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Journal : Jurnal Natural

PRELIMINARY STUDIES OF SYNTHESIS POLYURETHANE MEMBRANE OF NYAMPLUNG SEED OIL (Calophyllum inophyllum) WITH HEXAMETHILENE-1,6-DIISOCYANATE (HMDI) Mutia Farida; Mustanir Yahya; Marlina Marlina
Jurnal Natural Volume 16, Number 2, September 2016
Publisher : Universitas Syiah Kuala

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (62.201 KB) | DOI: 10.24815/jn.v16i2.4920

Abstract

Nyamplung oil originated from Ujong Pancu, Aceh Besar is one of the vegetable oil sources which is not fully utilized yet. The extraction of nyamplung oil is done using soxhletation with n-hexane solvent; during this process, the oils produced is at the 55.55% levels. The product is in the form of yellowish green liquid with the density of 0.88gr/ml. The nyamplung oil extract has the iodine number of iod 83.53 mg iod/g and hydroxyl number of  64.292 mg KOH/gram which can be utilized as the raw material in making polyurethane membrane. Polyurethane membrane is synthesized by reacting fatty acids from nyamplung seed oil with hexamethylene-1.6-diisocyanate (HDMI). The ration of the oil towards HDMI is variated as, 5:1;5:3;5:5;5:7;5:9 v/w. The membrane has a composition of  5:7 v/w  with 90-100 oC polymerization temperatures and  160oC curring temperature for 8 hours is hard, homogenous and quite elastic with a transparent brown colour. 
SINTESIS MEMBRAN POLIURETAN BERBASIS MINYAK BIJI ALPUKAT (Avocado Seed Oil) DAN HEKSAMETILEN-1,6-DIISOSIANAT (HMDI) Fitriani Fitriani; Marlina Marlina; Khairan Khairan
Jurnal Natural Volume 16, Number 2, September 2016
Publisher : Universitas Syiah Kuala

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (137.304 KB) | DOI: 10.24815/jn.v16i2.5126

Abstract

This research aims to synthesize polyurethane membrace from avocado seed oil as a source of hydrixyl (-OH) and hexametylhene -1.6-dissocyanate (HDMI) as a source of isocynate (-NCO). The oil were extracted from avocado seeds at temperature of  60-80oC for 2 hours using n-hexane solvent. The results of FTIR spectrum analysis from avocado seed oil showed that there were -OH clusters absorption on the wavelength number of 3393.819 cm-1, thus this oil can be used to synthesize polyurethane membrane. The isocyanate composition, time and temperature during synthesis process of polyurethane membrane were varied. The polyurethane membrane were moulded in petri dishes, then heated up for 48 hours on the temperature of  70oC, and finally taken out from its mould. The characteristics of the polyurethane membrane from avocado seed oil are brown in colour, homogenous, elastic, solid, transparent and shaped like a membrane. The measurements from FTIR spectrum showed that the -NCO clusters are no longer present. This condition happened because there were no more absorption in the wavelength number of  2270 cm-1 . It can be concluded that the isocyanate has completely reacted during polymerization and the curing process, thus urethane was created in the 1699,965 cm-1 absorption which was the urethane C=O clusters absorption.
PRELIMINARY STUDIES OF SYNTHESIS POLYURETHANE MEMBRANE OF NYAMPLUNG SEED OIL (Calophyllum inophyllum) WITH HEXAMETHILENE-1,6-DIISOCYANATE (HMDI) Mutia Farida; Mustanir Yahya; Marlina Marlina
Jurnal Natural Volume 16, Number 2, September 2016
Publisher : Universitas Syiah Kuala

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24815/jn.v16i2.4920

Abstract

Nyamplung oil originated from Ujong Pancu, Aceh Besar is one of the vegetable oil sources which is not fully utilized yet. The extraction of nyamplung oil is done using soxhletation with n-hexane solvent; during this process, the oils produced is at the 55.55% levels. The product is in the form of yellowish green liquid with the density of 0.88gr/ml. The nyamplung oil extract has the iodine number of iod 83.53 mg iod/g and hydroxyl number of  64.292 mg KOH/gram which can be utilized as the raw material in making polyurethane membrane. Polyurethane membrane is synthesized by reacting fatty acids from nyamplung seed oil with hexamethylene-1.6-diisocyanate (HDMI). The ration of the oil towards HDMI is variated as, 5:1;5:3;5:5;5:7;5:9 v/w. The membrane has a composition of  5:7 v/w  with 90-100 oC polymerization temperatures and  160oC curring temperature for 8 hours is hard, homogenous and quite elastic with a transparent brown colour. 
SINTESIS MEMBRAN POLIURETAN BERBASIS MINYAK BIJI ALPUKAT (Avocado Seed Oil) DAN HEKSAMETILEN-1,6-DIISOSIANAT (HMDI) Fitriani Fitriani; Marlina Marlina; Khairan Khairan
Jurnal Natural Volume 16, Number 2, September 2016
Publisher : Universitas Syiah Kuala

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24815/jn.v16i2.5126

Abstract

This research aims to synthesize polyurethane membrace from avocado seed oil as a source of hydrixyl (-OH) and hexametylhene -1.6-dissocyanate (HDMI) as a source of isocynate (-NCO). The oil were extracted from avocado seeds at temperature of  60-80oC for 2 hours using n-hexane solvent. The results of FTIR spectrum analysis from avocado seed oil showed that there were -OH clusters absorption on the wavelength number of 3393.819 cm-1, thus this oil can be used to synthesize polyurethane membrane. The isocyanate composition, time and temperature during synthesis process of polyurethane membrane were varied. The polyurethane membrane were moulded in petri dishes, then heated up for 48 hours on the temperature of  70oC, and finally taken out from its mould. The characteristics of the polyurethane membrane from avocado seed oil are brown in colour, homogenous, elastic, solid, transparent and shaped like a membrane. The measurements from FTIR spectrum showed that the -NCO clusters are no longer present. This condition happened because there were no more absorption in the wavelength number of  2270 cm-1 . It can be concluded that the isocyanate has completely reacted during polymerization and the curing process, thus urethane was created in the 1699,965 cm-1 absorption which was the urethane C=O clusters absorption.
Co-Authors A Halim Abda Abda Abdul Gani ABDUL GANI Abul Khair Ade Khadijatul Z. Hrp Ahmad Taufiq Harahap Aidil Amar Akor Sitepu Alfatih S. Manggabarani Alfatih S.M Alfatih S.M Alfizar Alfizar Aliman Aliman Alvi Syahrin Alvi Syahrin Anda Syahputra Andi Elis Andri Afriansyah Anggara Faisal Ani Sutriningsih Antoni Simanjuntak Ari Ade Bram Manalu Arief Hidayat Arif Arif Arifuddin Arifuddin Arisul Mahdi Armaini Armaini Asdiana Asdiana Asni Deselia Khairunnisa Azuar Anas Badriani Badawi Bebi Sindi Putra Bertha Alan Manuel Brury Prisma Bustanur, Bustanur Cakrawati Cakrawati Cinthia Mutiara Hapsari Dearman Saragih Dedi Harianto Denny setiawan DESI MARIAYU SIREGAR Dewi Laraswati Diah Fridayati Diana Diana Dini Wahyuni Harahap Dt Ananda Farkhie Edi Yunara Ediwarman Ediwarman Edy Ikhsan Edy Junianto Edy Yunara Eka Hariyani Eka Rahmi Eldi Yudianto Elsa Yuniarti Elvi Zahara Enas Enas Enny Lestari Erico Syanli Putra Eva Nelli Eva Sitindaon Evanirosa Evanirosa faidir faidir Fatmawati Fatmawati FAUZAN AKMAL AKMAL Fauzul Hamdi Lubis Febry Ramadhan Felix Christian Jonathan Ferdian Ade Cecar Tarigan Fikri Prabowo Fikrinda Fikrinda Fitra Gustiar, Fitra Fitriani Fitriani Floransya Dwi Ganda Sumekar Grahita Kusumastuti, Grahita Hadi Projo Sinaga Hajidin Hajidin Hambali Hambali Hanif Zehra Mohara Heru Sulistianta Husni Watul Hasanah Ibnu Khaldun Ida Anggriani Indarti Indra Kurniawan Indrawan Ardi Irma Bastaman Ismawati Ismawati Isnaini Isnaini Jamal Jamal Jon Efendi Joni Prihatin Juhandi, Nendi Kadarisman Kadarisman Kamaliah Kamaliah KARDOPA NABABAN Khairan Khairan Khairi Rahmi Khairul Anwar Hasibuan Khairul Khairul Khairuna Khairuna Komeyni Rusba Kristina Sitanggang Kustiawan Kustiawan Kuswanto Kuswanto Lia Nurlaila Liza erwina Lukman Hakim Luthfiani Hardyanti Moinori M. Ikhsan M.Wirawan Saputra Madiasa Ablisar Mahmud Mulyadi Mahmul Siregar Manap Somantri Maria Fitriana Mariana Mariana Marissa Hutabarat Marudut Hutajulu Maslina Maslina Maslina Maslina Mastutiniyah Mastutiniyah Maya Novira MB Nani Ariani Meilia Safri Meliasta Julin M Mhd Nuh Michael Simbolon Miftah, Munasiron Miftakul Munir Moh. Hatta Mohammad Eka Muhammad Ekaputra Muhammad Hamdan Muhammad Sayuthi Mustanir Yahya Mustoip, Sofyan Mutia Farida Nelfa Yosi Nelvia Nelvia Nisfayati Juir Nofdi Rahmat Amda NONI DWI SARI Nurhafidhah Nurhafidhah Nurjana Nuraita Nurlaela Mei Tienje Nurmala Waty Nurmalawaty Nurmalawaty Odelia Yulita Oscar Karnalim, Oscar Oscar Wongso Prinst Rayenda Putra Wisnu Putri Gusmarini Rachmat Aribowo Rafiqoh lubis Rahmaeni Zebua Rahmat Rahmat Rahmawati Rarussyamsu Rahmi Rahmi Rahmi, Rahmi Raja wahid Nur Sinambela Ratih Intan Gayatri RAVEINAL RAVEINAL Ringga Novelni Rini Fitriani Risca Ardilla Rozel Ristiono Ristiono Rita Retnowati Rohani Mustari Safrina Junita Samuel F Nainggolan Samuel Pangaribuan Saniah, Nur Sanisah Sanisah SATRIYAS ILYAS Septia Maulid Seri Yanti Serlis Mawarni SILVIE YOELANDA PRATIWI PRATIWI Siti Mariam Solissa, Everhard Markiano Sri Adelila Sari SRI LESTARI Sri Mudayati Sunarmi, Sunarmi Suwardi Lubis Syafruddin Hasibuan Syafruddin Kalo Syafruddin Syafruddin Syahabuddin Syahabuddin Sylvia Sinuhaji Teguh Achadi Teoli Bewamati Telaumbanua Tika Hendrawati Triana Putrie Vinansari Vincent Elbert Budiman Wajnah Wajnah Wessy Trisna Widya Mulya Wisman Goklas Yeni Irawan Yuniawati Kencanasari Yustika Dwi Novia Zainul, L.M. Zainul Zhafira Aini Zuhriyati Yati Zulhaini Zulhaini