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All Journal JURNAL SAINS PERTANIAN EQUATOR Jurnal Pendidikan Sosiologi dan Humaniora Diponegoro Journal of Accounting Jurnal Media Infotama ProNers Jurnal Bahan Alam Terbarukan Jurnal Sosialisasi: Jurnal Hasil Pemikiran, Penelitian dan Pengembangan Keilmuan Sosiologi Pendidikan PROSIDING SEMINAR KIMIA REPOSITORY KIMIA Jurnal Kimia Mulawarman PROFESIENSI JURNAL ATOMIK Jurnal Arsir Jurnal Teknik Informatika UNIKA Santo Thomas Gulawentah:Jurnal Studi Sosial INTECOMS: Journal of Information Technology and Computer Science ComTech: Computer, Mathematics and Engineering Applications Jurnal Ilmiah Fillia Cendekia JURNAL EKSBIS Prosiding National Conference for Community Service Project Jurnal Informatika dan Sistem Informasi STUDI PELAKSANAAN SELFMEDICATION PADA PENDERITA DIARE BERDASARKAN TINGKAT PENGETAHUAN MASYARAKAT PESISIR KECAMATAN SOROPIA KABUPATEN KONAWE Shift Key: Jurnal Teologi dan Pengembangan Pelayanan Jurnal Pengabdian Masyarakat Indonesia Jurnal Pendidikan PKn Jurnal Sains, Teknologi, Urban, Perancangan, Arsitektur (Stupa) Journal La Multiapp Akasia: Artikel Ilmiah Sistem Informasi Akuntansi Journal Peqguruang: Conference Series Indo-MathEdu Intellectuals Journal Jurnal Teknik Informatika Unika Santo Thomas (JTIUST) Algoritme Jurnal Mahasiswa Teknik Informatika Jurnal Atma Inovasia ABDINE Jurnal Pengabdian Masyarakat Jurnal Natural The International Journal of Tropical Veterinary and Biomedical Research INTERNATIONAL JOURNAL OF HUMANITIES, SOCIAL SCIENCES AND BUSINESS (INJOSS) IJMI Daya Nasional: Jurnal Pendidikan Ilmu-Ilmu Sosial dan Humaniora Jurnal Medika Veterinaria Pinisi Journal of Social Science Banking & Management Review Jurnal Bisnis Digital dan Enterpreneur (BISENTER) Peternakan Abdi Masyarakat (PETAMAS)
Daniel Daniel
Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan alam, Universitas Mulawarman
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MINI RIVIEW: POTENSI ASAM MALAT (2-hydrobutanedioic-acid) DAN TURUNANNYA SEBAGAI SURFAKTAN Rachmat, A. Khafifah Dwi; Daniel, Daniel; Pasaribu, Subur P.
PROSIDING SEMINAR KIMIA Vol 3 No 1 (2024): Prosiding SNK 2024
Publisher : Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman

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Abstract

Malic acid (2-hydrobutanedioic-acid) is a dicarboxylic acid (carboxylic acid) which is generally found in many apples. Several malic acid derivatives have been synthesized through esterification and amidation reactions, including methyl malate, maleyl oleate and maleyl glutamide. Based on the results of FT-IR analysis of malic acid, it is known that there is an absorption peak at wave number 3448.72 cm¬-1 indicating the presence of an alcohol group and an absorption peak at wave number 1720.50 cm-1 indicating the presence of a carboxylic group. In methyl malate, it is known that in the wave number area of ​​1735.93 cm-1, stretching vibrations of the C=O ester carbonyl group occur. In maleyl oleate, the absorption in the wave area of ​​1743.65 cm-1 is a typical absorption from the stretching vibration of C=O ester. In maleyl glutamide, it is known that there is absorption at the peak wave number of 3425.58 cm-1 which is the stretching vibration of the NH (amide) group. The results of several literatures explain that the malic acid derivative, namely methyl malate, has an HLB value of 11.2 and can be used as an O/W (Oil in Water) emulsifier. The HLB value of maleyl oleate has a value of 4.61 which can be used as a W/O (Water in Oil) emulsifier and for maleyl glutamide the HLB is 14.84 which can be used as an O/W (Oil in Water) emulsifier. Therefore, malic acid derivatives have potential as materials for surfactant synthesis. Keywords: Malic Acid, Esterification and HLB (Hydrophilic Lipophilic Balance).
Sosialisasi Penguatan Rasa Nasionalisme melalui Pendekatan Eksplorasi pada Peserta Didik di SMAN 1 Sajingan Perbatasan Indonesia Malaysia Astari, Zuri; Imran, Imran; Ramadhan, Iwan; Zatalini, Adhalia; Daniel, Daniel
ABDINE: Jurnal Pengabdian Masyarakat Vol. 4 No. 2 (2024): ABDINE : Jurnal Pengabdian Masyarakat
Publisher : Sekolah Tinggi Teknologi Dumai

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.52072/abdine.v4i2.952

Abstract

Pengaruh budaya dan sosial dari negara tetangga melemahkan rasa nasionalisme kalangan peserta didik. Tanpa adanya upaya efektif dalam penguatan rasa nasionalisme, ada risiko generasi muda ini akan kehilangan identitas nasionalnya dan kurang memahami pentingnya menjaga keutuhan dan kedaulatan negara. Pentingnya sosialisasi penguatan rasa nasionalisme di daerah perbatasan. Tujuan utama sosialisasi ini untuk meningkatkan kesadaran nasional, menanamkan kebanggaan terhadap identitas nasional serta meningkatkan kesadaran akan pentingnya menjaga kedaulatan negara di kalangan peserta didik SMAN 1 Sajingan. Sosialisasi dilakukan dengan memberikan materi  melalui ceramah, diskusi dan tanya jawab. Melalui diskusi  peserta didik dapat menggali lebih dalam mengenai tantangan dan peluang dalam menjaga identitas nasional serta memperkuat rasa nasionalisme. Pelaksanaan sosialisasi ini dirancang untuk memastikan bahwa peserta didik di SMAN 1 Sajingan memiliki kesadaran yang kuat tentang pentingnya nasionalisme. Capaian hasil pengabdian dari survei menunjukkan 66,7% peserta didik  kategori sangat setuju dan 26,7%  kategori setuju jika penguatan rasa nasionalisme penting dan sekolah memiliki program mendukung peningkatan nasionalisme. Hal tersebut menunjukkan keberhasilan pengabdian ini meningkatkan pemahaman nasionalisme peserta didik di kawasan perbatasan. Selain itu terdapat kesadaran  dampak negatif pengaruh budaya asing. Melalui sosialisasi ini diharapkan peserta didik tumbuh menjadi generasi yang berkomitmen menjaga dan memperjuangkan kedaulatan bangsa di masa depan.
Screening of Bioactive Compounds of Gambir leaf (Uncaria gambir Roxb) as Antibiofilm Againts the Glucosyltransferase of Streptococus mutans Enzyme Khalid, Idham; Sari, Dea Kurnia; Bakri, Muttaqien; Daniel, Daniel; Frengki, Frengki; Makmur, Ali; Riandi, Lian Varis; Ferdian, Riyan; Amiruddin, Amiruddin
Jurnal Medika Veterinaria Vol 18, No 2 (2024): J. Med.Vet
Publisher : Universitas Syiah Kuala

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21157/j.med.vet..v18i2.43265

Abstract

The use of natural ingredients in dental care, such as manginang which has become part of the Minang community culture, is considered an alternative dental care that must be created to overcome the negative impacts of dental care made from artificial materials. The core of this study is to change the manginang tradition towards logical verification through screening of bioactive compounds of gambir leaves (Uncaria gambir Roxb.) as antibiofilms against Streptococcus mutans. This study was conducted using an in silico strategy approach with the help of computer programs such as MOE v.09 and Chimera 1.13.1, as well as the Way2Drug site, protein information bank, and protox_ii. This study began with the collection of ligand information from the writing, followed by transformation into 2D and 3D designs. Other antibiofilm actions were decided using the QSAR procedure through the website (http://www.way2drug.com/PASSOnline/predict.php). The selected antibiofilm compounds were then followed by observing their affinity for the receptor (pdb id. 3AIB) using an atomic docking strategy. Finally, the ligand damage profile was observed to anticipate. The results of this study indicate that of the 41 identified gambir leaf compounds, there are 20 compounds that have the potential to have antibiofilm effects with quinnic acid having the highest score (Pa 0.703), while the compound with the strongest affinity for the receptor is chlorogenic acid with an affinity score (Gbinding) of -16.03 kcal/mol and an average of low toxicity (level IV-VI). However, of the 20 bioactive compounds of gambir leaves, only 5 compounds are predicted to have the same potential as the -maltose control.
THE EFFECT OF PROVIDING GAMAL LEAF SILAGE (GLIRICIDIA SEPIUM) ON CONSUMPTION,WEIGHT GAIN AND RANSUM CONVERTION OF LOCAL MALE GOATS DERIVED FROM ETTAWA CROSSBREEDS Ridha, Ahmad; Yustendi, Dedhi; Daniel, Daniel; Zulkifli, Zulkifli
International Journal Multidisciplinary (IJMI) Vol. 2 No. 1 (2025): International Journal Multidisciplinary
Publisher : ANTIS PUBLISHER

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.61796/ijmi.v2i1.302

Abstract

Objective: This study aimed to evaluate the effect of gamal (Gliricidia sepium) leaf silage on the growth performance of local male goats. The research focused on key growth parameters, including daily feed consumption, daily body weight gain (PBBH), feed conversion, and feed efficiency. Method: The experiment was conducted using a randomized block design (RAK) with four treatments and four replications. The treatments included (P0) control with elephant grass without gamal leaves, (P1) 20% gamal leaf silage and 80% elephant grass, (P2) 50% gamal leaf silage and 50% elephant grass, and (P3) 100% gamal leaf silage. The goats were monitored over four weeks to assess their growth response to different feeding compositions. Results: The findings revealed a significant effect of gamal leaf silage on the growth performance of local male goats. The inclusion of gamal leaf silage improved daily body weight gain, feed conversion, and feed efficiency. Higher proportions of gamal leaf silage in the diet resulted in better growth performance compared to the control group. Novelty: This study highlights the potential of gamal leaf silage as an alternative, cost-effective feed source for ruminants. The results contribute to the understanding of utilizing non-conventional feed ingredients to reduce feed costs while maintaining livestock productivity.
Pelatihan Penggunaan Aplikasi Kasir untuk Meningkatkan Efisiensi Pencatatan Transaksi di Jakarta Selatan Nurmadewi, Dita; Daniel, Daniel; Jonatan, Jonatan
Jurnal Pengabdian Masyarakat Indonesia Vol 5 No 1 (2025): JPMI - February 2025
Publisher : CV Infinite Corporation

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.52436/1.jpmi.3409

Abstract

Program Pengabdian kepada Masyarakat (PkM) desa binaan bertujuan meningkatkan kapasitas dan kemandirian mitra desa dalam mengelola usaha ekonomi lokal berbasis sumber daya lokal. Mitra desa binaan pada kegiatan ini adalah ibu-ibu PKK RW 02 Kelurahan Pancoran, Jakarta Selatan, yang memiliki usaha produksi dan penjualan cheese stick. Kegiatan ini bertujuan membantu mitra dalam menyederhanakan proses pencatatan transaksi dan meningkatkan efisiensi operasional melalui penggunaan aplikasi kasir berbasis web. Tahapan kegiatan meliputi pengambilan data melalui wawancara hingga pelatihan penggunaan aplikasi, serta evaluasi hasil pelatihan. Aplikasi kasir yang digunakan menyediakan fitur pencatatan transaksi otomatis, pengelolaan inventaris, dan laporan keuangan secara real-time. Evaluasi menunjukkan bahwa peserta merasa percaya diri dalam mengoperasikan aplikasi, dan pelatihan dinilai relevan dengan kebutuhan serta mudah dipahami.Hasil implementasi ini tidak hanya meningkatkan efisiensi dalam pencatatan transaksi, tetapi juga memperkuat kapasitas ibu-ibu PKK RW 02 dalam memanfaatkan teknologi informasi untuk pengembangan usaha. Program ini menjadi bukti penerapan teknologi dalam mendukung pemberdayaan ekonomi lokal berbasis komunitas.
PENENTUAN DERAJAT ASILASI (DA) DENGAN METODE BASE LINE DARI SINTESIS N-ALDIMIN KITOSAN Soma, Yolanda V. A; Daniel, Daniel; Saleh, Chairul
JURNAL ATOMIK Vol 3 No 1 (2018)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

Determination Degree of Acylation (DA) with the baseline method from the synthesis of N-Aldimin Chitosan was obtained from the acylation reaction between chitosan and acetaldehyde. The formation of N-Aldimin Chitosan is supported by the data of FT-IR spectroscopy in the wave number 3441.01 cm-1 shows the stretching vibration of OH of chitosan and absorption peaks in the area of wave number 1627.92 cm-1 and 1566.20 cm-1 is vibration C=N which identifies the formation aldimine chitosan. Wavenumber 2924.09 cm-1 shows the C-H stretching vibration as evidenced by a wave number 1404.16 cm-1 which is C-H bending and C-O absorption at wavenumber 1087.85 cm-1. Acylation degree (DA) obtained by 81.33%.
ISOLATION OF CHEMICAL ACTIVE COMPOUNDS ANTIOXIDANT FROM ETHYL ACETATE FRACTION OF BETEL LEAF FOREST (Piper aduncum L.) Batan, Alfrida; Daniel, Daniel; Simanjuntak, Partomuan
JURNAL ATOMIK Vol 3 No 2 (2018)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

Research about the isolation of chemical active compounds antioxidants from ethyl acetate fraction of betel leaf forest (Piper aduncum L.) have been done. This research aimed to determine the type of secondary metabolites that contained in ethyl acetate fraction and the value of antioxidant activity as well as the structure that contained in ethyl acetate fraction. The test results of phytochemical showed that the secondary metabolites in ethanol extract are alkaloids, steroids and triterpenoids. The inhibitory concentration 50% (IC50) value that shown in the fraction Piper aduncum ethyl acetate-4-3 (PAEA-4-3) is 132.84 ppm. Fraction of PAEA-4-3 that have high levels of antioxidant activity was analyzed using a spectrophotometer Ultra Violet-Visible (UV-Vis), Infrared Fourier-Transform (FTIR) and Nuclear Magnetic Resonance (NMR) proton and carbon. The result analysis of PAEA-4-3 isolates showed the compound as 2,3-dimethoxy-metilanaoksi-benzene.
UJI TOKSISITAS DAN SIFAT ALELOPATI EKSTRAK ALANG-ALANG (Imperata cylindrica) TERHADAP PERKECAMBAHAN BIJI PADI (Oryza sativa) Kurniati, Triani; Daniel, Daniel; Sudrajat, Sudrajat
JURNAL ATOMIK Vol 3 No 1 (2018)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

Penelitian inibertujuan untuk mengetahui toksisitas dan sifat alelopati ekstrak alang-alang (Imperata cylindrica) terhadap perkecambahan biji padi (Oriza sativa). Sampel kering akar alang-alang dari Kutai Lama dimaserasi menggunakan pelarut etanol dan di fraksinasi menggunakan pelarut n-heksana dan etil asetat. Sampel kemudian di Skrining fitokimia dan uji toksistas dengan metode (Brini Shrimp Lethality Test) BSLT. Fraksi yang menunjukkan nilai LC50 paling rendah kemudian diuji sifat alelopati dan dianalisis dengan GC-MS. Hasil uji skrining fitokimia menunjukkan adanya kandungan alkaloid, triterpenoid dan fenol. Hasil uji toksisitas dengan metode (Brini Shrimp Lethality Test) BSLT menunjukkan bahwa fraksi etanol memiliki toksisitas tertinggi pada larva udang dengan nilai LC50 sebesar 647,5364 ppm. Uji senyawa alelopati dari ekstrak alang-alang dilakukan pada biji padi (Oriza sativa) memiliki pengaruh nyata terhadap perkecambahan biji padi. Analisa kandungan senyawa kimia pada fraksi etanol dari akar alang-alang menghasilkan dua puncak komponen senyawa pada spektra massa yang ditunjukkan dari hasil GC-MS yaitu fenol dan tetradecamethylcycloheptasiloxane. Kata kunci : Alang-alang (Imperata cylindrica), Fitokimia, Toksisitas dan Sifat Alelopati Terhadap Biji Padi
PHYTOCHEMICAL TEST ON METHANOL EXTRACT OF LEAF OF Macaranga hullettii King ex Hook.f. Rismawati, Rismawati; Marliana, Eva; Daniel, Daniel
JURNAL ATOMIK Vol 3 No 2 (2018)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

Phytochemical test of Macaranga hullettii King ex Hook.f have been done. This research aims to find out the secondary metabolites using Thin Layer Chromatography (TLC) from methanol extract on Macaranga hullettii leaf. Based on results of phytochemical screening, it is known that methanol extract contains alkaloid, steroid/triterpenoid, polifenol and flavonoid compounds.
PHYTOCHEMICAL TEST, TOXICITY TESTS AND ANTIOXIDANT ACTIVITIES OF MAHOGANY SEEDS (Swietenia mahagoni (L) Jacq) Rindawati, Novi; Daniel, Daniel; Saleh, Chairul
JURNAL ATOMIK Vol 4 No 2 (2019)
Publisher : Jurusan Kimia FMIPA UNMUL

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Abstract

Phytochemical tests, toxicity tests and antioxidant activities of mahogany seeds (Swietenia mahagoni (L) Jacq) were carried out. This study is meant to identify the secondary metabolism, the LC50 and LC50 of extract of ethanol, n-hexane fraction, and ethyl acetate fraction with the seeds of (Swietenia mahagoni (L) Jacq). Phytochemical screening on ethanol extract of mahogany seeds showed the presence of alkaloids, flavonoids, triterpenoids and phenolic n-Hexane fraction contains alkaloids compounds, triterpenoid and phenolic compounds. Ethyl acetate fraction contains flavonoids, triterpenoids and phenolic compounds. The toxicity level is performed by tests of BSLT (Brine shrimp lethality test), while antioxidant activity is performed by a spectrofotometr uv-vis. The total extract of ethanol is obtained at the smallest amount of LC50 for 49.47565 ppm, n-Hexane fractions obtained from LC50 as much 75.30347 ppm, ethyl acetate fraction obtained from LC50 as much as 77.87461 ppm and those three extracts are toxic. The IC50 value of a total ethanol of 176 ppm, n-Hexane fraction of as 189 ppm and ethyl acetate fraction of 144 ppm with is strength medium antioxidant.
Co-Authors Abdul Hamid A. Yusra Abdul Latief Abdurizal Arsyad, Syech Geopandu Adi Suyatno Agatha, Septian Ahmad Ridha Akbar, Fath Ali Amin, Abdul Rachmad Zahrial Amiruddin Amiruddin Amrazi Zakso ANDI ACO AGUS Andi Muhammad Fadhal Hiqh.T Pangera Andreas Saputra, Andreas Angelita, Maya Anis Chariri Annisa Purbasari, Annisa Athaillah, Farida Batan, Alfrida Bihairi Hadi, Ricky Lutfi Br Ginting, Survina Osalia C. Pickerling Cahya, Lisye Mareta Cendana, Colleen Chairul Saleh Chandra Wijaya Christiyanto, Laurensius Erdin Christopher, Arvin Damanik, Justin Gamaliel Dedhi Yustendi Dewi, Camelia Eugenia Dewi, Ezra Shandra Dhita Wahyu Anggraeni, Dhita Wahyu Dwi Agustina Ermawati Ermawati Erwin Erwin Eva Marliana, Eva Farhany, Farhany Fathurrohman, Reza Fazhar Sumantri Fellyanto, Fellyanto Ferdian, Riyan Ferdian, Ryan Fila Sasmita Firmansyah, Muchammad Ravi Fredy Purnomo Frengki Frengki, Frengki Gaanty Pragas Maniam, Gaanty Pragas Hartono, Eric Hasibuan, Serepina Yoshika Hasriati Hasriati, Hasriati Hendrawan Armanto Hermanto Hermanto Hidayat, Farah Amalia Hiyahara, Irfan Ashari Idham Khalid Imran Imran Indra, Natal Iwan Ramadhan Jap Tji Beng Jonatan, Jonatan Juliana, Eva Junianto Wika Adi Pratama Justin, Justin Kirana, Stephani Nindya Kumahara, Wien Kurniati, Triani Larosa, Setiaman Latumahina, Bill Samuel Lelunu, Sapta Leslivania, Monika Liangga, David Lukman Hakim M Ezar Al Rivan M. Hasan Magdaleni, Agustina R. Magdaleni, Agustina Rahayu Makmur, Ali Malina, Khaira Manisha, Manisha Margareta, Serlen Marpaung, Franky Hadinata Maylina, Ajeng Chandra Meiliana, Evita Meriyani, Susi Michael Michael Mochammad Imron Awalludin Moron, Maria Selvi Muhammad Jalaluddin, Muhammad Muhammad Nadir Mulyono, Romi Kurniawan Agni Muttaqien Bakri, Muttaqien Nataniel Tandirogang Noni Zakiah Noor Hindryawati, Noor Nora Usrina Nugrahanto, Cornelius Septian Nurhidayah, Annisa Nurleni, Nurleni NURLIANA NURLIANA Nurmadewi, Dita Nurmawan, Mardatungga Octa Maria Sihombing Octavianus Octavianus, Octavianus Olivia, Nia Panannangan, Josua K. Partomuan Simanjuntak Pentagon, Pentagon Pontan, Darmawan Pratama, Ellen Putri, Erika Ardya Mesia Rachmat, A. Khafifah Dwi Rachmat, Zul Rahmawati, Rahmawati Rakhmad, Rakhmad Ravensca, Irene Riandi, Lian Varis Rindawati, Novi Riska Riska Rismawati Rismawati Riyanto, Rahmat Fajar Rosalina Putri, Kesia Roslizawaty Roslizawaty, Roslizawaty Rosmaidar Rosmaidar, Rosmaidar Rustiyarso, Rustiyarso Ryn Pratiwi, Djihan Saibun Sitorus Sandra, Putri Ayu Sanjaya, Regi Sara Ruhghea Sari, Dea Kurnia Sari, Wahyu Eka SATRIYAS ILYAS Sembiring, Rinawati Sigit, Miarsono Sikwan, Agus Silvia Monica Sisilia, Desy Sitompul, Citra Uli Soma, Yolanda V. A Sormin, Hendro Jatmiko Subagyono, R.R. Dirgarini Julia Nurlianti Subur P Pasaribu Sucipto, Rakhmat Hadi Sudrajat Sudrajat Sumeru, Indrawati Suteja, Mekar Sari Suzzana Winda Artha Mustika Swastika, Rahayu Syafrida, Yuni Tandjung, Muhammad Akbar Toibah Umi Kalsum TONE, KAMARUDDIN Tony Tony Torro, Supriadi Variani, Joanna Rika Vedro, Vedro Vera Methalina, Vera Vincent Tristan, Radick Viny Christanti M Wardhani, Lailia Dwi Kusuma Wardoyo, Arif Wasino Wasino Widiastiani, Nindry Sulistya Wirya, Wirya Yenni Yusriani Yohanes Bahari Yonas, Yonas Yunita, Risna Zulkifli Zulkifli Zulkifli, Baidillah Zuri Astari