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Use of CoO/ZnAl2O4 Catalysts and Microwaved Assisted in Vanillin Synthesis Birhi, Damiana Nofita; Iftitah, Elvina Dhiaul; Warsito, Warsito
Jurnal Kimia Valensi Jurnal Kimia VALENSI Volume 9, No. 1, May 2023
Publisher : Syarif Hidayatullah State Islamic University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15408/jkv.v9i1.29727

Abstract

Vanillin is a main component in vanilla, which is widely used in the industrial world. Market demand for vanillin extract continues to increase, while the availability of vanilla pods is decreasing. To overcome this problem, research on the synthesis of vanillin continues to be carried out and develops every year. This research aims to examine the conversion level and selectivity of the catalyst as well as microwave radiation efficiency usage in vanillin synthesis. Catalyst CoO/ZnAl2O4 was synthesized from CoO and ZnAl2O4 using the impregnation method, then analyzed using FTIR, XRD, and SEM-EDX. Vanillin synthesis was conducted in two steps, incorporating microwave usage at 120oC, underwent 30 minutes to be completed then followed by oxidation around 10- and 15-minutes involving nitrobenzene also 1%, 4%, and 7% of catalysts CoO/ZnAl2O4. The result showed that during 10 and 15 minutes, the selectivity value and various yield percentages for each time variation and catalyst loading of vanillin had been successfully 100% converted. The best result was obtained using CoO/ZnAl2O4 with 4% catalyst loading for 15 minutes. The selectivity value and yield percentages were 67.78% and 7.5%. A one-step vanillin synthesis with conventional reflux could also be a comparison. The reactions were done at 130oC for 2 and 3 hours with 4% catalyst loading.
Pertumbuhan dan Hasil Tanaman Kacang-kacangan dengan Pupuk Organik Cair berbagai Sisa Buahan Achadi, Teguh; Haikal, Umair; Angraini, Lili; Ghifari, Muhammad Al; Yakup, Yakup; Marlina, Marlina; Warsito, Warsito
Seminar Nasional Lahan Suboptimal Vol 10, No 1 (2022): Prosiding Seminar Nasional Lahan Suboptimal ke-10 “Revitalisasi Sumber Pangan N
Publisher : Pusat Unggulan Riset Pengembangan Lahan Suboptimal (PUR-PLSO) Universitas Sriwijaya

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Abstract

Achadi T, Haikal U, Angraini L, Ghifari MA, Yakup Y, Marlina M, Warsito W. 2022. Growth and yield of legume crops with liquid organic from various fruit residues. In : Herlinda S et al. (Eds), Prosiding Seminar Nasional Lahan Suboptimal ke-10 Tahun 2022, Palembang  27 Oktober 2022. pp. 217-225. Palembang: Penerbit & Percetakan Universitas Sriwijaya (UNSRI).Liquid organic fertilizer is the result from decomposition of organic matter derived from animals or plants. Liquid organic fertilizer is made from damaged or rotten fruit and from the skin of the fruit (banana, papaya, pineapple and a mixture of all three). This study aimed to determine the effect of liquid organic fertilizer (POC) on the growth and yield of legumes (Soybeans, Peanuts and Green Beans). This research was conducted from July to October 2022. This study used a Complete Randomized Design with eight treatments including controls, namely A (recommended NPK fertilizer), B (POC of banana fruit residue), C (POC of pineapple fruit residue), D (POC sis of Papaya fruit), E (POC of banana + pineapple fruit residue), F (POC of banana + papaya fruit residue), G (POC of pineapple fruit residue + papaya) and H (remaining banana fruit + pineapple + papaya). The results showed that liquid organic fertilizer were not significantly different the recommended NPK fertilizer to all variables with out number of branches and productive branch of Soybeans and numbers of branches of Peanuts so hope that liquid organic fertilizer from Various Fruit Residues increase to Yield of Legume Crops (Soybeans, Peanuts and Green Beans).
Pupuk Organik Cair asal Limbah Kulit Nanas untuk Perbaikan Lahan Karet Rakyat di Payaraman Barat, Ogan Ilir Setyawan, Dwi; Maren, A; Budianta, D; Warsito, Warsito; Priatna, S J
Seminar Nasional Lahan Suboptimal Vol 10, No 1 (2022): Prosiding Seminar Nasional Lahan Suboptimal ke-10 “Revitalisasi Sumber Pangan N
Publisher : Pusat Unggulan Riset Pengembangan Lahan Suboptimal (PUR-PLSO) Universitas Sriwijaya

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Abstract

Setyawan D, Maren A, Budianta D, Warsito W, Priatna SJ. 2022. Liquid organic fertilizer from pineapple peel waste for rural rubber land improvement in West Payaraman, Ogan Ilir. In: Herlinda S et al. (Eds.), Prosiding Seminar Nasional Lahan Suboptimal ke-10 Tahun 2022, Palembang  27 Oktober 2022. pp. 878-884.  Palembang: Penerbit & Percetakan Universitas Sriwijaya (UNSRI).Rubber plantations are an important source of income in Payaraman District, Ogan Ilir and are generally cultivated on marginal lands. Meanwhile, pineapple peel waste that is not utilized will pile up into garbage even though it can be used as liquid organic fertilizer or compost. This study aimed to assess the effectiveness of POC pineapple peel waste in increasing soil N, P, and K nutrients and latex production. The study used a split plot design with the main plot of weed clearing (without and with weeding) while the subplots were POC doses of 0, 1, 2, 3 and 4% (equivalent to 0, 10, 20, 30 and 40 ml POC). per liter of water). Watering is done with a frequency of once per week. The treatment was repeated three times. The experimental unit consisted of 30 mature rubber trees. Latex is collected weekly. The results showed that the POC of pineapple peel had a pH of 3.95; 0.05 % N; 0.027 % P and 0.19 % K. The initial soil pH value from 4.13 to 4.18 increased to around pH 5.0 after POC application for 4 weeks. Likewise, the total N content is about 0.26%; P-total 100 mg/kg and K-total 14 mg/kg. ANOVA results showed that the best treatment was a dose of 30 ml/liter with a latex production of 770 g/tree. Based on these observations, it can be concluded that the POC of pineapple waste has the potential to improve soil fertility and latex production. Weeding is important to reduce nutrient competition with rubber plants. 
HUMANISME DAN PETAKA MODERN Warsito, Warsito; Muttaqin, Husnul
The Sociology of Islam Vol. 2 No. 2 (2012): Desember
Publisher : Prodi Sosiologi, Fakultas Ilmu Sosial dan Ilmu Politik, UIN Sunan Ampel Surabaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15642/jsi.2012.2.2.%p

Abstract

Peradaban modern dimulai dari geliat renaissance yang kemudian disempurnakan dengan aufklarung. Dengan janji-janji kemanusiaannya, peradaban baru yang mengusung misi humanisasi ini membangun peradaban dengan kecepatan tinggi. Karya besar gerakan humanisme ini dapat kita saksikan pada peradaban modern yang kita saksikan saat ini. Namun, dalam perjalanannya yang panjang, humanisme antroposentris ini ternyata tidak benar-benar mampu mewujudkan janji-janji manisnya. Manusia berada dalam ancaman serius berupa bencana alam dan perbudakan manusia oleh manusia lain dan perbudakan manusia oleh teknologi yang ia ciptakan sendiri. Tampaknya, bencana ini terjadi karena setelah manusia secara gilang gemilang berhasil menaklukkan alam, mereka kemudian bergerak lebih jauh dengan “membunuh” Tuhan dan kemanusiaan. Untuk itulah, humanisme teosentris ditawarkan sebagai antitesis agar manusia dapat keluar dari keterpurukannya. Kata Kunci: antroposentris, humanisme teosentris, modernitas
Automasi dan Internet of Things (IoT) pada Pertanian Cerdas: review artikel pada Jurnal Terakreditasi Kemenristek Setyawan, Dodi Yudo; Warsito, Warsito; Marjunus, Roniyus; Sumaryo, Sumaryo
Prosiding Semnastek PROSIDING SEMNASTEK 2024
Publisher : Universitas Muhammadiyah Jakarta

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Abstract

Pertanian cerdas adalah model pertanian yang melibatkan atau memanfaatkan teknologi otomasi dan Internet of Things (IoT) dalam praktik pertaniannya. Inovasi teknologi ini memiliki peran sentral dalam meningkatkan daya saing dan dinamika pertanian di Indonesia, serta diperlukan lebih banyak penelitian yang mendalam di bidang ini. Review yang mendalam perlu dilakukan pada penelitian-penelitian yang telah terbit pada jurnal yang terakreditasi oleh Kemenristek. Review ini bertujuan untuk mengetahui sejauh mana teknologi otomasi dan IoT yang telah diterapkan oleh para peneliti. Review ini dimulai dari penelusuran metadata artikel pada Google Scholar dengan kata kunci IoT, otomasi, dan pertanian cerdas menggunakan aplikasi Publish or Perish (PoP). Diperoleh 162 metadata artikel, review dilakukan dari review parsial hingga review mendalam, dan diperoleh 29 artikel terakreditasi Kemenristek. Review mendalam dengan Research Question (RQ) diperoleh informasi bahwa artikel terbanyak terbit pada jurnal ranking 4 akreditasi Kemenristek, trend penelitian naik dari tahun ke tahun, sensor dan tools IoT yang paling banyak digunakan adalah sensor kelembaban tanah dan website.Kata kunci—Pertanian cerdas, IoT, automasi, review
PENGARUH KOMUNIKASI INTERPERSONAL, MOTIVASI BELAJAR SISWA DAN LINGKUNGAN SEKOLAH TERHADAP PRESTASI BELAJAR PPKn WARSITO, WARSITO
Jurnal Sosialita Vol. 13 No. 1 (2020): JURNAL SOSIALITA
Publisher : Program Magister Pendidikan IPS UPY

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Abstract

WarsitoABSTRAKPenelitian ini bertujuan untuk mengetahui pengaruh komunikasi interpersonal, Motivasi belajar dan lingkungan sekolah terhadap prestasi belajar PPKn. Penelitian ini dilaksanakan di SMK Negeri 2 Wonosari. Jenis penelitian merupakan penelitian kuantitatif. Subjek dalam penelitian ini berjumlah 143 siswa. Teknik pengumpulan data dalam penelitian ini menggunakan angket dan dokumentasi. Teknik analisis data menggunakan analisis regresi ganda. Hasil penelitian menunjukkan bahwa 1) Ada pengaruh positif dan signifikan komunikasi interpersonal terhadap prestasi belajar PPKn. Berdasarkan hasil analisis data diperoleh nilai thitung = 3.285 dengan p = 0,001. 2) Ada pengaruh positif dan signifikan motivasi belajar terhadap prestasi belajar PPKn. Berdasarkan hasil analisis data diperoleh nilai thitung = 3.165 dengan p = 0,002. 3) Ada pengaruh positif yang signifikan lingkungan sekolah terhadap prestasi belajar PPKn. Berdasarkan hasil analisis data diperoleh nilai thitung = 3.340 dengan p = 0,001. Ada pengaruh positif dan signifikan komunikasi interpersonal, motivasi belajar dan lingkungan sekolah secara bersama-sama terhadap prestasi belajar PPKn. Berdasarkan hasil analsis data diperoleh nilai Fhitung = 18.343 dengan p = 0,000, hal ini berarti bahwa semakin tinggi komunikasi interpersonal, semakin baik motivasi belajar siswa dan semakin baik lingkungan sekolah maka semakin tinggi pula prestasi belajar siswaKata Kunci: komunikasi interpersonal, motivasi belajar, prestasi belajarThis research purports to discover the influence of interpersonal communication, learning motivation and school environment on students’ academic achievement in Civics. This research was conducted in State Vocational High School (SMKN) 2 Wonosari. The type of the research is quantitative study. Research subjects are 143 students. Data collection method in this research relied on questionnaires and documentation. Data analysis technique is based on multiple regression. The result of the research indicates that 1) Interpersonal communication has a positive and significant influence of students’ academic achievement in learning Civics. The result of data analysis reveals the score of tcalc = 3.285 ; p = 0,001. 2) Learning motivation has a positive and significant influence on students’ academic achievement in Civics. Result from data analysis shows the score of tcalc = 3.165 ; p = 0,002. 3) school environment has a positive and significant influence on students’ academic achievement in Civics. According to the result from data analysis the score of tcalc = 3.340 ; p = 0,001. Altogether interpersonal communition, learning motivation and school environment have a positive and significant influence on students’ academic achievement on Civics. According to data analysis the score of Fcalc = 18.343 ; p = 0,000, this means that the higher the interpersonal communiction, the better the students’ learning motivation and the better their school environment, the higher their academic achivement would be.Keywords: interpersonal communication, learning motivation, academic achievement
Implementation of fuzzy logic approach for thalassemia screening in children Redy Susanto, Erliyan; Syarif, Admi; Warsito, Warsito; Nisa Berawi, Khairun; Ayu Sangging, Putu Ristyaning; Wantoro, Agus
IAES International Journal of Artificial Intelligence (IJ-AI) Vol 13, No 4: December 2024
Publisher : Institute of Advanced Engineering and Science

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.11591/ijai.v13.i4.pp4062-4070

Abstract

Thalassemia is one of the most dangerous blood disorders that can lead to severe complications. It is an inherited disease, usually detected after a child is two to four years old. Identification of thalassemia is a complex task, involving many variables. Doctors generally diagnose thalassemia by using a complete blood count (CBC) and high-performance liquid chromatography (HPLC) test results. However, HPLC tests are expensive and time consuming, hence the need for other methods to identify thalassemia. There are many studies on the application of artificial intelligence for medical applications. In this study, we developed a new fuzzy-based approach to identify thalassemia based on a patient’s blood laboratory results. First, we analyzed the CBC data for blood disorder prediction. Secondly, we adopt the test results of peripheral blood smear (PBS) to identify whether the person has thalassemia. We conducted several experiments using 30 (thirty) hospital patient data and the results were compared with the results provided by experts. The experimental results show that the system can determine blood disorders with 93% accuracy and 100% precision in thalassemia prediction. This system is very effective to help doctors in diagnosing thalassemia patients.
Screening of Aroma Compounds in Commercial Tea (Camellia sinensis) from Indonesia and Testing Their Activity as Antioxidants Warsito, Warsito; Alief, M. Fadel; Azzahra, Vina Octavia; Rahman, M. Farid; Retnowati, Rurini
Journal of Tropical Pharmacy and Chemistry Vol. 8 No. 2 (2024): J. Trop. Pharm. Chem.
Publisher : Faculty of Pharmacy, Universitas Mulawarman, Samarinda, Indonesia, 75117, Gedung Administrasi Fakultas Farmasi Jl. Penajam, Kampus UNMUL Gunung Kelua, Samarinda, Indonesia

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Abstract

Tea from tea leaves of the Camellia sinensis species is a superior industrial plant that promises superior bioactivity. For a more in-depth study of the essential oils contained in commercial teas on the market, their significant characteristic from their constituent compounds were determined. The essential oil yields of the three commercial samples were obtained by distillation using a Liken-Nickerson vessel and analyzed by gas chromatography-mass spectrometry (GC-MS), then tested for antioxidant properties by the DPPH method. The yield obtained ranged from 0.08-0.13%. The main major components (more than 0.5% identified) contained in the three samples identified were benzyl acetate, between 4,56-26.27%, and linalool compounds from tea leaves, as much as 20.59%, and 3.42% in samples C and B which were not found in sample A. As shown by our results, antioxidant activity significantly correlated with benzyl acetate and linalool composition. Sample A showed the best antioxidant profile, with highest inhibition (IC50 20.19 mg/mL).
Hydrogenation of Alpha-pinene over Nickel Nanoparticles under Mild Condition Pressure Rizqi Alima Fabri, Ahmad; Warsito, Warsito; Ulfa, Siti Mariyah; Masruri
The Journal of Pure and Applied Chemistry Research Vol. 13 No. 3 (2024): Edition September-December 2024
Publisher : Chemistry Department, The University of Brawijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21776/ub.jpacr.2024.013.03.7916

Abstract

Alpha-pinene is the main compound in turpentine oil and is widely used as a fragrance, fine chemistry, flavour, and antibacterial. Due to the presence of unsaturated double bonds in its structure, this compound’s chemical properties are relatively active. Hydrogenation is a common method for saturating compounds and nickel has shown good activity in this process as catalysts. However, it often shows reaction conditions such as high pressure. The research method added nickel chloride to a suspension mixture of NaBH4 in isopropyl alcohol until a black colloidal solution and a-pinene reagents were added. Hydrogen gas was added in different conditions, with a pressure of 2-4 atm at the temperature of 50-60 oC 24h. The result showed a nickel formed at a nanoparticle size of 34-81 nm. Furthermore, FT-IR results show a difference in intensity at wavelengths of 1600 and 3000 cm-1, indicating the formation of hydrogenation products. The GC-MS shows a new peak at a retentivity of 5.503, which characteristics show that it is identified as a pinane compound with the highest percentage of 63% at a reaction condition of 4 atm. 
Determining the Grade of Robusta Coffee Beans of Lampung, Bengkulu, and South Sumatra Provinces by Using the Analytical Hierarchy Process (AHP) Yuniarthe, Yodhi; Syarif, Admi; Gitosaputro, Sumaryo; Warsito, Warsito
JOIV : International Journal on Informatics Visualization Vol 9, No 1 (2025)
Publisher : Society of Visual Informatics

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.62527/joiv.9.1.2667

Abstract

Coffee is an important commodity for the world business community. One of the world's leading coffee producers is Indonesia. In Indonesia, several provinces produce coffee beans, especially in Sumatra island. They generally cultivate robusta-type coffee. The determination of coffee quality here is still done manually. Recently, along with the increasing recognition of computers, several decision-support system approaches have been introduced, including the Analytical Hierarchy Process (AHP). This research aims to implement the AHP to assess Indonesian robusta coffee beans (Lampung, Bengkulu, and South Sumatra). The researchers use a systematic process, including the preparation stage, data collection using datasets, determination of criteria and alternatives, hierarchical structure, creation of matrices to compare pairs, calculation of priority vectors and eigenvector values, and accuracy testing. This research uses six criteria with 19 sub-criteria and seven alternatives. From the rankings calculated using the AHP method for coffee production areas, the best quality coffee bean is in West Lampung, with the highest value of  0.28. The results of this study are compared with those given by an expert. The results show the MAPE error of 4.42%, a very accurate category.  Thus, it is shown that this method provides excellent results. Future research can be conducted to develop a more sophisticated and efficient AHP method for multi-criteria decision-making in various fields such as business management, engineering, environment, and health.
Co-Authors A. Ghanaim Fasya Abd. Rasyid Syamsuri Abdul Madjid Adhaini, Finna Adi Hermansyah, Adi Admi Syarif Adryanto, Edwin Aewaditha, Randha Kentama Agus Hermawan Agus Hidayat Agus Wantoro Ahmad Ahmad Ahmad Amarullah, Ahmad Akhmad Dzakwan, Akhmad Alief, M. Fadel Angraini, Lili Anis Artiyani Arie Srihardyastutie Arif Fadilah, Ahmad Armanto, Mustika Edi Asrowi Asrowi Ayu Sangging, Putu Ristyaning Azhar, Asyfariatus Zulfa Aziz, Mohamad Fathoni Azzahra, Vina Octavia Bakri Bakri Bayu Indrayanto Chabiburrochman, M. Mas'ud Citra, Dewi Sriani D Budianta, D Damiana Nofita Birhi Darmanto, Prihadi Setyo Dedi Muhtadi, Dedi Destyarini, Normalita Dewi, S. K. Dewi, S. K. Dian Wahyuningsih Dodi Iskandar, Dodi Dwi Hartantri, Saktian Dwi Setyawan Dyan Isworo Edi Priyo Utomo Elvina Dhiaul Iftitah Endah Setiani Astuti Evi Elisanti, Evi Farhana, Nida Fuady, Anies Ghifari, Muhammad Al Gumilar, Aris Guntoro, Muhammad Yogi Gurum A P Gurum A P, Gurum A P Gusrianto, Anindira Aiska Haikal, Umair Hamdani Hamdani Hardati, Ratna Nikin Haswati, Desty Heni Sulistiani Hepsi Nindiasari Husnul Muttaqin I Made Astina Ichsan Ichsan Ilham Mundzir Iskandar, Ratu Sarah Fauziah Junaidi Junaidi Kalpataru I Kalpataru I, Kalpataru I Kamilatun, Nur Ahya Kautsari, Alya Paradisa Khairun Nisa Kuncara, Fatihah Nanda Kurnia Muludi M. Farid Rahman M. Rahman Mardiansa, Edwin Maren, A Marjunus, Roniyus Markoni Markoni Marlina Marlina Marsi Marsi Masruri Masruri Masruri Melan, Firdania Desfani Moch Sasmito Djati Momon Sodik Imanuddin Muhammad Ikhsanudin, Muhammad Muhammad Wildan Muhammad Yasir Mulyoto mulyoto Mustaufir, Mustaufir Nashi Widodo Nisa Berawi, Khairun Noer Aini Nugraha, Fadylah Akbar Nur Choiro Siregar, Nur Choiro Nur Hidayat Nuriyanti, Ika Nur’aini, Dhiva Maulida Rizqi Pangestu, Ilham Aji Pradja, Bara P. Prahesti Tirta Safitri, Prahesti Tirta Pratomo, Sigit Adhi Priatna, S J Purwo Haryono Redy Susanto, Erliyan Renih Hayati Rina Arum Prastyanti, Rina Arum Rini Rahayu Kurniati Rizqi Alima Fabri, Ahmad Rodiyah, Roirotul Rohaya, Nizla Rollando, Rollando Rosli, Roslinda Rukmono Budi Utomo, Rukmono Budi Rully Charitas Indra Prahmana Rurini Retnowati Sabaruddin Sabaruddin Sabilah, Sahla Sahil, Mawardi Abi Saleh, Hairul Satria Jaya Priatna, Satria Jaya Setyawan, Dodi Yudo Shofiatul Jannah Sholikah, Nisa’us Siti Mariyah Ulfa SITI MUSLIKAH Sri Anitah Sri Budiyono, Sri Sri Suciyati, Sri Sri Wahyu Suciyati Sudiyo Widodo, Sudiyo Suharti, Eni Suhud Eko Yuwono Sukirwan Sukirwan Sulaiman, Abdulah Suleman Duengo Sumaryo Gitosaputro Sumaryo Sumaryo Supriyanto, Amir Surtono, Arif Susi Harnani, Susi Sutiman B. Sumitro Teguh Achadi Upik Mutiara Vientje Ratna Multiwijaya Widoretno, W. Widoretno, W. Wisnu Nugroho Aji, Wisnu Nugroho Wulan, Indah Indar Yakup Parto Yeni Nuraeni, Yeni Yeni Prasetyo, Yeni Yodhi Yuniarthe Zatira, Dhea