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Effect of Adding PVA to The Size of Silver Nanoparticle Synthesized Using Bioreductor Soursop Leaf Extract (Annona muricata L.) Dewi Rahmadani; Sumiati Side; Suriati Eka Putri
SAINSMAT: Jurnal Ilmiah Ilmu Pengetahuan Alam Vol. 9 No. 1 (2020): Volume 9 Nomor 1 (Maret 2021)
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Negeri Makassar

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Abstract

This study aims to determine the effect of adding Polyvinyl Alcohol (PVA) to the size of silver nanoparticle synthesized using bioreductor soursop leaf extract (Annona muricata L.). Silver nanoparticle made through method bioreduction, bioreductor solution was mixed with AgNO3 precursor, without addition of PVA and with the addition of PVA. That the variant of concentrations is 1%; 1.5%; 2%; and 2.5%. Based on the analysis of functional groups of soursop leaf extract using a spectrophotometer FT-IR (Fourier Transform Infrared), showed absorption at wave number 3443 cm-1 which indicate a -OH group.The process of formation of silver nanoparticles seen by UV-Vis absorption. The measurement results shows that the absorbance value increased with increasing contact time. The maximum absorbance measurement result of the samples synthesized each concentration showed λmax 503.0; 463.1; 436.0; 476.1; 503.1 nm for two days with various concentrations without PVA, 1%, 1.5%, 2%, and 2.5%. The size of silver nanoparticle were determined using XRD (X-Ray Diffraction), the average size distribution of silver nanoparticle without the addition of PVA is 30.80- 50.25 nm and the smallest size range is 9.90-10.20 nm silver nanoparticle with addition PVA 1.5%. Based on research that has been done, it can concluded that addition of PVA have the effect to the size of silver nanoparticle. The stabilizer acts to control the size of silver nanoparticle.
Analysis of Metal Oxide on Natural Zeolite of South Sulawesi Activated Hydrochloric Acid Suriati Eka Putri; Sumiati Side
SAINSMAT: Jurnal Ilmiah Ilmu Pengetahuan Alam Vol. 9 No. 2 (2020): Volume 9 Nomor 2 (September 2020)
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Negeri Makassar

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Abstract

This study aims to determine the metal oxide content of natural zeolite before being activated and after being activated. The activator used was hydrochloric acid6 M. Analysis of metal oxide content was carried out using the X-Ray Fluoresence (XRF) instrument. The results showed that there was a decrease in impurity levels after the zeolite was activated by acid. The content of Al2O3; SiO2; K2O and CaObefore activation were 2.15%; 86.34%; 4.32%; and 2.54% respectively, while after activation were 2.11%; 86.40%; 4.56%; and 2.78%respectively. The content of other metal oxides (impurity) generally decreases in levels after the zeolite is activated.
Sintesis Nanokitosan dari Limbah Kulit Udang Windu (Panaeus monodon) Isna Sejati Syam; Hasri Hasri; Suriati Eka Putri
SAINSMAT: Jurnal Ilmiah Ilmu Pengetahuan Alam Vol. 11 No. 1 (2022): Volume 11 Nomor 1 (Maret 2022)
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Negeri Makassar

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This study aims to determine the characteristics of nanochitosansynthesized from chitosan from tiger prawn shells (Panaeus monodon) using sonochemical and ionic gelation methods based on variations in chitosan concentration. The characterization of nanochitosan includedthe degree of distillation using FTIR, particle size using PSA, and morphology testing using SEM. The results showed that the chitosan obtained had a degree of deacylation of 81.23%. The average size of the smallest nanochitosan synthesized using the sonochemical method is 54.44 nm with 0.2% chitosan concentration, while that produced using the ionic gelation method is 39.65 nm with 0.05% chitosan concentration, and there is a pore appearance on the surface. nanochitosan surface. Based on these data, it can be concluded that the ionic gelation method produces a smaller average nanochitosan particle size than the sonochemical method.
Microstructure Investigations of Natural Clay From Pattallassang District, Takalar Regency, South Sulawesi Province, Indonesia Abd Rahman; Suriati Eka Putri; Diana Eka Pratiwi; Satria Putra Jaya
SAINSMAT: Jurnal Ilmiah Ilmu Pengetahuan Alam Vol. 12 No. 1 (2023): Volume 12 Nomor 1 (Maret 2023)
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Negeri Makassar

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Abstract

The study aimed to investigate the microstructure of natural clay from Pattallassang District, Takalar Regency, South Sulawesi Province. The clay was characterized using X-ray diffractometer (XRD), surface area analyzer (SAA), and scanning electron microscope (SEM). The XRD analysis showed that the main mineral composition of the clay was kaolinite, quartz, hematite, geothite, magnetite, and anatase phases. The SAA using BET analysis shows the large surface area of 59.26 m2/g and BJH analysis for pore distribution of 32.77 nm. SEM observations revealed that the clay consists of plate-like kaolinite particles arranged randomly. The results indicate that the natural clay from Pattallassang District has good potential for use in various industrial applications due to its high kaolinite content and favorable microstructure.
The Effect of Acid Treatment on The Characteristics of Modernite Zeolite Sumiati Side; Suriati Eka Putri; Diana Eka Pratiwi; Aulia Rahma; Abd Rahman
SAINSMAT: Jurnal Ilmiah Ilmu Pengetahuan Alam Vol. 12 No. 2 (2023): Volume 12 Nomor 2 (September 2023)
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Negeri Makassar

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This work investigated the use of acid treatment on the characteristics of zeolite mineral. The effects of treating zeolite with various acid solutions hydrochloric acid (HCl) and sulfuric acid (H2SO4) were measured using x-ray fluorescence (XRF), x-ray diffraction (XRD), and scanning electron microscope (SEM). The results showed an increase in the percentage of SiO2 and Al2O3 after zeolite activation, and also a decrease in the amount of impurities. The crystalline phase of the zeolite was carried out using XRD analysis, indicating the type of zeolite used is modernite. The SiO2 phase in the sample is quartz, and the Al2O3 phase is corundum. The average crystal size decreased after activation, from 14.23 nm to 6.85 nm for HCl and 5.42 nm for H2SO4. Furthermore, the surface morphology of all zeolite samples has a form of irregular spherical surface, and the surface size of the particles after activation shows a smaller particle shape. The results of this study are expected to become recommendations for further research related to natural zeolite pretreatment as a catalyst support.
Adsorption Kinetics of Cd(II) From Aqueous Solution Using Surfactant Modified Activated Carbon-Sodium Lauryl Sulphate (SMAC-SLS) Sumiati Side; Suriati Eka Putri; Rini Perdana; Abd. Rahman
SAINSMAT: Jurnal Ilmiah Ilmu Pengetahuan Alam Vol. 13 No. 2 (2024): Volume 13 Nomor 2 (September 2024)
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Negeri Makassar

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The purpose of this study was to determine the adsorption kinetic model of Cd(II) from aqueous solution using Surfactant Modified Activated Carbon-Sodium Lauryl Sulphate (SMAC-SLS). This study began by varying pH, contact time, and adsorbate concentration. The concentration of Cd(II) was measured using a spectrophotometric method. The results of the analysis showed that the optimum pH occurred at pH 5 with an adsorption percentage of 84.58±1.44% and the optimum contact time at 100 minutes with an adsorption percentage of 88.75±1.5%. Furthermore, in the variation of adsorbate concentration, the adsorption percentage decreased with increasing adsorbate concentration. The adsorption kinetics followed a pseudo second order with an R2 value of 0.9945 with an adsorption capacity of 8.89 mg/g. Thus, the use of SMAC-SLS as a future adsorbent for Cd(II) is highly recommended.
KINETICS PHOTODEGRADATION OF METHYLENE BLUE DYE USING ZNO-MONTMORILLONITE COMPOSITE Suriati Eka Putri; Diana Eka Pratiwi; Tiara Anugrah Ria; Abd Rahman; Shoira Shukurovna Abdiyeva
SAINSMAT: Jurnal Ilmiah Ilmu Pengetahuan Alam Vol. 14 No. 2 (2025): Volume 14 Nomor 2 (September 2025)
Publisher : Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Negeri Makassar

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.35580/sainsmat142761972025

Abstract

The purpose of this study was to determine the degradation kinetics of methylene blue dyes using ZnO-Montmorillonite (MMT) composites. This study is an experimental research covering several stages, namely the preparation and purification of MMT samples, the synthesis of ZnO-MMT composites by impregnation method, the characterization of ZnO-MMT composites, and the determination of optimal conditions for the degradation of methylene blue (MB) dyes using the UV-Vis instrument. The results of the ZnO-MMT composite research were able to degrade MB dyes irradiated by UV light with an optimal time of 150 minutes with a photodegradation rate of 4.199 minutes-1
Adsorpsi Logam Cu(II) menggunakan Actived Carbon-Sodium Lauryl Sulphate (AC-SLS) dari Kulit Kacang Tanah Mega Putri Aulia; Maryono Maryono Maryono; Suriati Eka Putri
Chemica: Jurnal Ilmiah Kimia dan Pendidikan Kimia Vol 26, No 2 (2025): CHEMICA
Publisher : Jurusan Kimia FMIPA UNM

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.35580/chemica.v26i2.53666

Abstract

Salah satu upaya yang dapat dilakukan untuk meningkatkan proses adsorpsi adalah dengan melakukan modifikasi kimia karbon aktif. Modifikasi karbon aktif dengan menggunakan surfaktan sodium laurly sulphate (SLS) dapat meningkatkan kemampuan daya serap terhadap logam Cu(II). Tujuan penelitian adalah mengetahui kondisi optimum adsoprsi logam Cu(II) menggunakan Actived Carbon-Sodium Lauryl Sulphate (AC-SLS). Serta mengetahui model isoterm adsorpsi dan kinetika adsorpsi logam Cu(II) menggunakan Actived Carbon-Sodium Lauryl Sulphate (AC-SLS). Penentuan kondisi optimun yang dilakukan adalah penentuan pH, Waktu adsorpsi, Kinetika Adsorpsi, Isoterm Adsorpsi, dan Uji efektivitas adsorpsi. Pengukuran konsentrasi Cu(II) menggunakan instrumen Atomic Absorption Spectrophotometer (SSA). Analisis pengaruh masing-masing perlakuan menggunakan uji ANOVA. Hasil penelitian menunjukkan Actived Carbon-Sodium Lauryl Sulphate (AC-SLS) mampu mengadsorpsi logam Cu(II) dengan pH optimum 5 dan waktu optimum 45 menit dengan persentase daya serap sebesar 88,33% dengan SLS mengikuti pola isoterm adsorpsi Langmuir dengan nilai R2 yaitu 0,9813 dan mengikuti pseudo orde dua dengan nilai R2 yaitu 0,9713 .One of the efforts that can be made to improve the adsorption process is to carry out chemical modification of activated carbon. Modification of activated carbon using sodium laurly sulphate (SLS) surfactant can increase the ability to absorb Cu(II) metal. The purpose of this research is to determine the optimum conditions for adsorption of Cu(II) metal using Actived Carbon-Sodium Lauryl Sulphate (AC-SLS). And to know the adsorption isotherm model and adsorption kinetics of Cu(II) metal using Actived Carbon-Sodium Lauryl Sulphate (AC-SLS). Determination of optimized conditions carried out is the determination of pH, adsorption time, adsorption kinetics, adsorption isotherm, and adsorption effectiveness test. Measurement of Cu(II) concentration using Atomic Absorption Spectrophotometer (SSA) instrument. Analysis of the effect of each treatment using ANOVA test. The results showed that Actived Carbon-Sodium Lauryl Sulphate (AC-SLS) was able to adsorb Cu(II) metal with an optimum pH of 5 and an optimum time of 45 minutes with a percentage of absorption of 88.33% with SLS following the Langmuir adsorption isotherm pattern with an R2 value of 0.9813 and following the second-order pseudo with an R2 value of 0.9713
Co-Authors A. Irma Suryani Abd Rahman Abd Rahman Abd Rahman Abd Rahman Abd. Rahman Abd. Rahman Abd. Rahman Abd. Rahman Abd. Rahman Abdul Karim Abdul Rahman Achmad Fudhail Ahmad Fudhail Majid Ahmad Fudhail  Majid Ahyar Ahmad Ahyar Ahmad Ahyar Ahmad Alimin Alimin Alimin Alimin Alimin Andi Erwin Eka Putra Andi Indra Wulan Sari Ramadani Angriyani Ahmad Anita Anita Anwar, Fadil Arfah, Rugaiyah Andi Astri Wiyani GM Astriana Dewi Aulia Rahma Aulia Rahma Bunyamin, Andi Bulqiah Nur Dahlang Tahir daya, Nurhidaya Dewi Rahmadani Dewi Rahmadani Dewiyanti Fadly Diana Eka Pratiwi Diana Eka Pratiwi Diana Eka Pratiwi Diana Eka Pratiwi Diana Eka Pratiwi Diana Eka Pratiwi Diana Eka Putri Dipo Ade Putra Iskandar Djangi, Muh. Jasri Elfira Jumrah Elfira Jumrah Ganing, Melani Hapzi Ali Hardin hardin hardin Harningsih Karim Harningsih Karim Hartati Hartati Hartati, Hartati Hasnah Natsir Hasri Hasri Hasri Hasri Hasri Hasri Hasri Hasri Hasri Hasri Hasri Hasri Umas Heryanto Heryanto Ilyas, Nita Magfirah Ilyas, Nita Maghfirah Indah Raya Irfandi, Rizal Isna Sejati Sam Isna Sejati Syam Juintan Pratiwi Jusniar Magfirah Ilyas, Nita Marlina Ummas Genisa Maryono Maryono Maryono Maryono Maryono Mazaya, Maulida Mega Putri Aulia Miftahul Jannah Mohammad Wijaya Mohammad WIJAYA Mohammad wijaya Muhammad Danial Muhammad Ilham Wardhana Haeruddin Muhammad Iskandar Musa Muhammad Iskandar Musa Muhammad Nur Alam Muhammad Syahrir Muhammad Taufiq Munawwarah Munawwarah Munawwarah Munawwarah Munawwarah, Munawwarah Musdalifah Musdalifah Mutahharah Hasyim, Mutahharah Negara, Satria Putra Jaya Netti Herawati Nilasari Nilasari Nilasari Nilasari Nilasari, Nilasari Nita Magfirah Ilyas Nita Magfirah Ilyas Nita Magfirah Ilyas Nita Magfirah Ilyas Nita Magfirah Ilyas Nita Magfirah Ilyas Nur Afni Nur Riska Nurfadilah Adam Nursafitri Nursafitri Paulina Taba Paulina Taba Pince Salempa Rachmat Triandi Tjahjanto Rachmat Triandi Tjahjanto Rachmawaty, Rachmawaty Rahim, Mega Putri Aulia Ramadani, Ananda Ramdani Ramdani Ramdani Ramdani Ria, Tiara Anugrah Rial Tangaran Riksfardini Annisa ERMAWAR Rini Perdana Rini Perdana Rismawati Rismawati Rismawati Rismawati Rosmala Rauf Sahribulan Sahribulan Sarlan, Sarlan Satria Putra Jaya Satria Putra Jaya Shoira Shukurovna Abdiyeva SITI HALIMAH LAREKENG, SITI HALIMAH Sitti Faika Sri Diana Sudding Suleman, Annisa Inayah Sumiati Side Sumiati Side Sumiati Side Sumiati Side Sumiati Side Sumiati Side Sumiati Side Sumiati Side Susilo Sudarman Desa Syafaatullah, Achmad Qodim Syamsidah Tiara Anugrah Ria Widya Faramitha Arisma Wijaya, Khalida Yunanda FR Yunanda Yunanda Zakinah, Ilmiati Zubair, Sakinah