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Efek Aktivasi H2SO4 Terhadap Lempung Sebagai Katalis Dalam Pembuatan Biodiesel Dari Crude Palm Oil (CPO) Muhammad Disro; Syaiful Bahri; Khairat Khairat
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 5 (2018): Edisi 2 Juli s/d Desember 2018
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Abstract

Indonesia petroleum consumed are increasing, while hot Indonesia's petroleum reserves are depleting so that fuel substitution needs to be sought. Recent years, a lot of research has done, purposed to find an alternative source one of that is biodiesel. Raw material for biodiesel production can be from animal fat or vegetable oil. Crude palm oil (CPO) one of an alternative raw material. This research is aimed to produce biodiesel from CPO, studying factors which influences production process, such as catalyst, recycle and regeneration as well as to determine the physical and chemical properties of biodiesel produced. The transesterification process was done, a mole ratio of oil: methanol 1: 9, oil mass 50 grams, weight of the catalyst 1%-wt, having temperature of 60°C for 90 minutes. Clay catalysts are activated with acids, and then recycle and regeneration of catalyst. Result given by of alkaline activation of the catalyst 90.16%. Based on characterization of physical properties of biodiesel, result as follow density 0.869 g/ml, kinematic viscosity 4,65 mm2/s, the flash point 120oC and cetane number 51,74. The catalyst regeneration proved not a 100% of catalyst reactived.Keywords: biodiesel, clay, recycle, regeneration, transesterification
Pembuatan Biodiesel Dari Minyak Biji Kapuk (Ceiba Pentandra) Dengan Katalis Lempung Teraktivasi; Pengaruh Kecepatan Pengadukan Erlisa Yanuari Putri; Syaiful Bahri; Edy Saputra
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 5, No 1 (2018): Wisuda April Tahun 2018
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Abstract

Biodiesel producted by transesterifiation reaction which on energy source. Biodiesel was developed in Indonesia as an anticipatis of energy crisis problem suppported by goverment national energy policy. This research is aimed to make biodiesel from cotton seed oil, studying the effect of agitation speed to the amount of biodiesel produced and determined the best catalyst activated by acid or base, and determined the characteristics of biodiesel produced. The transesterification process was occured at a temperature of 60oC, on weight of oil 100 grams, reaction time 1,5 hours, mole ratio of oil to methanol 1 : 9, catalyst concentration 0,5% -weight of oil for varions of agitation rate 400, 500 and 600 rpm, and variations of catalyst acid 0,47, 0,62 and 0,78% and alkaline activated with a concentration of 0,33, 0,44 and 0,66%. From the result was obtained the highest biodiesel yield of 95,45% for alkaline activated 0,66% for agitation speed of 400 rpm. Characterization of physical properties of biodiesel obtained here density of 878 kg/m3, 3,03 mm2/s kinematic viscosity, acid number 0.34 mg KOH/g sample, and the flash point 195oC.Keywords: biodiesel, clay catalysts, activation of acids and bases, transesterification
Pengaruh Kecepatan Pengadukan Pada Sintesis Biodiesel Dari Minyak Jarak Pagar (Jatropha Curcas L) Dengan Katalis La/Lempung Yenni Octavia; Syaiful Bahri; Khairat Khairat
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 7 (2020): Edisi 1 Januari s/d Juni 2020
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Abstract

The increased energy needs of fossil fuels in particular leads to a decline in the world’s oil reserves which make this extremely rare. One way to reduce the energy crisis and the impact that fossil-funded energy use can have is to develop new and renewable energies such as vegetable fuels. One of the alternative forms of energy currently being developed is biodiesel. Biodiesel is one of the environmentally friendly alternative to diesel fuel. This research studied the effect of agitation speed with variations 300 rpm, 400 rpm 500 rpm, metal that falls into clay with variations 1%, 3%, 5% and activation NaOH with variation 1N, 2N and 3N to the yield biodiesel produced, and to indentifying the characterictics of biodiesel produced. This study begins impregnation of La metal into clay, the La/clay catalyst is calcination for 6 hours at 500oC with N2 gas, oxidation for 2 hours at 400oC with O2 gas and reduction for 2 hours at 400oC with H2 gas. After that, do the process of esterification in the flat bed reactor the temperature reaction 60 oC and reaction time 60 minutes, and then process of transesterification with temperature reaction 60 oC, reaction time 90 minutes, ratio mole oil : methanol 1/9, and catalyst weight 3 % (w/w) oil. Highest biodiesel yield obtained amounted to 89,78 % at the agitation speed 400 rpm and metals La(5%)/clay activation NaOH 3N. Physical characterization of biodiesel were done such as density 884 kg/m3, kinematic viscosity 5.54 mm2/s, acid number 0.676 mg-KOH/g biodiesel and flash point 139 oC respectively which have accordance with the standards of Indonesian biodiesel (SNI 04-7128-2015). Keywords: BBN, biodiesel, esterification, La/Clay catalyst, transesterification
Pembuatan Biodiesel Dari Minyak Biji Kapuk (Ceiba Pentandra) Dengan Katalis Lempung Teraktivasi; Pengaruh Waktu Reaksi Terhadap Yield Biodiesel Nurlis Nurlis; Syaiful Bahri; Edy Saputra
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 4, No 2 (2017): Wisuda Oktober Tahun 2017
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Abstract

Research on production biodiesel from kapok seed oil (ceiba pentandra) using an activated clay catalyst has been performed. It aimed to determine the effect of an activated clay catalyst on producing biodiesel, its quality and to study the effect of reaction time. Clay catalyst was activated by H2SO4 0.47%, 0.62%, 0.78% and NaOH with a concentration of 0.33%, 0.44%, 0.66%. Esterification with methanol in the ratio 1:12 with the addition of H2SO4 as much as 1% of the weight of oil. The next transesterification reaction, the kapok seed oil is reacted with methanol in the ratio of 1: 9 with the acids and bases activated clay catalyst. The reaction temperature of 60 °C, various of reaction time 1 hour, 1.5 hours and 2 hours. The results showed that the use of an activated clay catalyst H2SO4 0.78%, the reaction time of 1.5 hours to produce the highest yield 92.18%. Physical characteristics of biodiesel were obtained density 869 kg/m3, kinematic viscosity of 2.67 cSt, the acid number of 0.45 mg KOH/g sample and the flash point of 209oC. From the results was obtained biodiesel produced in compliance with the SNI 7182: 2015.Keywords: activation, biodiesel, clay, kapok seed oil, transesterification
Pembuatan Bio-Oil Dari Kayu Cemara (Causarina Equisetifolal) Dengan Teknologi Pirolisis Menggunakan Katalis MO/NZA Hasnul Bustaman; Syaiful Bahri; Amun Amri
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 3, No 2 (2016): Wisuda Oktober Tahun 2016
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Bio-oil can be produced by pyrolisis of causarina wood with catalyst Mo/NZA. The purpose of this research was to produce bio-oil from causarina wood, determine the effect of theimpregnation percentage of Mo metal and ratio of Mo/NZA catalyst on the yield of bio-oil and determine the physical and chemical characteristics of bio-oil. Pyrolysis using 50 grams causarina wood, 500 ml silinap and Mo/NZA catalyst with variations of the impregnation percentage of Mo metal 0%, 0,5%, 1%, 1,5% and the variation ratio of Mo/NZAcatalyst 3% and 5% of the biomass with a stirring speed of 300 rpm and a temperature of 320ºC for 120 minutes. In this research, the highest yield on the variation of the impregnation percentage of metal 1,5% and the ratio of catalyst 5% of the biomass amounted to 66,79%. Characteristics of bio-oil obtained were density 1,012 gr/ml, viscosity 3,14 cP, acid number 75,48 mg NaOH/gr sample, and the flash point 52oC. The results of GC-MS analysis, the dominant chemical components inthe bio-oil were 2-propanone,1-hydroxy- with an area 51,55 % , 1,1’-bibicyclo(2.2.2)octyl-4- carboxylic acid with an area 14,77 % dan 2-Propanone with an area 0,8 %.Keywords: Bio-oil, Pyrolysis, Catalyst Mo/NZA, Causarina wood
Pirolisis Kayu Akasia (Acacia Mangium) Menjadi Bio-Oil Menggunakan Katalis Ni/NZA Dengan Variasi Pengembanan Logam Dan Rasio Katalis Sari Rahma Yanti; Syaiful Bahri; Amun Amri
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 2, No 1 (2015): Wisuda Februari Tahun 2015
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The problems that currently appear in Indonesia is the energy crisis, especially fuel oil (BBM). Fuel derived from crude oil (fossil fuel) that can not be updated, so the next few years is expected to be deprived community will fuel. To overcome these problems needed alternative energy sources is the use of renewable biomass into bio-oil. Bio-oil is produced from biomass through pyrolysis. The purpose of this research was determine the effect of the impregnation percentage of Ni metal and ratio of catalyst Ni/NZA on the yield of bio-oil and determine the physical and chemical characteristics of bio-oil. Pyrolysis using 50 grams acacia wood, 500 ml silinap and Ni/NZA catalyst with variations of the impregnation percentage of Ni metal 0%, 1%, 3%, 6% and the variation ratio of catalyst Ni/NZA 3%, 6% and 9% of the biomass with a stirring speed of 300 rpm and a temperature of 320ºC for 120 minutes. In this research, the highest yield on the variation of the impregnation percentage of metal 1% and the ratio of catalyst 9% of the biomass amounted to 77,85%. Characteristics of bio-oil obtained were density 0,865 gr/ml, viscosity 1,621 cSt, acid number 88,115 mg NaOH/gr sample, and the flash point 43oC. The results of GC-MS analysis, the dominant chemical components in the bio-oil were 1,3-Pentadiene, 2,4-Dimethyl (1,591%), 3-Octyne,7-methyl (1,591%), 4-Nonene,5-butyl (7,846%), Dodecane,5,8-diethyl (3,531%) and 1-Tricosanol (7,158%).Keywords: Bio-oil, pyrolysis, catalyst Ni/NZA, acacia wood
Konversi Termal kayu ketapang (Terminalia Catappal) Menjadi Bio-Oil Dengan Teknologi Pirolisis Menggunakan Katalis NiMo/NZA Ari Aditia Sukma; Syaiful Bahri; Aman Aman
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 1, No 1 (2014): Wisuda Februari Tahun 2014
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Abstract

Availability of fossil fuels are depleting resulted in higher mining costs and selling prices to the public. In addition, the results of its combustion also releases GHG to the environment. One way to reduce the use of fossil fuels is produce bio-oil through pyrolysis technology. Ketapang rod is a huge potential used as feedstock for bio-oil production because its high cellulose content (41.80%). Synthesis of bio-oil from Ketapang stem begins with the process of size reduction of biomass and natural zeolite to -100+200 mesh size. Then, into the natural zeolite impregnated Ni and Mo to form the bimetallic catalyst NiMo/NZA. The catalyst is then activated through the stages of calcination, oxidation, and reduction. Pyrolysis process is done by varying the weight percentage of catalyst to biomass, ie: 1.5%, 2%, 2.5%, and 3% w/w. In addition, the catalytic pyrolysis process is carried 3% NZA only  and 3% NiMo/NZA were activated by calcination process alone. The highest yield was obtained on the use of catalysts NiMo/NZA perfect activated which amounted to 91.05%. From physics analysis performed on the bio-oil obtained: density of 0.91 g/ml, viscosity 10.839 cSt, acid number 46.954 mg NaOH/g sample, flash point 52oC, and the heating value 42.66 MJ/Kg. The figures are included in the range of physical characteristics of diesel-oil. Five (5) the dominant compound results of chemical analysis by GC-MS of the bio-oil from Ketapang rod by using a catalyst NiMo/NZA 3% by weight are: 3,4,4-trimethyl-2-nonene (10.29%), isobutylene (8.84%), 2,2-dimethyl-butane (8.05%), 3,4,4-trimethyl-2-pentene (5.76%), and 2-methyl-1-heptene (5.26%).  Keywords: Bio-oil, Pyrolysis, and Catalyst NiMo/NZA
Pirolisis Kulit Kayu Pinus (Pinus Mercusil) Menjadi Bio-Oil Menggunakan Katalis Ni/Lempung Laila Kusmiati; Syaiful Bahri; Khairat Khairat
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 2, No 1 (2015): Wisuda Februari Tahun 2015
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Requirement for the source of energy which increasing and petroleum reserve as source of primary energy which continuing attenuate to become the main reason for the importance ofsearching for alternative energy sources instead of petroleum. Biomass specially pine bark only considered as waste that pollutes the environment, whereas the pine bark is biomass that can be processed to become alternative energy that is bio-oil. Bio-oil can be produced through pyrolisis process using catalyst Ni/clay. This research aim to study the effect of the ratio of amount of catalyst to biomass which variation to 3%, 5% and 7% b/b and also the effect of Ni metal consentrate on clay equal to 0%, 1%, 2% and 3% w /w of the yield bio-oil produced. In thisresearch, pine bark biomass as much 50 grams with size of --60+80 mesh, silinap 500 ml, and catalyst Ni/clay entered into pyrolisis reactor. Process of pyrolisis is conducted at temperature320 oC and stirring speed of 300 rpm during 120 minute with stream of nitrogen gas (N2) as inert gas. The result obtained indicate that optimum yield obtained at 2% catalyst Ni/clay asmuch as 7% of biomass that is equal to 61,03%. Physical properties test result obtained that is density (0,856 gr/ml), viscosity (9,306 cSt), acidity number (24,986 mg of NaOH/gr of sample) and flash point (54 oC). Result of chemical analysis with GC-MS, obtained the dominant chemical components in bio-oil are 2-Pentene 22,31%, Pentane 13,46%, 1-propene 7,55%, 2- Hexene 7,35 and 1-Pentene 5,95%.Keywords: Biomass, Bio-oil, Catalyst Ni/Clay, Pine Bark, Pyrolysis
Produksi Biodiesel Dari Minyak Nyamplung Dengan Katalis Ni/Lempung Taufik Kharnofa; Syaiful Bahri; Yusnimar Yusnimar
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 3, No 2 (2016): Wisuda Oktober Tahun 2016
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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The research has been done to produce biodiesel from calophyllum inophyllum oil with Ni/clay catalyst. Several variations of the process variables were done to assess its influence on acquisition (yield) of biodiesel and quality of biodiesel produced. The variables are used consist of a dependent variable and independent variable. Dependent variables are calophyllum inophyllum oil weight 50 grams, the catalyst concentration Ni / clay 0.5%-b oil, reaction temperature of 60 °C and a reaction time of 90 minutes, while the independent variable which variation mole ratio of oil : methanol 1: 6, 1: 9 and variations of Ni metal impregnation 0% -w (no metal) 1%-w, 2%-w and 3%-w samples of clay. This research has given result the highest yield of 95.36% biodiesel obtained in the use of Ni(3%)/clay catalyst and the mole ratio of oil : methanol of 1: 9. The biodiesel produced has a density of 883 kg/m3, kinematic viscosity of 4,46 mm2/s, acid number of 0.50 mg KOH / g sample and the flash point of 155°C respectively.Keywords: Biodiesel, Ni/Clay Catalyst, Calophyllum Inophyllum Oil
Pembuatan Biodiesel Dari Biji Saga (Adhenantera Pavonina) Dengan Katalis Padat H-Zeolit James Becker; Syaiful Bahri; Syamsu Herman
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 3, No 1 (2016): Wisuda Februari Tahun 2016
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Abstract

Transesterification reaction is a reaction between the oil (triglyceride) with alcohol to produce methyl esters. One of commercial product is biodiesel. The production of biodieselfrom vegetable oils, especially seed oil saga is still very limited, it is necessary to develop a vegetable oil-based biodiesel. In this research, the manufacture of biodiesel bytransesterification reaction using natural zeolite catalysts are activated to H-Zeolite, with a variation of the molar ratio of reactants (1: 3, 1: 6 and 1: 9) and the number of H-zeolitecatalyst (6%, 8% and 10%) with a fixed variable is the reaction temperature 60 ° C, the reaction time of 200 minutes and the stirring speed of 200 rpm. From the test results showthat the molar ratio transesterification and the amount of catalyst affects the reaction rate toachieve equilibrium of the reaction. The best operating conditions obtained in this study isthe molar ratio of 1: 9 and the amount of catalyst 8% which resulted in a conversion reaction of 86.44%. Characteristics of biodiesel produced in this study meets the standards of commercial biodiesel with kinematic viscosity of 5.15 cp, specific gravity (40 ° C) 0.853 and saponification numbers were 0.49 mg KOH / g sample.Keywords : Biodiesel, H-zeolite, Oil, Transesterification.
Co-Authors ', B. Isyandi ' -, Sunarno Abd. Mukti, Abd. Abd. Rasyid Syamsuri Abid, Hussein Rasool Abu Bakar Adam Fadillah Ade Evi Fatimah Adelina Samosir Adita Sukma Ramadhania Afina, Zahira Afria Anggreini Afrielyanda H Agung Abadi Kiswandono Agus Faisal Asyha Ahmad Fadli Ahmad Fuad Ahmadi, Peni Ainol Yaqin, Ainol Ajmal, Muhammad Alhajj, Irfan Qowwiyul Aziz Alhamid, Ipa Fatma Almasdi Syahza Altarawneh, Mohammednoor Aman aman Ambarwati, Yuli Amilia Linggawati Amini Amini Amiruddin Amiruddin Amun Amri Andari , AA Andi Mulya Adha Andi Setiawan ANDI WIJAYA Anggreini, Winsa Septi Anisa, Lia Rizqi Nur Anna Apryana Annisa, Devi Nur Annisa, Eka Dini Antania, Livia Anwar Sumianto Aprilia, Tika Dwi Arai, Masayoshi Arbhy Indera Ikhwansyah Ari Aditia Sukma Ari Sandhyavitri Aria Gusti Ariasih, Rr. Arum Aries Saifudin Arinda, Shafira Aprilla Aritonang, Muhibbah Asad, Muhammad Mujtaba Asman, Pendi Aspita Laila Aulia Rahman Aura Dhayang Fiarizky Ayumi, Eksa Azhar, Muhammad Rizwan Aziz, Melly Pusvita Baharudin Baharudin Baryanto Berghuis, Nila Tanyela Bernard Isyandi Brilliant Asmit Bunga Fitriani Gumadita Bustamam, Nurbaity Chairul Chairul Chairul Chairul Chartady, Rachmad Damanik, Khairunnisa Dani Ali, Nurhalim Daud, Attaillah Dedi Afandi Dedy Hidayatullah Alarifin, Dedy Hidayatullah Desak Made Yoniartini Desi Heltina Dhani Nur Miftahudin Dian Agustin Djaimi Bakce Dzaljad, Rifma Ghulam Edwidya Ocktaviani Armay Edy Saputra Edy Saputra Effendi, Mardian Effendy, Sjahril Ekadian Lestari Simatupang Eko Prihandono Ella Awaltanova Elvi Yenie, Elvi Elvianto Dwi Daryono Emi Tipuk Lestari *, Emi Tipuk Lestari Erlisa Yanuari Putri Ermiyati Erniwati Erniwati Fabryza, Dhina Fadillah, Ryan Faizal, Doddy Fajar Restuhadi Fathiyah Zulfahni Febrian, Ramadhoni Feby Pratama Nugraha Feni Nopriza Figna, Harry Pratama Fikri, Muhammad Fathan Fiqna, Harry Pratama Firman syah Firmansyah, Muhammad Yusuf Fistiyanti, Davinta Fitra Marsela Fitriani Fitriani Fitriani, Nurdiana Friska Octavia Rosa, Friska Octavia Ganjar Andhulangi Genardus Oktavri Sijabat Habibie, R. Fikry Nanda Hade Karimata Hadyan Sartoni Hafidz Nifa, Muhamad Hajar, Muhammad Nurul Hambali, Ach Hamdali, Hamdali Hammad, Hammad Harahap, Ahmad Indra Harahap, Dosma Gabena Hardiansyah Hardiyanto, Candra Hari Setiono, Hari Hartono, Arif Haryo Satriya Oktaviano HASANAH, IDA FADIRATUL Hasnul Bustaman Hasrudy Tanjung, Hasrudy Hedri Yanti Hery Widijanto Hesty Rodlotu Yula Hetti Zuliani, Hetti Husna, Zakiyatul Hutahaean, Agung Mangalambok I KADEK ADHI DWIPAYANA . I Nengah Suandi I Wayan Suastra Ibnu Oktariza Ida Bagus Putu Arnyana Idi Warsah Idral Amri Ilim, Ilim Ilmi, Assyifa Aini Ilmiddaviq, M. Bahril Inget Yester Yunanda Irawan, Nopi Irdoni Irdoni Irlani, Intan Irnaliah, Irnaliah Irwan Fathurrochman, Irwan Irwan Irwan Isma Swadjaja Isnaini, Nurdiana Fitri Iswadi Idris James Becker Jefriadi Jefriadi Jiang, Zhong Tao John Hendri Julian, Risma Juliasih, Ni Luh G. R. Juliasih, Ni Luh Gede Ratna Jumira Warlizasusi Karim, Ahmad Fauzun Karina Octaria Putri Keisya, Nurul Khairat Khairat Khairat, Khairat Khairul, Anapuja Khairunnisa, Zhafira Amriyatti Kharismatunnisaa, Fiona Khoiriyah, Alfiatul Kholil, Moh. Kinanti Kinanti, Kinanti Kiswandono, Agung A. Laila Kusmiati Lailatul Qomariyah, Lailatul Lalu Erwan Husnan, Lalu Erwan Larasaty, Anisya Lestari, Miranti Tri Lianingsih, Firli Dwi Lisna Efiyanti Lubis, Afandi Husin Amin Syahrul Lutfiah, Rosyidatul M Arfi Adharyandy Firman M. Nasor, M. Makkah Ramadhan Putra Rizal Margrety, Betty Margunaji, Agus Maya Sista, Eliya Meliagustin, Adilla Mhd. Reza Pahlepi Miftahudin, Dhani Nur Miran, Hussein A. Miswaty, Miswaty Mita Rilyanti Mitri Irianti Mizna Sabilla Mohammad Muhibbin Muhammad Amin Muhammad Azlin , Dico Muhammad Disro Muhammad Imam Nugraha Muhammad Isa Alamsyahbana Muhammad Ismet muhammad rizky, muhammad Muhammad Sulthon Siregar Muhammad Zulfikar Adha Muhdarina Muhdarina . Muhdarina Muhdarina Muhtadi Muhtadi MUIS FAUZI RAMBE Mukti, Lailatul Latifa Mulyadi Mulyadi Mulyono Mulyono MURNI YANTO Musbar, Al Swendo Nabila, Abelia Najmuddin MA, Najmuddin nasir, muh Nasution, Jamilah Aini Nia Meisa Wulandari Nifa Abdillah, Muhamad Hafidz Norlena Notiragayu, Notiragayu Nova Dwi Safitir Nur Ainiyah Nurbaity, Nurbaity Nurfaradina, Zaskia Ayu Nurfatihayati Nurhaeni Nurhaeni Nurhasanah Nurhasanah Nurhasanah Nurhasanah Nurhayati Nurhayati Nurhayati, Nurhayati Nurkholimah, Siti Nurlis Nurlis Nurmarita, Nurmarita Oci Khairani Oktarina, Rasmi Zakiah Oktaviyana, Amiliya Pambudi, Naufal Prawiranegara, Barata Aditya Prayoga, Mohammad Dicky Puji Prasetyo, Angga Puji, Lela Kania Rahsa Purba, Doni El Rezen Purwadi, Ofik Taupik Putri Azizah Putri, Karina Octaria Putri, Nazla Syafrina Qudus, Hardoko Insan R. Supriyanto R.Y, Silvia Rachma, N. Rahmadani, Natasya Suci Rahmah, Yulia Rahman, M. Mahbubur Rahman, Waqi’ Rahmansyah Rahmansyah Rahmiyati, Evi Rais , Wendi Raja Valti Mhd Siregar Rajib Azri Ramin, Moh. Ranum Anggun Sari, Ranum Anggun Ratna Dian Armalita Raudhatul Jannah Raudloh, St. Regina Gita Riani Dio Renia Navivin Revita Sari Riady, Yasir Riansyah, Muhammad Ridho Fahrozi Ridwan Siskandar Rifa’I , Ahmad Rinawati Rinawati Rinawati Rinawati Rinny Jelita Rino Hasanatul Isra Risca Dwiaryanti, Risca Rizal, Makkah Ramadhan Putra Rizka Aulia Hardi, Rizka Aulia RM Riadi Rofiqi, Ahmad Romie Jhonnerie Rosalina, Fira Rosita, Dara Ryan Dhika Priyatna S Siswanto Sabrina, R Salim Aktar Salim, Sulaiman Samawi, Oscar Raihan Saputra, Adika Saputra, Yourdan SAPUTRI, KENI APRILIA Saputri, Rafhita Ika Sari Rahma Yanti Sari, Linda Nevia Sari, Silvya Reza Novita Sarma, Deki Savitri Larasati Setiadi, Fydel Setianingsih, Ayu Setiawan, Fendi Shabira, Qonita Shahib, Abdul Sheiscatamya, Vezhia Shubhi, Muhammad Silvi Puteri Anggraini Silvia R.Y Siti Nurbaya Siti Nurul Khotimah siti rahmah Sofi Dwi Octavia Ningtiyas Sri Waluyo Subangkit Julio Jaya Sucipto Sufi, Sutan Badarudin Sugeng, Santoso Sugiyanto - Sukiman Hernanda Sukitman, Tri Sulistyawati Sulistyawati Sulton Sholehuddin, Sulton Sunarno Sunarno - Sunarno Sunarno Sunarno Sunarno Suratman Suratman Surya Romadani Sutopo Hadi Sutrisno, Sutrisno Suwanto Suwanto Syaddad, VirzqiZulviqar Syafrial Nur Syamsu Herman Syamsuri T. Ariful Amri Tahir, Tahir Tanjung, Muhammad Hafiz Taufik Kharnofa Tirsya, Riana Tresia Monika Natalia Sinaga Tri Okta Ratnaningtyas Utama, Panca Setia WAWAN ABDULLAH SETIAWAN, WAWAN ABDULLAH Wega Trisunaryanti Widiarto, Sonny Widiarto, Sony Wisrayetti Wisrayetti Wisrayetti, Wisrayetti Wulandari, Ika Rizki Wulandari, Revika Yanto, Murni Yatim Lailun Ni’mah Yelmida Azis Yeni Puji Astuti Yeni Rizki Yenni Octavia Yopalim Zanstra Yuli Ambarwati Yulianti Yulianti Yuliati Eka Putri Yuliatmi Yuliatmi Yumna, Nada Ibtihal Yusnimar Sahan Yusuf Yusuf Zainuddin, Zainuddin Zetria Pujiana Zipora Sembiring Zuchra Helwani Zuchra Helwani, Zuchra