by Hydrothermal method, Aluminium was deposited on ZnO NRs by DC Magnetron Sputtering method, and PANi was synthesized by polymerization method. From the XRD characterization results, it can be concluded that the addition of aluminium to ZnO NRs/PANi causes an increase in crystallinity and peak shift. SEM characterization shows that the addition of Al to ZnO NRs/PANi causes the porosity value to increase. In addition, UV-Vis characterization showed that the addition of Al material to the ZnO NRs/PANi thin film resulted in a wider range of absorbance of the light spectrum. Then, Cyclic Voltammetry test shows that the addition of aluminium increases the efficiency of the photoelectrochemical.
Harnessing the Role of Carbon Black: A New Frontier for Energy-Density Supercapacitor Electrodes Komariyah, Ana Yuli; Luthfiyah, Ishmah; Albadi’ah, Ida Vaeruza; Nasikhudin, Nasikhudin; Meevasana, Worawat; Diantoro, Markus
Journal of Mechanical Engineering Science and Technology (JMEST) Vol 9, No 1 (2025)
Publisher : Universitas Negeri Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17977/um016v9i12025p268

Abstract

The performance of activated carbon (AC)-based supercapacitor electrodes is often limited by poor electrical conductivity, prompting interest in conductive additives such as carbon black (CB). This study explores the transformative potential of CB as a conductive additive in AC-based supercapacitor electrodes and systematically investigates CB mass loadings of 0%, 5%, 10%, 15%, and 20%, using styrene-butadiene rubber (SBR) as the binder. The findings in this study demonstrate that 10% CB is the optimal loading, offering a balanced performance in terms of structure, morphology, and capacitance. X-ray diffraction (XRD) analysis reveals a distinct structural evolution at 10% CB, characterized by the exclusive emergence of a (100) peak at 43° 2θ, which indicates the formation of dense graphene-like layers and enhanced π-π electron delocalization. This promotes the formation of robust conductive networks, reducing electrode resistivity by 72%. Morphological and specific surface area characterization confirms the uniform particle distribution of an ultra-thin electrode AC-10% CB (26.5 μm) with a high surface area of 851.84 m²/g; this maximizes ion-accessible active sites and minimizes diffusion pathways. These combined effects result in a specific capacitance of 61.33 F/g, representing a 12% improvement over the pristine electrode (56.36 F/g) and 89.87% capacitance retention after 50 cycles. These results highlight the importance of optimizing CB loading: Lower concentrations (
Effect of Thickness of Nanofiber Separator Membrane PAN/PVDF on Supercapacitor’s Performance Agustina, Silvia Nurlaili; Diantoro, Markus; Hartatiek, Hartatiek; Nasikhudin, Nasikhudin
Journal of Mechanical Engineering Science and Technology (JMEST) Vol 9, No 1 (2025)
Publisher : Universitas Negeri Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17977/um016v9i12025p228

Abstract

Separators in supercapacitors have an important role as intermediaries for ions that pass during the charge-discharge process and affect the performance of supercapacitors. Therefore, a comprehensive study is needed related to separator characteristics, including morphology, pore size, diameter, functional group, and electrochemical performance of separator membranes from PAN/PVDF composites. The separator membrane was synthesized using the electrospinning method with thickness variation (2, 4, 6, 8, and 10 layers), followed by supercapacitor fabrication with coin cell device. The resulting membrane was then characterized by Scanning Electron Microscope (SEM) and Fourier Transform Infrared (FTIR). For the result of supercapacitor fabrication with coin cells, Galvanostatic Charge-Discharge (GCD), Cyclic Voltammetry (CV), and Electrochemical Impedance Spectroscopy (EIS) were carried out to determine supercapacitor performance. FTIR results showed that the PAN/PVDF membrane was successfully composites with the addition of new peaks identified as PVDF and PAN at wave numbers 2243.21 and 881 cm-1. The nanofibers formed have diameters ranging from 319.7 to 339.95 nm. The optimum percentage of electrolyte uptake is obtained at membranes that have 6 layers, which is 318.18% and decreases to 173.68% the thickness is 10 layers. In this study, the optimum supercapacitor performance was obtained in the 6 layers variation with a thickness of 75.91 x 103 nm with a gravimetric capacitance value is 53.36 F/g, the capacity retention is 88.96% after being tested for 500 cycles, the largest curve area of CV, and an ionic conductivity value is 54 x 10-5 S/cm.
Co-Authors -, Kurnia Galuh Candra Kirana A.N. Afandi Abdillah, Ahmad Muhaimin Abdul Kariem Arof Abdulloh Fuad Ade Siyanti Nurul Hidayah Ade Siyanti Nurul Hidayah Adetya Rahman Aditya Wahyu Setiawan Afrianda, Teguh Agung Haryono Agus Budiyono Agus Purnomo Agustina, Silvia Nurlaili Agustinus Agung Nugroho Ahmad Taufiq Ahmad Taufiq Ahmad Zulian Aji Prasetya Wibawa Akhmad Al Ittikhad Akhmad Al Ittikhad Al-Afandy, Farhan Nur Albadi’ah, Ida Vaeruza Aldias Bahatmaka Alfianti Nur Laili Alias, Yatimah Binti Alma Nur Roisatul Masruhah Amrizaldi Amrizaldi Amrizaldi, Amrizaldi Andrivo Rusydi Ani Rahmawati Anjar Nur Ramadhani Apri Wiyono Aprilita Ekasari Arif Hidayat Arif Hidayat ARIF HIDAYAT Aripriharta - Ariptiharta Astrini Dewi Kusumawati Aturroifah, Nuviya Illa Muthi Avinly Muhammad Najib Abdullah B. Anggit Wicaksono B. Anggit Wicaksono, B. Anggit Brian Yuliarto Budi Mulyanti Chaifa, Dian Emma Chusna, Nadiya Miftachul Chusnana Insyaf Yogiyanti Dean Setyawan Derry Pradhana Dian Farida Rosanti Dina Maftuha Dinda Taruna Nagara Doni Andra Ema Tri Alvianti Endang Purwaningsih Endang Purwaningsih Endang Purwaningsih Eny Susanawati Erni Yulianti Erwinestri Hanidar Nur Afifi Ety Rimadani Faizuna Roudhotin Nurilma Fajariman, Ilham Dias Fath, Yusril Al Fathoroni Fathoroni Fathoroni, Fathoroni Fatmawati , Fatmawati Febriani, Candra Putri Fernando, Trio Junira Fikri, Ahmadani Darul Fina Nur Azizah Fitri Fatimah Fitriyah, Ana Lailatul Futri Yuliana G. Blake Hafizh Prihtiadi Haliq, Muh Idham Handoyo Saputro Hari Rahmadani Hari Wisodo, Hari Hartatiek, Hartatiek Hartatiek, Hartatiek Helmi Helmi Helmi Helmi Helrin Pujiarti Hendra Susanto Herawati Susilo Herlin Pujiarti Hidaayatullaah, Hasan Nuurul Hidayah, Ade Siyanti Nurul Hidayat, Rachmat Husen Jauwad I Dewa Putu Nyeneng Ida Hamidah Ida Purnamasari Ida Vaeruza Albadi’ah Idris Idris Imam Abdul Syukur Imani Dyah Aulia Hans Irvany Nurita Pebriana Ishmah Luthfiyah Ishmah Luthfiyah J. Baas Jamiatul Mufidah Jamiatul Mufidah Joko Utomo Joko Utomo Jumril Yunas Karim, Moh. Hafidhuddin Karin Mayludya Handi Kartini Herlina Khoirul Haniin Komariyah, Ana Yuli Kormil Saputra Kurniawan, Novian Candra Laksono, Yoyok Adi Setio Lenny Agustina Suwastika Sari Leny Suryaning Astutik Lia Yulianti Lia Yuliati Lia Yuliati, Lia Lilia Halim, Lilia Lilik Hasanah Lilis Nuryanti Lisa Ainun Najihah Luthfiyah, Ishmah M. Abdurrahman Sunni M. Alfian Mizar Mapandi, Rohanie D Meevasana, Worawat Miksandri Eksanita Millah Nurhamidah Moch. Sholihul Hadi Moh. Hafidhuddin Karim Mohamad Rodhi Faiz Mohammad Zaky Tatsar Mubarak, Bagja Rahmat Muchammad Akbar Nadhiif Muchammad Harly Mudinillah, Adam Muh Idham Haliq Muhamad Fadhil Rahman Muhammad Baqir Zaini Muhammad Safwan Aziz Muhardjito Muhardjito Mustikasari, Ayu Azrurin Nabila Hari Arimbi Nadea Catur Nurmayanti Nadhira, Anissa Chairani Alfin Nadi Suprapto Nadiya Ayu Astarini Nadiya Ayu Astarini Najmi, M. Ikhwan Nandang Mufti Nando Dyas Arya Nasikh Nasikhudin Nita Nur Aini Nur Amirah Mat Nor Nuril Munfaridah, Nuril Nurilma, Faizuna Roudhotin Nurmayanti, Nadea Catur Nurul Atqiya Nuviya Illa Muthi Aturroifah Pahlevi, Reza Akbar Parno Parno Parno Prabowo, Eri Setyo Priyadi, Rian Ramdhani Ramdhani Ramesh T. Subramaniam Retnaningsih, Prihatini Revnika Faizah Reza Akbar Pahlevi Rian Priyadi Rian Priyadi Ridha Diningsih Rif’atu Nuril Laily Risa Suryana Robi Kurniawan Roer Eka Pawinanto, Roer Eka Roshifah Dinilqoyyimah S E I Suryani S W Himmah Sabilal Rosyad Sandriana Parantean Sari, Eprilia Trikusuma Sefia Kharen Gilar Tiana Sentot Kusairi Shahan Shah Shelya Nova Candra Kirana Silvia Nurlaili Agustina Siti Maryam Siti Zubaidah Solehudin Solehudin Sri Rahayu Lestari Subakti S Sucihatiningsih Dian Wisika Prajanti Suhiro Wongso Susilo Sunaryono Sunaryono Sunaryono, Sunaryono Supriana, Edi Supriyono Koes Handayanto Susriyati Mahanal Sutopo Sutopo T. T. M. Palstra Taufik Hidayat Thathit Suprayogi Titik Istirohah Ulwiyatus Sa’adah Vita Herlin Nur Vidianti Wardani, Dwisri Wartono Wartono Wasis, W Wicaksono, Adi Tri Winarto Winarto Wulandari, Nurul Putri Yudyanto Yudyanto Yuliana, Futri Yulmaisi Dwi Asmarita Yunan Amza Muhammad Yusril Al Fath Z Nurdiana ZAINUL ARIFIN IMAM SUPARDI