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ISOLATION OF CHEMICAL ACTIVE COMPOUNDS ANTIOXIDANT FROM ETHYL ACETATE FRACTION OF BETEL LEAF FOREST (Piper aduncum L.) Batan, Alfrida; Daniel, Daniel; Simanjuntak, Partomuan
JURNAL ATOMIK Vol 3 No 2 (2018)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

Research about the isolation of chemical active compounds antioxidants from ethyl acetate fraction of betel leaf forest (Piper aduncum L.) have been done. This research aimed to determine the type of secondary metabolites that contained in ethyl acetate fraction and the value of antioxidant activity as well as the structure that contained in ethyl acetate fraction. The test results of phytochemical showed that the secondary metabolites in ethanol extract are alkaloids, steroids and triterpenoids. The inhibitory concentration 50% (IC50) value that shown in the fraction Piper aduncum ethyl acetate-4-3 (PAEA-4-3) is 132.84 ppm. Fraction of PAEA-4-3 that have high levels of antioxidant activity was analyzed using a spectrophotometer Ultra Violet-Visible (UV-Vis), Infrared Fourier-Transform (FTIR) and Nuclear Magnetic Resonance (NMR) proton and carbon. The result analysis of PAEA-4-3 isolates showed the compound as 2,3-dimethoxy-metilanaoksi-benzene.
UJI TOKSISITAS DAN SIFAT ALELOPATI EKSTRAK ALANG-ALANG (Imperata cylindrica) TERHADAP PERKECAMBAHAN BIJI PADI (Oryza sativa) Kurniati, Triani; Daniel, Daniel; Sudrajat, Sudrajat
JURNAL ATOMIK Vol 3 No 1 (2018)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

Penelitian inibertujuan untuk mengetahui toksisitas dan sifat alelopati ekstrak alang-alang (Imperata cylindrica) terhadap perkecambahan biji padi (Oriza sativa). Sampel kering akar alang-alang dari Kutai Lama dimaserasi menggunakan pelarut etanol dan di fraksinasi menggunakan pelarut n-heksana dan etil asetat. Sampel kemudian di Skrining fitokimia dan uji toksistas dengan metode (Brini Shrimp Lethality Test) BSLT. Fraksi yang menunjukkan nilai LC50 paling rendah kemudian diuji sifat alelopati dan dianalisis dengan GC-MS. Hasil uji skrining fitokimia menunjukkan adanya kandungan alkaloid, triterpenoid dan fenol. Hasil uji toksisitas dengan metode (Brini Shrimp Lethality Test) BSLT menunjukkan bahwa fraksi etanol memiliki toksisitas tertinggi pada larva udang dengan nilai LC50 sebesar 647,5364 ppm. Uji senyawa alelopati dari ekstrak alang-alang dilakukan pada biji padi (Oriza sativa) memiliki pengaruh nyata terhadap perkecambahan biji padi. Analisa kandungan senyawa kimia pada fraksi etanol dari akar alang-alang menghasilkan dua puncak komponen senyawa pada spektra massa yang ditunjukkan dari hasil GC-MS yaitu fenol dan tetradecamethylcycloheptasiloxane. Kata kunci : Alang-alang (Imperata cylindrica), Fitokimia, Toksisitas dan Sifat Alelopati Terhadap Biji Padi
PHYTOCHEMICAL TEST ON METHANOL EXTRACT OF LEAF OF Macaranga hullettii King ex Hook.f. Rismawati, Rismawati; Marliana, Eva; Daniel, Daniel
JURNAL ATOMIK Vol 3 No 2 (2018)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

Phytochemical test of Macaranga hullettii King ex Hook.f have been done. This research aims to find out the secondary metabolites using Thin Layer Chromatography (TLC) from methanol extract on Macaranga hullettii leaf. Based on results of phytochemical screening, it is known that methanol extract contains alkaloid, steroid/triterpenoid, polifenol and flavonoid compounds.
PHYTOCHEMICAL TEST, TOXICITY TESTS AND ANTIOXIDANT ACTIVITIES OF MAHOGANY SEEDS (Swietenia mahagoni (L) Jacq) Rindawati, Novi; Daniel, Daniel; Saleh, Chairul
JURNAL ATOMIK Vol 4 No 2 (2019)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

Phytochemical tests, toxicity tests and antioxidant activities of mahogany seeds (Swietenia mahagoni (L) Jacq) were carried out. This study is meant to identify the secondary metabolism, the LC50 and LC50 of extract of ethanol, n-hexane fraction, and ethyl acetate fraction with the seeds of (Swietenia mahagoni (L) Jacq). Phytochemical screening on ethanol extract of mahogany seeds showed the presence of alkaloids, flavonoids, triterpenoids and phenolic n-Hexane fraction contains alkaloids compounds, triterpenoid and phenolic compounds. Ethyl acetate fraction contains flavonoids, triterpenoids and phenolic compounds. The toxicity level is performed by tests of BSLT (Brine shrimp lethality test), while antioxidant activity is performed by a spectrofotometr uv-vis. The total extract of ethanol is obtained at the smallest amount of LC50 for 49.47565 ppm, n-Hexane fractions obtained from LC50 as much 75.30347 ppm, ethyl acetate fraction obtained from LC50 as much as 77.87461 ppm and those three extracts are toxic. The IC50 value of a total ethanol of 176 ppm, n-Hexane fraction of as 189 ppm and ethyl acetate fraction of 144 ppm with is strength medium antioxidant.
PEMBUATAN SURFAKTAN BERBAHAN DASAR MINYAK BIJI KETAPANG Terminalia catappa DENGAN TRIETANOLAMINA Ravensca, Irene; Saleh, Chairul; Daniel, Daniel
JURNAL ATOMIK Vol 2 No 2 (2017)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

Research synthesis esteramin with cattapa seed oils (Terminalia cattapa) has been done through a transesterification reaction. The synthesis process was conducted on the extraction, esterification and transesterification. The results showed cattapa seed oil content of 51.9%, the acid value of 7.559 mg KOH / g and ALB levels of 3.4496%. The composition of the oil determined using GC-MS. GC-MS analysis of the composition of the most dominant oil is oleic acid amounted to 34.86%. Esterification process in the formation of methyl esters can be known ALB decreased to 0.7%. Methyl esters are reacted with triethanolamine through a transesterification reaction. The results showed esteramin water surface tension value of 34.947 dyne / cm, the HLB value of 5.25 is included in the water in oil emulsifiers scale and on a TLC plate there are two stains.
SYNTHESIS OF SULPHONATED MESOPOROUS SILICA FROM RICE HUSK ASH (Oryza sativa L.) Maylina, Ajeng Chandra; Subagyono, R.R. Dirgarini Julia Nurlianti; Daniel, Daniel
JURNAL ATOMIK Vol 3 No 2 (2018)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

A study on the synthesis of sulphonated mesoporous silica from rice husk ash (Oryza sativa L.) been conducted. The preparation of sulphonated MSU-H was conducted by several steps namely, extraction of silica from rice husk ash, synthesis of mesoporous silica, synthesis of sulphonated mesoporous silica with post-grafting method. The N2 adsorption-desorption characterization results show the surface area of mesoporous silica 134 m2/g, pore volume 0.81 cm3/g and pore size 24.13 nm. The FT-IR characterization results of sulphonated mesoporous silica indicate the presence of Si-O-Si, Si-O, O-H and C-H alkane clusters.
PELATIHAN TEKNIK BEDAH OVARIOHISTERECTOMI (OH) PADA KUCING BETINA YANG EFEKTIF KEPADA DOKTER HEWAN PRAKTISI DI KABUPATEN ACEH TENGAH Khalid, Idham; Riandi, Lian Varis; Ferdian, Ryan; Daniel, Daniel; Ruhghea, Sara; Malina, Khaira; Kumahara, Wien
Peternakan Abdi Masyarakat (PETAMAS) Vol 4, No 2 (2024): Vol 4, No 2 (2024): Volume 4, Nomor 2, Desember 2024
Publisher : Departemen of Animal Science, Agriculture Faculty, Syiah Kuala University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24815/petamas.v4i2.44055

Abstract

Pelatihan teknik bedah ovariohisterektomi (OH) merupakan salah satu bentuk pengabdian masyarakat yang bertujuan untuk meningkatkan kompetensi dokter hewan praktisi di Kabupaten Aceh Tengah. Kegiatan ini dilatarbelakangi oleh pentingnya pengendalian populasi kucing liar yang berdampak pada kesehatan hewan dan masyarakat. Tujuan dari pelatihan ini adalah memberikan pemahaman teoretis dan keterampilan praktis dalam melakukan bedah OH yang efektif, aman, dan minim risiko komplikasi. Metode pelaksanaan meliputi sesi teori, demonstrasi bedah, dan praktik langsung dengan pendampingan instruktur. Hasil kegiatan menunjukkan peningkatan signifikan dalam pemahaman peserta terkait anatomi reproduksi, teknik asepsis, serta prosedur operatif. Kesimpulan dari kegiatan ini adalah pelatihan bedah OH efektif dalam meningkatkan kemampuan dokter hewan praktisi sehingga dapat diaplikasikan dalam pelayanan klinis sehari-hari.
Konsep Pendidikan dalam Keluarga, Sekolah, dan Masyarakat Dalam Kerangka Pendidikan Nilai dan Karakter Daniel, Daniel; Andi Muhammad Fadhal Hiqh.T Pangera; Fila Sasmita; Andi Aco Agus; Najamuddin
Indo-MathEdu Intellectuals Journal Vol. 6 No. 3 (2025): Indo-MathEdu Intellectuals Journal
Publisher : Lembaga Intelektual Muda (LIM) Maluku

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.54373/imeij.v6i3.3172

Abstract

This study aims to understand and analyze the role and contribution of each educational environment of family, school, and community in instilling moral values ​​and forming the character of students in an integrated and sustainable manner. This qualitative study uses library research, the research method is carried out by collecting and analyzing various relevant written sources. These sources can be in the form of scientific journals, books, online articles, research reports, or official publications that discuss the concept of education in families, schools and communities within the framework of value and character education. The results of the study show that: 1) Value and character education is most effective when there is synergy between family, school, and community; these three environments complement each other in forming the personality and morals of students. 2) Lack of consistency in instilling values ​​between the three environments can cause value confusion in children, so intensive communication and cooperation are needed between parties to achieve the goals of complete character education. Why impact why the results are like that because family, school, and community have an important role in shaping children's character. If all three are in harmony and support each other.
PENERAPAN KONSEP RUANG FLEKSIBEL DALAM BANGUNAN TINGGI PADA PUSAT KOMUNITAS DI GONDANGDIA Daniel, Daniel; Suteja, Mekar Sari
Jurnal Sains, Teknologi, Urban, Perancangan, Arsitektur (Stupa) Vol. 7 No. 1 (2025): APRIL
Publisher : Jurusan Arsitektur dan Perencanaan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24912/stupa.v7i1.33937

Abstract

Boplo Market, also known as Gondangdia Market, was built in the 1920s by N.V. de Bouwploeg in the Nieuw-Gondangdia-Menteng area. The name "Boplo" is a local adaptation of "Bouwploeg," meaning "building group." Reconstructed in 2014 after a fire, the market held significant value for residents during the 1960s-1980s. However, rapid globalization and the shift from conventional to digital transactions have caused a decline in buyers and sellers, revealing the need for architecture to adapt to changing demands. This study seeks to redesign Boplo Market, focusing on creating a flexible structure that can accommodate evolving functions. Applying the regenerative approach introduced by Pamela Mang and Bill Reed, the redesign emphasizes revitalizing the natural environment and strengthening the surrounding community. The regenerative concept ensures the building's capacity for continuous renewal, making it future-proof and relevant over time. The design transforms what was once a placeless space—devoid of unique local identity—into an adaptive, contextually harmonious environment that responds to local needs and characteristics. Through a balance of tradition and innovation, the proposed redesign positions the market as a resilient space capable of withstanding the challenges of globalization while fostering a strong connection to its cultural and social context. This approach ensures that the market remains a vital, functional part of the community for years to come. Keywords:  boplo; community; flexible; placeless; regenerative Abstrak Pasar Boplo atau yang dikenal sebagai pasar Gondangdia, merupakan pasar yang dibangun pada tahun 1920-an, oleh N.V de Bouwploeg dan berada di kawasan Nieuw-Gondangdia-Menteng. N.V. Bouwploeg merupakan sebuah biro arsitektur yang bertujuan menata kawasan tersebut menjadi kota taman, dan nama Boplo merupakan pelafalan yang lebih lokal dari kata Bouwploeg oleh warga lokal, yang memiliki arti sebagai ‘kelompok membangun’. Pasar yang pernah mengalami pembangunan ulang pada tahun 2014 akibat kebakaran ini mempunyai arti penting bagi warga lokal pada tahun 1960-1980. Akibat dari globalisasi yang begitu cepat, perubahan kebutuhan dan proses jual-beli barang dan jasa antar manusia dari pembayaran konvensional menjadi pembayaran digital, Pasar Boplo kini mengalami penurunan jumlah pembeli dan penjual. Perubahan-perubahan tersebut menunjukkan bahwa arsitektur perlu fleksibilitas dalam ruangnya, fleksibilitas yang dapat memfasilitasi perubahan fungsi yang terjadi. Tujuan dari penelitian ini adalah merancang kembali bangunan Pasar Boplo, sehingga dapat lebih fleksibel terhadap perubahan fungsi di masa depan. Pendekatan regeneratif, seperti yang dikemukakan oleh Pamela Mang dan Bill Reed, diterapkan dengan tujuan untuk merevitalisasi lingkungan alam dan komunitas di sekitarnya. Konsep ini memungkinkan bangunan untuk terus-menerus memperbarui dirinya seiring waktu. Dalam pengembangan narasi arsitektur, konsep regeneratif diterapkan pada ruang yang awalnya tidak memiliki identitas lokal (placeless), sehingga mampu menciptakan ruang yang adaptif dan selaras dengan kebutuhan serta karakteristik lokal. Bangunan ini dirancang agar tetap relevan dan bertahan menghadapi tantangan globalisasi.
Social Movement for Rejection of Coastal Reclamation Development in Majene Regency: Social and Environmental Impact Analysis Tandjung, Muhammad Akbar; Torro, Supriadi; Daniel, Daniel
Pinisi Journal of Social Science Vol 2, No 2 (2023): September
Publisher : Universitas Negeri Makassar

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26858/pjss.v2i2.72059

Abstract

The objectives of writing this article are (1) To see the role of social movements in response to the development of Waterfront City/coastal reclamation in Majene Regency. (2) Studying the process of Waterfront City/reclamation development in the coastal area of Majene City. (3) Analyze the implications of Waterfront City/coastal reclamation development on the environment and the socio-economic conditions of fishing communities. The development of Waterfront City in Majene Regency significantly affects the lives of fishing communities and local wisdom. This project threatens their livelihoods that have been dependent on the sea, forcing them to look for alternative jobs due to environmental changes that occur. The method used in this article is descriptive analytical research method. The importance of previous environmental studies is undeniable as it helps identify and mitigate negative impacts, such as coral reef damage that may arise from reclamation. Strict regulations and the application of high standards are vital to ensure the viability of the project. The findings of the environmental assessment related to Waterfront City also indicated potential environmental threats that must be addressed immediately. Fishing communities are fighting in various ways, including direct protests, to protect their environment, cultural heritage and livelihoods from the threats of the project. In the face of these challenges, fishing communities, such as the Alliance to Save Sul-Bar Fishermen and Coastal Areas, continue to work to protect the environment from the negative impacts of Waterfront City development in Majene Regency
Co-Authors A An Arief Jusuf Abdul Hamid A. Yusra Abdurizal Arsyad, Syech Geopandu Adi Suyatno Adu, Desmon Ayub Agatha, Septian Ahmad Ridha Akbar, Fath Ali Amin, Abdul Rachmad Zahrial Amiruddin Amiruddin Amrazi Zakso ANDI ACO AGUS Andi Muhammad Fadhal Hiqh.T Pangera Andreas Saputra, Andreas Andri Dwi Hernawan Angelita, Maya Anggunadi, Angelica Anis Chariri Annisa Purbasari, Annisa Arjuna, Arjuna Asrini, Luh Juni Athaillah, Farida Batan, Alfrida Bihairi Hadi, Ricky Lutfi Br Ginting, Survina Osalia C. Pickerling Cahya, Lisye Mareta Carolin, Avine Sindi Cendana, Colleen Chandra Wijaya Chatarina Dian Indrawati Christiyanto, Laurensius Erdin Christopher, Arvin Damanik, Justin Gamaliel Dedhi Yustendi Dewantara, Jagad Aditya Dewi, Camelia Eugenia Dewi, Ezra Shandra Dhita Wahyu Anggraeni, Dhita Wahyu Dwi Agustina Dwiputra, Achmad Irvan Erwin Erwin Etriwati E Eva Marliana, Eva Faisal Jamin Faisal Mustafa Farhana, Siti Farhany, Farhany Fathurrohman, Reza Fazhar Sumantri febriyanti febriyanti Febriyanto Febriyanto Feliciana, Anastasia Fellyanto, Fellyanto Ferdian, Riyan Ferdian, Ryan Fila Sasmita Firmansyah, Muchammad Ravi Fredy Purnomo Frengki Frengki, Frengki Gaanty Pragas Maniam, Gaanty Pragas Gunarto, Chintya Halim, Grace Suriadi Harefa, Kasieli Hartono, Eric Hasibuan, Serepina Yoshika Hasriati Hasriati, Hasriati Hendrawan Armanto Hermanto Hermanto Hidayat, Farah Amalia Hiyahara, Irfan Ashari Husnawati Husnawati Hutabarat, Rugun Romaida Idham Khalid Imran Imran Indra Riyana Rahadjeng Isyana Emita Iwan Ramadhan Jap Tji Beng Juliana, Eva Junianto Wika Adi Pratama Justin, Justin Kirana, Stephani Nindya Kumahara, Wien Kurniati, Triani Kusumo, Catherine Tjondro Kwan, Jessyca Larosa, Setiaman Latumahina, Bill Samuel Lelunu, Sapta Leslivania, Monika Liangga, David Liku, Yeli Oktaviana Liku LUCKY, MAYLANI Lukman Hakim Lumbantoruan, Haposan M. Hasan Magdaleni, Agustina R. Magdaleni, Agustina Rahayu Makmur, Ali Malina, Khaira Manisha, Manisha Margareta, Serlen Marpaung, Franky Hadinata Maswadi - Maygusten, Maygusten Maylina, Ajeng Chandra Megawaty, Megawaty Meiliana, Evita Mekar Sari Suteja Melyani Melyani, Melyani Meriyani, Susi Michael Michael Miyata, Andrew Febrian Mochammad Imron Awalludin Moron, Maria Selvi Mufid, Zainul Muhammad Ezar Al Rivan Muhammad Fachrurrozi Bafadal Muhammad Hasan Muhammad Isa Muhammad Jalaluddin, Muhammad Mulyono, Romi Kurniawan Agni Muttaqien Bakri, Muttaqien Naibaho, Lamhot Natal Indra Naufaludin, Ahmad Noni Zakiah Noor Hindryawati, Noor Nora Usrina Nugrahanto, Cornelius Septian Nurhidayah, Annisa Nurleni, Nurleni NURLIANA NURLIANA Nurmawan, Mardatungga Octa Maria Sihombing Octavianus Octavianus, Octavianus Oktavianus Oktavianus Olivia, Nia Panannangan, Josua K. Partomuan Simanjuntak Parulian Hutajulu, Josua Pentagon, Pentagon Pontan, Darmawan Pranita, Widya Pratama, Ellen Puspita Handayani Putri, Andini Amelia Putri, Erika Ardya Mesia R. Rusli Rachmat, A. Khafifah Dwi Rachmat, Zul Rafik, Ahmad RAHMAT GUNAWAN Rahmawati, Rahmawati Rakhmad, Rakhmad Rantung, Dyoys Anneke Ravensca, Irene Razali Daud Riandi, Lian Varis Rindawati, Novi Rismawati Rismawati Riyanto, Kuncoro Budi Riyanto, Rahmat Fajar Rizkiana Karmelia Shaura Rosalina Putri, Kesia Roslizawaty Roslizawaty, Roslizawaty Rosmaidar Rosmaidar, Rosmaidar Rufi'i Rustiyarso, Rustiyarso Ryn Pratiwi, Djihan Saibun Sitorus Saleh, Chairul Sandra, Putri Ayu Sanjaya, Regi Sara Ruhghea Sari, Dea Kurnia Sari, Wahyu Eka SATRIYAS ILYAS Sebastian, Novianto Sembiring, Rinawati Seputri, Merryana Sigit, Miarsono Sikwan, Agus Silvia Monica Sirait, Muhammad Alfajri Erutama Sisilia, Desy Siti Aisyah Sitompul, Citra Uli Sitti, Nur Faridah Situmorang, Aspriska R. Soma, Yolanda V. A Subagyono, R.R. Dirgarini Julia Nurlianti Subur P Pasaribu Sucipto, Rakhmat Hadi Sudrajat Sudrajat Suharti, Tien Sumeru, Indrawati Suriyanisa, Suriyanisa Sutrisno, Marshela Suzzana Winda Artha Mustika Swastika, Rahayu Syafrida, Yuni Tandjung, Muhammad Akbar Thomy Sastra Atmaja Tony Tony Torro, Supriadi Trisna Fajar Prasetyo Variani, Joanna Rika Vedro, Vedro Vera Methalina, Vera Vincent Tristan, Radick Vincentia, Meyshela Viny Christanti M Wangsawidjaja, Dustin Pranata Wardhani, Lailia Dwi Kusuma Wardoyo, Arif Wasino Wasino Widiastiani, Nindry Sulistya Widyandana Widyandana Wijaya, Christian Julius Willyanto, Hubertus Carmelo Dinar Wirya, Wirya Yaputri, Leticia Yenni Yusriani Yohanes Bahari Yonas, Yonas Yudhistira Oscar Olendo Yunita, Risna Zamzami, Rumi Sahara Zulkifli Zulkifli Zulkifli, Baidillah Zulkifli, Said Zuri Astari