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The Oriented Attachment Crystal Growth Model in Hydrothermal Synthesis of Magnetite (Fe3O4) Nanoparticles Ahmad Fadli; Amun Amri; Esty octiana sari; Sukoco Sukoco; Deden Saprudin
Journal of Applied Materials and Technology Vol. 1 No. 1 (2019): September 2019
Publisher : AMTS and Faculty of Engineering - Universitas Riau

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31258/Jamt.1.1.15-19

Abstract

The magnetite nanoparticles (Fe3O4) are very promising nanomaterials to be applied as drug delivery due to their excellent superparamagnetic, biocompatibility and easily modified surface properties. Those properties are influenced by the structure and size of the material which can be controlled by studying the evolution of crystal growth. The purpose of this research is to study the evolution of crystal growth of magnetite nanoparticles in the hydrothermal system and determine the crystal growth kinetics using the Oriented Attachment Growth model. Magnetite nanoparticles were synthesized using a hydrothermal method from FeCl3, citrate, urea and polyethylene glycol at 210?C for 1 - 12 hours at a various concentration of FeCl3 (0.05 M, 0.10 M, and 0.15 M). The characterizations were conducted by X-ray Diffraction (XRD), Transmission Electron Microscope (TEM), Particle size analyzer (PSA), and Vibrating Sample Magnetometer (VSM). The XRD difractogram indicated that the magnetite was begun to form at 3.5 hours synthesis. The crystallinity and the crystal size of magnetite rose with reaction time. The diameter of magnetite crystals was in the range of 9.4-30 nm. Characterization by TEM showed that the particles were formed from a smaller particles which were then agglomerated. The PSA characterization showed that the distribution of diameter size enlarged with the enhancement of concentrations. VSM result showed that the magnetite nanoparticle has superparamagnetic properties. The magnetite crystal growth can be fitted by the Oriented Attachment Growth model with an error of 29%.
Pembuatan lilin aroma terapi menggunakan sarang lebah dan ekstrak lemon di Kelurahan Sungai Pagar Kecamatan Kampar Kiri Kabupaten Kampar Silvia Reni Yenti; Ahmad Fadli; Zultiniar Zultiniar; Sunarno Sunarno
Unri Conference Series: Community Engagement Vol 1 (2019): Seminar Nasional Pemberdayaan Masyarakat
Publisher : Lembaga Penelitian dan Pengabdian kepada Masyarakat Universitas Riau

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31258/unricsce.1.355-361

Abstract

Village development is one of the national development interests in which universities contribute to the implementation of the Community Work Program (KUKERTA) in the form of Community Service in a designated area. Kampar is one of the areas that has the biggest honey sialang potential in Riau Province, one of which is Sungai Pagar sub-district, Kampar Kiri Hilir sub-district. Honey honeycomb processing that is not processed optimally can provide the latest innovation, namely the making of aromatherapy candles by using honeycomb and lemon extract. This dedication activity aims to provide new knowledge expertise to the community of Sungai Pagar sub-district as one form of efforts in increasing national development. A series of activities include counseling or outreach, training in aromatherapy candle making, packaging and marketing. This activity gave a positive response from the Sungai Pagar community by forming a collaboration between the KUKERTA Community Service Team and Imbo Kaluang UKM. The outputs generated from these community service activities are aromatherapy candle products, Appropriate Technology Book (TPG), mass media publications (print and online) and journal publications.
Peningkatan Kapasitas Produksi Unit Usaha Di Rumah Amal Mis Hubbullah Kelurahan Tangkerang Timur Kecamatan Tenayan Raya Kota Pekanbaru Silvia Reni Yenti; Amun Amri; Ahmad Fadli; Zultiniar Zultiniar; Sunarno Sunarno; Wisrayetti Wisrayetti
Unri Conference Series: Community Engagement Vol 3 (2021): Seminar Nasional Pemberdayaan Masyarakat
Publisher : Lembaga Penelitian dan Pengabdian kepada Masyarakat Universitas Riau

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31258/unricsce.3.665-672

Abstract

Increasing the production capacity of the business unit at the Mis Hubbullah charity house to develop and improve the business unit so that it is expected to increase income that supports the Education program at the Mis Hubbullah charity house, one of the sources of animal protein that is widely consumed by the public, easy to obtain is fish and the price is cheap, but Fish quickly undergo a process of decay, so it is necessary to preserve fish. Preservation of fish aims to reduce the water content in the fish body so that it does not provide an opportunity for bacteria to breed. Fish undergo the process of decay quickly compared to other foodstuffs. To increase sales value and income, it is necessary to give a touch of innovation so that it can add business units and attract public interest. Therefore, in this community service activity, counseling was carried out on the diversification of processed catfish meat products into practical and more quality catfish nugget products. In addition, training on making catfish nuggets was conducted. Potential targets who will be given counseling are students from the Al-Ansar Mis Hubbullah Foundation.
The Oriented Attachment Model Applied on Crystal Growth of Hydrothermal Derived Magnetite Nanoparticles Ahmad Fadli; Amun Amri; Iwantono Iwantono; Arisman Adnan; Sunarno Sunarno; Sukoco Sukoco; Mayangsari Mayangsari
Indonesian Journal of Chemistry Vol 20, No 2 (2020)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.42917

Abstract

Magnetite (Fe3O4) nanoparticles are very promising to be applied as a drug delivery system (DDS) for cancer chemotherapy. In this research, the crystal growth of hydrothermal derived magnetite particles was studied by oriented attachment (OA) model. The OA model was used to investigate the mechanism and the statistical kinetic of crystal growth. The crystal diameter change as a function of time with different concentration was measured using XRD. Firstly, 0.3248 g FeCl3 and 1.1764 g of sodium citrate, as well as 0.3604 g urea were dissolved into 40 mL of distilled water in a reactor. Subsequently, the reactor temperature was maintained at 210 °C and reaction time of 3.5–12 h in an air oven. The morphology of obtained particles was characterized using TEM, whereas VSM was used to determine the magnetic hysteresis curve. The XRD pattern showed that magnetite was obtained at temperature 210 °C and 3.5 h reaction time, as well as its intensity increased with reaction time. The crystal size of Fe3O4 was 9.44 nm at 3.5 h and appropriate with the oriented attachment model. The magnetite nanoparticles with shaped core-shell size less than 50 nm and suitable for biomedical application especially as drug delivery.
INOVASI Green Bone Implant MENGGUNAKAN ROTAN ( Calamus manau M ) SEBAGAI SUBSTITUT LOGAM Agung Prabowo; Muhammad Reski; Ahmad Fadli
Indonesian Journal of Fundamental Sciences Vol 3, No 2 (2017)
Publisher : Universitas Negeri Makassar

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (377.05 KB) | DOI: 10.26858/ijfs.v3i2.4780

Abstract

Rotan merupakan tanaman yang banyak terdapat di Indonesia. Struktur anatomi batang rotan berhubungan erat dengan menentukan keawetan dan kekuatan rotan, antara lain  adalah besar pori dan tebalnya dinding sel serabut. Dinding sel adalah komposit serat yang terbuat dari mikro-fibril selulosa yang disisipkan ke dalam matriks hemiselulosa dan lignin. Pergantian bundel serat dan daerah berpori saluran ini lah membuat kayu sebagai bahan elektif untuk digunakan sebagai template dalam memulai persiapan pengganti tulang baru yang ditandai oleh struktur hirarkis biomimetik. Hidroksiapatit (HA) merupakan bentuk mineral dari kalsium apatit yang terbentuk secara alami dengan formula Ca10(PO4)6(OH)2. Salah satu inovasi besar dalam bidang rekonstruksi tulang adalah mengaplikasikan HA sebagai lapisan permukaan pada logam implan yang kuat secara mekanik dan dapat meningkatkan kestabilan implan pada tulang sehingga meningkatkan umur pemakaian implan logam. Pembuatan implan tulang menggunakan rotan sebagai subtitut logam dilakukan dengan bebeapa tahap yaitu pirolisis, karburisasi, oksidasi, karbonisasi dan tahap terakhir pembentukan senyawa hidroksiapatit dengan cara phospatisasi. Analisa karakteristik produk yang dihasilkan adalah dengan beberapa uji diantaranya SEM, XRD, Densitas, Porositas dan Uji Kuat Tekan.
Exploring the potential of fermented papaya as a functional ingredient for sourdough bread: a study on fermentation time and quality of sourdough donuts Anisa Mutamima; Ahmad Fadli; Indra Purnama; Yelmida Azis; Muhammad Syafiq Izzuddin
Jurnal Ilmiah Pertanian Vol. 20 No. 1 (2023): Jurnal Ilmiah Pertanian
Publisher : Universitas Lancang Kuning

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31849/jip.v20i1.13064

Abstract

Sourdough bread is known to have health benefits due to its fermentation process using lactic acid and wild yeast. It can improve the taste, texture, shelf life, and nutritional content of bread as a functional food. In this study, sourdough was made from fermented papaya with varying fermentation times of 4, 5, and 6 days. The substrate was fed five times to strengthen the sourdough, resulting in a robust enough mixture to develop the dough. The resulting sourdough was used to create sourdough bread with a 30% sourdough concentration. The fermentation time impacted the quality of the sourdough, with results showing that sourdough became increasingly active as fermentation time progressed. The best sourdough was obtained from a six-day fermentation period, with a pH of 3.60 and a total plate count of 1.70 × 104 CFU/ml. The best donuts were produced using the sourdough that had been fermented for six days, with an almost perfect score of 3.9 out of 4 for all aspects, including color, aroma, taste, and texture. Using this sourdough resulted in a significantly longer shelf life; no mold appeared until the eighth day of storage at room temperature. The moisture content of the donuts was measured at 4.57%. This study demonstrates the potential benefits of using sourdough made from fermented papaya to improve the quality and shelf life of sourdough bread while also providing potential health benefits.
PERANCANGAN REAKTOR DAN PELATIHAN PEMBUATAN ASAP CAIR SEBAGAI PENGAWET ALAMI DALAM PEMBUATAN BAKSO Cory Dian Alfarisi; Sunarno Sunarno; Anisa Mutamima; Ahmad Fadli; Silvia Reni Yenti; Wisrayetti Wisrayetti
JMM (Jurnal Masyarakat Mandiri) Vol 7, No 5 (2023): Oktober
Publisher : Universitas Muhammadiyah Mataram

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31764/jmm.v7i5.17414

Abstract

Abstrak: Yayasan Al-Ikhwan yang berlokasi di Kelurahan Tangkerang Timur Pekanbaru merupakan sebuah yayasan yang secara aktif terlibat dalam proyek-proyek sosial, pendidikan, pemberdayaan ekonomi, budaya, dan kesehatan masyarakat. Yayasan ini membawahi berbagai unit operasi, termasuk unit usaha bakso Al-Ikhwan, yang saat ini menghadapi keterbatasan kuantitas produksi dan area pemasaran karena masa simpan bakso yang singkat pada suhu ruang. Pada kegiatan pengabdian masyarakat ini, tim dosen Jurusan Teknik Kimia Universitas Riau bermitra dengan Yayasan Al-Anshar, khususnya unit usaha bakso Ikhwan yang dikolela oleh yayasan tersebut. Kegiatan ini berfokus pada pemberdayaan unit usaha dan berupaya mengatasi hambatan yang sedang dihadapi mitra dengan mengajarkan mitra bagaimana membuat asap cair dari tempurung kelapa, yang dapat digunakan sebagai pengawet alami dalam produksi bakso. Kegiatan ini meliputi beberapa tahap diantaranya; koordinasi dengan pihak terkait, desain dan pembuatan reaktor pirolisis, uji coba alat, edukasi tentang konsep asap cair, serta pelatihan mengenai penggunaan peralatan dan produksi asap cair. Kegiatan pengabdian ini memberikan pemahaman yang lebih baik kepada tim produksi tentang pilihan alami untuk produksi dan pengawetan bakso. Hasil positif yang diperoleh dari kegiatan ini diantaranya peningkatan pengetahuan mengenai asap cair sebagai pengawet alami dalam pembuatan bakso (75%), peningkatan keterampilan dalam pembuatan asap cair secara mandiri (62%), dan peningkatan kualitas (masa simpan) produk.Abstract: The Al-Ikhwan Foundation which is located in Tangkerang Timur Ward, Pekanbaru is an organization that actively involved in social, educational, economic empowerment, cultural, and public health projects. Under its purview, various business units operate, including the Al-Ikhwan meatball business, facing production and market limitations due to the short shelf life of meatballs at room temperature. This activity focuses on empowering the business unit and addressing the challenges faced by the partner by teaching them how to produce liquid smoke from coconut shells, which can be used as a natural preservative in meatball production. The involvement includes several phases; coordination with related parties, design and construction of the pyrolysis reactor, testing runs, education on liquid smoke concept, and instruction on how to use the equipment and produce liquid smoke. The project gives the production team better understanding of all-natural options for meatball production and preservation. Positive outcomes gained, include enhanced meatball production, longer shelf life, elevated quality, and food safety. Additionally, this project may be used as a model for other similar microenterprises, easing pressing manufacturing and marketing issues. Positive results obtained from this activity include an increased knowledge of liquid smoke as a natural preservative in meatball production (75%), improved skills in independently producing liquid smoke (62%), and an enhancement in product quality (shelf life).
Analisa Spesifikasi Fluff, Pellet, dan Bricket Pelepah Kelapa Sawit sebagai Biomassa Co-firing untuk Pembangkit Listrik Ari Aditia Sukma Sukma; Padil; Ahmad Fadli
Journal of Bioprocess, Chemical and Environmental Engineering Science Vol 4 No 1 (2023): Journal of Bioprocess, Chemical, and Environmental Engineering
Publisher : Jurusan Teknik Kimia, Fakultas Teknik, UNRI

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

The abundance of palm frond waste in Indonesia makes it an ideal source as co-firing material to increase renewable energy consumption. Therefore, it is necessary to determine whether oil palm fronds in the form of fluff, pellets, and brickets can be used as co-firing fuel. This study also aims to see whether there are differences in the potential of hard and soft palm fronds as solid fuel for power plants, as well as to calculate its slagging and fouling risk. Palm fronds was dried and reduced in sized using a wood chipper then sifted with a 20 mesh sieve to obtain palm frond fluff, then the fluff was mixed with 22% tapioca adhesive (weight ratio of 20% of the biomass) to be molded into pellet. Meanwhile, wood brickets was prepared by pyrolyzing the hard fronds (T= 550oC, t= 5 min) and mixing the charcoal obtained with 22% tapioca adhesive (weight ratio of 30% of the biomass). From the results of the analysis carried out, it is known that palm frond bricket provides the best results with an NCV value of 7095 cal/g. On the other side, both hard frond fluff and soft frond fluff contains the same sulfur content (0.06%), thus the difference in using hard or soft fronds as co-firing fuel does not have much effect. Furthermore, based on the analysis of potential slagging and fouling, all types of oil palm frond samples studied are shown to have a low to medium risk level.
Modifikasi Kitosan dari Limbah Udang menggunakan Metode Gelasi Ionik Nurfatihayati Nurfatihayati; Ahmad Fadli; Sunarno Sunarno; Allailus Syah Safara; Aulia Permatasari
Journal of Bioprocess, Chemical and Environmental Engineering Science Vol 4 No 1 (2023): Journal of Bioprocess, Chemical, and Environmental Engineering
Publisher : Jurusan Teknik Kimia, Fakultas Teknik, UNRI

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Abstract

Chitin contained in shrimp shells can be used as raw material for making chitosan which is then reprocessed into nanoparticle-sized chitosan which has many benefits. This study aims to synthesize nanoparticle chitosan using the ionic gelation method and determine the effect of variations in the concentration of formic acid, sodium tripolyphosphate (TPP), chitosan, and the volume ratio of chitosan: TPP on particle characteristics, which include particle size, polydispersity index, zeta potential, particle morphology, and functional groups of particles. The first step for making nanoparticle chitosan is to make a chitosan solution using a magnetic stirrer. After that, the TPP solution at a certain volume ratio between chitosan: TPP was added to the chitosan solution. Stirring is carried out for 1 hour with a stirring speed of 1200 rpm. Furthermore, the nanoparticle chitosan was characterized by using Particle Size Analyzer (PSA), zeta potential analyzer, Scanning Electron Microscopy (SEM), and Fourier Transform Infra-Red (FTIR). The synthesis of nanoparticle chitosan using the ionic gelation method has been successfully carried out, obtaining a particle size of 464.4 nm, a polydispersity index of 0.214, a zeta potential of +0.48, and a cross-link of chitosan-TPP particles is formed.
Pengaruh Penambahan Akuades Terhadap Lapisan Hidroksiapatit Pada Permukaan Logam Ines Indriyani; Komalasari Komalasari; Ahmad Fadli
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 6 (2019): Edisi 2 Juli s/d Desember 2019
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Abstract

316L stainless steel is a material that can be used as an implant because it has strong mechanical properties but does not have bioactive properties so it needs to be coated with hydroxyapatiteon the surface of 316L stainless steel. The aim of the study was to determine the effect of weight ratio of hydroxyapatite and distilled water to the thickness of the hydroxyapatite layer. The method used in the study starts from the preparation of the dipping solution then the substrate was installed in the dip coating unit and the dipping processbegins. The fixed variables used in this research are the amount of HAp weight that is 12 grams, the stirring time is 20 hours, and the sintering time is 1 hour. While the changeable variables used in this study are the amount of aquades by 24 and 28 grams. Parameters has a significant effect on layer coating thickness which gives 29,6% change in the thickness of the HAp layer. The more addition of distilled water to the coating solution, the thickness of the HAp layer decreases and vice versa.Keywords : dip coating, hydroxyapatite, implan, steel
Co-Authors Abdul Rasyid Achmad Noerkhaerin Putra Ade Pratama Adela Shofia Addabsi Adha Widoni Adi Maulana Putra Adi Mulyadi Putra Adrianto Ahmad Afrila Afrila Agung Prabowo Agung Prabowo Agung Prabowo Agung Prabowo Ahmad Riadi S Hasibuan Ahmad Zaki Alfarisi, Cory Dian Allailus Syah Safara Allailus Syah Safara Alltop Amri Ya Habib Amun Amri Annisa Aprilya Putri Annisa Rahmat Ari Aditia Sukma Sukma Arisman Adnan Ariya Eka Alel Arosyidin Arosyidin Aulia Permatasari Aulia Permatasari Bahruddin Bahruddin Benny Ahmadi Bima Wandika Putra Charismayani Charismayani Damayanti, Elok Debora Tambunan Deden Saprudin Deni Astika Deni Noviana Derry Hanriansyah Pratama Deska Deska Dewi Indah Pratiwi Dhamala Shobita Chandra Dhanang Hayuningwang Dion Julio Iskandar Dovy Reyandi Drastinawati Drastinawati Drastinawati Drastinawati Dwi Yerlis Rahmi Edy Saputra Ervina Ervina Esty Octiana Sari Esty Octiana Sari Fachry Abda El Rahman Fadhil Mubarak Fajril ' Akbar Fajril Akbar Feblil Huda Ferdy Ashari Syawal Fernando Susilo Gading Bagus Mahardika Gede Indra Ludy Wirata Heni ' Ismawati Heni Ismawati Heni Sugesti Herry Novriansyah Idral Amri Ika Karina Ilham Habib Indah Fitriani Indra Purnama Indra Yasri Ines Indriyani Irdoni HS Irdoni Irdoni Iwantono Iwan Barnawi Jabosar Ronggur Hamonangan Panjaitan Jenial S Julharmito Julharmito Komalasari Komalasari Lia Yuningsih Lilis Suriani Luci Octaria M Satria Haruda Marlinda MAYANG SARI Mayangsari Mayangsari Melda Helena S Miftah Anugrah Mochamad Reizal Ath Thariq Muchlis Ade Putra Muh Irwan Muhamamad Rizky Zuriadi Muhammad Hamdani Muhammad Reski Muhammad Syafiq Izzuddin Mustika Canra Mutamima, Anisa Nisa Mulya Nissa Aqhilla Novika Sri Wardani Nuraina Siregar Nurfajriani Nurfajriani Nurfatihayati Nursyaniati Nursyaniati Nurul Afifah Ongky Alexander Ongky Alexander Padil Padil Panca Setia Utama Pancasila Putri Peter Peter Prihartini Widiyanti Putri Arini Putri Rahmadani Rahimah Rahimah Rahmad Rasyidin Rani Handayani Rathesa Najela Rawdatul Fadila Ridho Wijaya Riki Rahmadhan Rio Andika Ririn Puji Hastuti Rozanna Sri Irianty Rusydy Rusydy ' Septiana Veronika S Silvia Reni Renti Silvia Reni Yenti Silvia Reni Yenti Silvia Reni Yenti Silvia Reni Yenty Siska Priscillia Aledya Siti Chotijah Sri Murda Niati Sri Murda Niati Subkhan Maulana Suhendri Sukoco Sukoco Sukoco Sukoco Sunarno Sunarno Sunarno Sunarno Syarifuddin Oko Syelvia Renni Yenti Thomson Simanjuntak Toni Ardi Ulfah Naida Marbun Wan Elsa Novtari Adiani Wasty Rusjaya Wilda Zakiah Wiriyan Jordy Wisrayetti Wisrayetti Wisrayetti Wisrayetti Wisrayetti Wisrayetti Wyda N Saragi Yelmida Azis Yelmida Aziz Yesi Afriani Yogi Yolanda Yunus Olivia Novanto Zakwan Zuchra Helwani Zultiniar Zultiniar Zultiniar Zultiniar Zultiniar Zultiniar